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排序方式: 共有562条查询结果,搜索用时 15 毫秒
1.
Joseph W. Rumer Sheng‐Yao Dai Matthew Levick Laure Biniek David J. Procter Iain McCulloch 《Journal of polymer science. Part A, Polymer chemistry》2013,51(6):1285-1291
Two novel dihydropyrroloindoledione (DPID)‐based copolymers have been synthesized in a two directional approach and characterized (gel permeation chromatography (GPC), ultraviolet‐visible (UV–vis), cyclic voltammetry, and computational models). These planar, broad absorption copolymers show promise for use in organic electronics, with deep energy levels and low bandgaps. The two‐directional Knoevenagel condensation used demonstrates the versatility of DPID as a useful yet underexploited conjugated unit. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
2.
Mérièm Anouti Amina Mirghani Johan Jacquemin Laure Timperman Hervé Galiano 《Ionics》2013,19(12):1783-1790
Herein, a facile method was developed for preparing high concentration of monodispersed gold nanoparticles (NPs) at room temperature from gold(III) chloride by using different media based on N,N-dimethylformamide or water solutions containing a protic ionic liquid (PIL), namely, the octylammonium formate or the bis(2-ethyl-hexyl)ammonium formate, based on which both PILs were used as redox-active structuring media. The formation of gold NPs in these systems was then characterized using UV–visible spectroscopy, transmission electron microscopy, and dynamic light scattering. From these investigations, it appears that the structure and aggregation pathway of PILs in selected solvents affect strongly the formation, growth, the shape, and the size of gold NPs. In fact, by using this approach, the shape-/ size-controlled gold NPs (branched and spherical) can be generated under mild condition. This approach suggests also a wealth of potential for these designer nanomaterials within the biomedical, materials, and catalysis communities by using designer and safer media based on PILs. 相似文献
3.
Adult zebrafish as a model organism for behavioural genetics 总被引:1,自引:0,他引:1
Recent research has demonstrated the suitability of adult zebrafish to model some aspects of complex behaviour. Studies of reward behaviour, learning and memory, aggression, anxiety and sleep strongly suggest that conserved regulatory processes underlie behaviour in zebrafish and mammals. The isolation and molecular analysis of zebrafish behavioural mutants is now starting, allowing the identification of novel behavioural control genes. As a result of this, studies of adult zebrafish are now helping to uncover the genetic pathways and neural circuits that control vertebrate behaviour. 相似文献
4.
5.
Badr Benmansour Ludovic Stephan Jean-Yves Cabon Laure Deschamps Philippe Giamarchi 《Journal of fluorescence》2011,21(3):843-850
This work presents spectroscopic properties of some Endocrine Disrupting Compounds (EDCs), frequently found in food and in
natural water. Studied molecules belong to the groups of phenolic and phthalate EDCs. In a first part, we have examined their
absorption and fluorescence properties. Fluorescence emission wavelengths are about 300 nm for phenolic compounds and 360 nm
for phtalate compounds; main excitation wavelengths being comprised between 210 nm and 230 nm. Fluorescence lifetimes measured
are short (about 4 ns) and the fluorescence quantum yield has been determined. In a second part, to avoid the time consuming
solvent extraction step, an analytical application to evaluate the performance of a direct analysis by laser induced fluorescence
spectroscopy of ECDs traces in tap water and in raw water is presented. Good detection limits have been obtained, i.e.: 0.35 μg.L−1 of chlorophenol in tap water, which are always lower than the reported Predictive Non Efficient Concentration (PNEC). 相似文献
6.
My-Loan-Phung Le Fannie Alloin Pierre Strobel Jean-Claude Lepr��tre Laure Cointeaux Carlos P��rez del Valle 《Ionics》2011,18(9):817-827
Ionic liquids, ILs, based on fluorinated pyrrolidinium and piperidinium ammonium cations and imide anion were prepared and characterized. The physicochemical and electrochemical properties of these ILs including melting point, glass transition and degradation temperatures, viscosity, ionic conductivity, and electrochemical stability were determined and compared to alkyl pyrrolidinium and piperidinium ILs. The incorporation of a CF3 group instead of a CH3 induces an increase of the IL viscosity, thus a conductivity decrease. However, good ionic conductivity is obtained with fluorinated pyrrolidinium IL. Cyclic amine ILs with propyl alkyl chain or fluorinated ammonium exhibit very high electrochemical stability toward oxidation. The effect of the addition of LiTFSI on the IL properties was studied with the same methodology. 相似文献
7.
We give here a complete derivation of the Navier-Stokes-Fourier equations from a model collisional kinetic equation, the BGK model. Though physically unrealistic, this model shares some common features with more classical models such as the Boltzmann equation.Then the program developed by Bardos, Golse and Levermore [Fluid dynamic limits of kinetic equations II. Convergence proofs for the Boltzmann equation, Comm. Pure Appl. Math. 46 (5) (1993) 667-753] to study hydrodynamic limits of the steady Boltzmann equation, and extended by Lions and Masmoudi [From Boltzmann equations to Navier-Stokes equations I, Archive Rat. Mech. Anal. 158 (2001) 173-193] in the time-dependent case, can be adapted here, and gives the expected convergence result provided that the particle density f satisfies some integrability assumption.The originality of the present work is to remove this assumption by establishing refined a priori estimates. The crucial idea is to decompose f as (f−Mf)+Mf where Mf is the local Maxwellian associated with f. The first term is then estimated by means of the entropy dissipation, while the other is smooth in v. A mixing property of the operator (ε∂t+v.∇x) allows to transfer some of this extra-integrability on the variable x. 相似文献
8.
We prove that the renormalized solutions of the Boltzmann equation considered in a bounded domain with different types of (kinetic) boundary conditions converge to the Stokes‐Fourier system with different types of (fluid) boundary conditions when the main free path goes to zero. This extends the work of F. Golse and D. Levermore [9] to the case of a bounded domain. © 2003 Wiley Periodicals, Inc. 相似文献
9.
Putkunz CT D'Alfonso AJ Morgan AJ Weyland M Dwyer C Bourgeois L Etheridge J Roberts A Scholten RE Nugent KA Allen LJ 《Physical review letters》2012,108(7):073901
Ptychographic coherent diffractive imaging (CDI) has been extensively applied using both x rays and electrons. The extension to atomic resolution has been elusive. This Letter demonstrates ptychographic electron diffractive imaging at atomic resolution, permitting identification of structure in a boron nitride helical cone at a resolution of order 1 ?, beyond that of comparative Z-contrast images. A scanning transmission electron microscope is used to create a diverging illumination in a defocused Fresnel CDI geometry, providing a robust strategy leading to a unique solution. 相似文献
10.
Diaz F Lee MS Rejeaunier X Lehoucq G Goudail F Loiseaux B Bansropun S Rollin J Debes E Mils P 《Optics letters》2011,36(3):418-420
Imaging systems that combine a phase mask in the pupil and digital postprocessing may have better performance than conventional ones. We have built such a system to enhance the depth of field of an uncooled thermal camera. The phase masks are binary, their structures are optimized thanks to an image quality criterion, and they have been realized with three different technologies that give equivalent results. The deconvolution postprocessing is performed in real time with a graphics processing unit. A significant increase of the depth of field of a factor 3 has been obtained. 相似文献