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1.
We investigate the dynamics of the Λ system driven by two resonant laser fields in presence of dissipation for coupling strengths where the rotating‐wave approximation starts to break down. This regime is characterised by Rabi frequencies being approximately equal or smaller than the field frequencies. A systematic procedure to obtain an expansion for the solution of the Bloch evolution equations of the system is presented. The lowest contribution results to be the well‐known rotating‐wave approximation. The method is based on a semi‐classical treatment of the problem, and its predictions are interpreted fully quantum mechanically. The theory is illustrated by a detailed study of the disappearance of coherent population trapping as the intensities of the fields increase. 相似文献
2.
M. Castagnino R. Id Betan R. Laura 《International Journal of Theoretical Physics》2003,42(10):2423-2439
By extending the notion of mixed states to functionals acting on the space of observables with diagonal singularity we obtain a well-defined complex spectral decomposition of the time evolution for a quantum decaying system. In this formalism, generalized Gamow states are obtained with well-defined physical properties. 相似文献
3.
J. Saunier F. Alloin J. Y. Sanchez B. Barrire 《Journal of Polymer Science.Polymer Physics》2004,42(3):544-552
Some microporous poly(vinylidene fluoride) (PVdF) separators for lithium‐ion batteries, used in liquid organic electrolytes based on a mixture of carbonate solvents and lithium salt LiPF6, were characterized by the study of the swelling phenomena on dense PVdF membranes. Various aspects of the kinetics of the carbonate solvents and the solvent mixture sorption in dense PVdF slabs were studied at different temperatures. Non‐Fickian behavior, characterized by S‐shaped sorption curves, was highlighted, and a salt effect, which resulted in two‐stage sorption, was studied. Diffusion coefficients and activation energies were calculated for the Fickian portions of the sorption curves, that is, at short times and low swelling ratios. A strong influence of the different interaction parameters was shown for the swelling kinetics. This study proved that the swelling of microporous PVdF membranes could be considered instantaneous. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 544–552, 2004 相似文献
4.
J. Saunier F. Alloin J. Y. Sanchez L. Maniguet 《Journal of Polymer Science.Polymer Physics》2004,42(12):2308-2317
Microporous poly(vinylidene fluoride) (PVdF) separators for lithium-ion batteries, used in liquid organic electrolytes, have been characterized with respect to the swelling phenomena on dense PVdF membranes (obtained through hot pressing). In the first and second parts of this study, we have described the swelling equilibria and swelling kinetics of dense PVdF. Here the thermal properties of PVdF gels and their irreversible modifications induced by swelling are characterized. Particular attention is paid to crystallinity modifications, polymer plasticization, and membrane degradation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2308–2317, 2004 相似文献
5.
6.
This paper studies the problem of how changes in the design of the genetic algorithm (GA) have an effect on the results obtained in real-life applications. In this study, focused on the application of a GA to the tuning of technical trading rules in the context of financial markets, our tentative thesis is that the GA is robust with respect to design changes. The optimization of technical trading systems is a suitable area for the application of the GA metaheuristic, as the complexity of the problem grows exponentially as new technical rules are added to the system and as the answer time is crucial when applying the system to real-time data. Up to now, most of GAs applications to this subject obviated the question of possible “design dependence” in their results. The data we report, based on our experiments, do not allow us to refute the hypothesis of robustness of the GA to design implementation, when applying to technical trading systems tuning. 相似文献
7.
Laura Bader Nicola Durante Maska Law Guglielmo Lunardon Tim Penttila 《Designs, Codes and Cryptography》2003,29(1-3):41-50
We do the tentative beginnings of a study of BLT-sets of generalised quadrangles via their symmetries. In particular, the study of whorls about a line leads us to hyperbolic reflections preserving a BLT-set of Q(4, q). 相似文献
8.
9.
Laura Montanaro K. Belgacem P. Llewellyn F. Rouquerol F. Merlo Paola Palmero 《Journal of Thermal Analysis and Calorimetry》2007,88(3):789-793
Wet chemical synthesis of precursor oxide ceramics is a method to obtain small particulate powders. Such powders are far more
prone to ageing in air than more traditional precursors. Thermogravimetric analysis is used to highlight the species responsible
for the ageing of ceramic precursors. Indeed water and carbon dioxide are observed to evolve from aged powders. Ceramics obtained
from aged precursors can reach a very low final density with respect to the theoretical value. A large degree of the original
sintering properties can be recovered after washing the aged powders with ethanol in a basic medium. 相似文献
10.
Supply Chain Management (SCM) is an important activity in all producing facilities and in many organizations to enable vendors,
manufacturers and suppliers to interact gainfully and plan optimally their flow of goods and services. To realize this, a
dynamic modelling approach for characterizing supply chain activities is opportune, so as to plan efficiently the set of activities
over a distributed network in a formal and scientific way. The dynamical system will result so complex that it is not generally
possible to specify the functional forms and the parameters of interest, relating outputs to inputs, states and stochastic
terms by experiential specification methods. Thus the algorithm that will presented is Data Driven, determining simultaneously
the functional forms, the parameters and the optimal control policy from the data available for the supply chain. The aim
of this paper is to present this methodology, by considering dynamical aspects of the system, the presence of nonlinear relationships
and unbiased estimation procedures to quantify these relations, leading to a nonlinear and stochastic dynamical system representation
of the SCM problem. Moreover, the convergence of the algorithm will be proved and the satisfaction of the required statistical
conditions demonstrated. Thus SCM problems may be formulated as formal scientific procedures, with well defined algorithms
and a precise calculation sequence to determine the best alternative to enact. A “Certainty equivalent principle” will be
indicated to ensure that the effects of the inevitable uncertainties will not lead to indeterminate results, allowing the
formulation of demonstrably asymptotically optimal management plans. 相似文献