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K. A. Vorotilov V. D. Zvorykin I. G. Lebo A. S. Sigov 《Journal of Russian Laser Research》2004,25(3):234-238
Preliminary experiments on laser annealing of ferroelectric samples by ultraviolet radiation of a KrF laser are carried out. In principle, laser annealing allows one to reduce appreciably the duration of thermal action, minimize the size of the samples treated, and control the crystallization processes in the samples. A special focussing system was employed to provide homogeneous irradiation of the spot with dimensions of ~1×1 cm2 within a broad energy range from 0.1 to 10~J per pulse. The range of energy densities leading to phase transitions in thin films is determined. 相似文献
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An experimental study of the thermal decomposition of a β‐hydroxy alkene, 3‐methyl‐3‐buten‐1‐ol, in m‐xylene solution, has been carried out at five different temperatures in the range of 513.15–563.15 K. The temperature dependence of the rate constants for the decomposition of this compound in the corresponding Arrhenius equation is given by ln k (s?1) = (25.65 ± 1.52) ? (17,944 ± 814) (kJ·mol?1)·T?1. A computational study has been carried out at the M05–2X/6–31+G(d,p) level of theory to calculate the rate constants and the activation parameters by the classical transition state theory. There is a good agreement between the experimental and calculated rate constants and activation Gibbs energies. The bonding characteristics of reactant, transition state, and products have been investigated by the natural bond orbital analysis, which provides the natural atomic charges and the Wiberg bond indices. Based on the results obtained, the mechanism proposed is a one‐step process proceeding through a six‐membered cyclic transition state, being a concerted and slightly asynchronous process. The results have been compared with those obtained previously by us (Struct Chem 2013, 24, 1811–1816) for the thermal decomposition of 3‐buten‐1‐ol, in m‐xylene solution. We can conclude that in the compound studied in this work, 3‐methyl‐3‐buten‐1‐ol, the effect of substitution at position 3 by a weakly activating CH3 group is the stabilization of the transition state formed in the reaction and therefore a small increase in the rate of thermal decomposition. 相似文献
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Abstract Due to the wide use of polymers in medicine, researchers are required to solve a very important problem–to understand the interaction between materials of nonphysiological origin and the surrounding biological liquids, and tissues, particularly blood. 相似文献
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S. G. Zaitsev I. G. Lebo V. B. Rozanov S. N. Titov E. I. Chebotareva 《Fluid Dynamics》1991,26(6):806-811
An experimental apparatus for investigating Rayleigh-Taylor instability in the transition layer between two gases at accelerations g 105g0 (g0 is the acceleration of gravity) is described. The constantly acting acceleration is communicated to the contact zone by the compression wave formed ahead of a flame front. The linear stage of development is investigated together with the effect of the thickness of the contact zone. It is shown that on the interval 0.3 < <- ( is the wavelength of the disturbance at the edge of the contact zone) the rate of growth of the perturbation amplitude 0.50, where 0 is the amplitude growth rate for media separated by an interface with a discontinuous change of density.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 15–21, November–December, 1991. 相似文献
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V. A. Gasilov S. Yu. Gus’kov A. Yu. Krukovskii I. G. Lebo A. A. Otochin V. B. Rozanov S. V. Zakharov 《Journal of Russian Laser Research》1997,18(6):515-528
This paper deals with a numerical simulation and theoretical investigation of the behavior of plasma flows produced when injecting a laser beam into a target for inertial thermonuclear fusion and absorbing laser radiation in the target internal cavity. Results of two-dimensional numerical calculation are presented for laser beam interaction with the sub critical plasma contained in the gap between two coaxial shells of a laser greenhouse target. The calculations confirm the possibility of initiating a supersonic wave of electron heat conduction in the absorber of the laser greenhouse target. 相似文献
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Z.M. Babar Wan Mohd Azizi Solachuddin JA Ichwan Qamar Uddin Ahmed Abul Kalam Azad Imranul Mawa 《Natural product research》2019,33(15):2266-2270
The current study provides a way of extraction for both active NSO and WSE from Nigella sativa seeds using 98% methanol. About 1?kg of ground seeds was macerated by 1:2.5 w/v (g/mL) for 72?hours. After rotary evaporation and 7 days of continuous drying and chilling at 50 and 4?°C, NSO and WSE were obtained at the same instant. Solubility tests of 24 solvents and 11 thin layer chromatographic analyses while 2, 2-diphenyl-1-picrylhydrazyl free radical scavenging assay of NSO (73.66) , WSE (33.32) and NSO?+?WSE (78.22) against ascorbic acid (IC50?=?4.28?mg/mL) was performed. WSE was found to be highly soluble in water and 5% NaOH exhibiting the same Rf value of 0.95 for EtOH:DMSO (9:1) against the honey. WSE has revealed more than twofold higher anti-oxidant activity than others. Formulation of WSE with Tualang honey may provide better targeted hydrophilic drug delivery systems. 相似文献
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