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1.
The extraction of Al(III) and Zn(II) from an aqueous solution with two water-in-oil microemulsions, one containing di(2-ethylhexyl)phosphoric acid (DEHPA), was investigated to aid the understanding of the role of the extractant and the metal specific characteristics in the mechanism of microemulsion extraction. The extraction of Al with the DEHPA microemulsion increased by a factor of about 10 with respect to that in the conventional DEHPA system, whereas the extraction of Zn was lower than that in the single DEHPA system. Extraction with the DEHPA-free microemulsion was very low, showing that metal ion solubilization was not important in the mechanism of microemulsion extraction. It is proposed that the effect of the mixed microemulsion on the metal distribution coefficient is the result of the balance between a decrease in the complexation reaction yield due to the interaction between butanol and DEHPA, and the adsorption of the metal complex at the macro- and microinterfaces. The former leads to a decrease in Zn(II) extraction and the latter to Al(III) extraction synergism. Copyright 2000 Academic Press. 相似文献
2.
The effect on the transmittance function in nonsymmetric gradient-index material due to a circular pupil is studied, and we characterize this material by its effective transmittance function. 相似文献
3.
For solvable roommate problems with strict preferences Diamantoudi et al. (Games Econ Behav 48: 18–28, 2004) show that for any unstable matching, there exists a finite sequence of successive myopic blocking pairs leading to a stable matching. In this paper, we define P-stable matchings associated with stable partitions and, by using a proposal-rejection procedure, generalize the previous result for the entire class of roommate problems. 相似文献
4.
In this work we obtain new properties connected with the number of conjugacy classes of elements of a finite group, through
the analysis of the numberr
G(gN) of conjugacy classes of elements ofG that intersect the cosetgN, whereN is a normal subgroup ofG andg any element ofG. The results obtained about this number are not only used in the general problem of classifying finite groups according to
the number of conjugacy classes, but they also allow us to improve and generalize known results relating to conjugacy classes
due to P. Hall, M. Cartwright, A. Mann, G. Sherman, A. Vera-López and L. Ortíz de Elguea. Examples are given which illustrate
our improvements.
This work has been supported by the University of the Basque Country. 相似文献
5.
对新概念指导下而设计的(La1-xSrx)2Cu1-xSnxO4超导体进行了119SnM(o)ssbauer谱研究.对不同掺杂量样品的系统研究表明,M(o)ssbauer谱实验结果进一步证实了Sn以Sn4+价态存在并占据Cu晶位,不存在占据La晶位的Sn2+离子. Sn4+离子附近的局域晶格畸变较小,但是随Sn掺杂量有增加趋势.在对La2CuO4母体进行Sr和Sn同时掺杂所引入的载流子对超导电性的影响存在新的机制.在新的额外氧机制下,讨论了Sn掺杂所导致的额外氧对超导电性的影响. 相似文献
6.
Fernández de Luis R Mesa JL Urtiaga MK Larrea ES Rojo T Arriortua MI 《Inorganic chemistry》2012,51(4):2130-2139
The hydrothermal treatment of Ni(NO(3))(2)·6H(2)O, NaVO(3), and Bpa (1,2-Di(pyridyl)ethane) (C(12)H(12)N(2)) at 120 °C during 3 days leads to green single crystals of the title compound. The single crystal X-ray diffraction reveals that [{Ni(3)(H(2)O)(3)(Bpa)(4)}(V(6)O(18))]·8H(2)O crystallizes in the monoclinic system, P2(1)/c space group, with a = 13.5536 (2), b = 19.0463 (2), c = 27.7435 (3) ?, β = 112.3880 (10)°, V = 6622(3) ?(3), with R1(obs) = 0.0558, wR2(obs) = 0.1359, for 10278 observed reflections. The complexity of the crystal structure is based on different points, as the existence of: both "gauche" and "trans" conformations of the organic ligand, the [V(12)O(36)](-12) cycles, formed by 12 corner-sharing VO(4) tetrahedra, and, finally, the combination of both three-dimensional metal-organic and inorganic substructures, giving rise to a self-catenated highly connected net. The crystallization water molecules are semi-encapsulated in the channels along the [100] direction, and their loss gives rise to a dynamical and reversible structural contraction. Moreover, after the removal of the crystallization water molecules, the compound exhibits a negative thermal behavior in the 85-155 °C temperature range, and irreversible structural transformation due to the loss of coordinated water molecules up to 200 °C. The IR and UV-vis spectra were determined for the as-synthesized sample, after the removal of crystallization water molecules and after the irreversible transformation due to the loss of coordinated water molecules. The thermal evolution of χ(m) was adjusted to a magnetic model considering an isotropic dimer plus two Ni(II) d(8) isolated octahedra. 相似文献
7.
Ni-GDC cermet tubes (~ 3 mm inside diameter, 0.3–0.4 mm wall thickness and ~ 100 mm in length) with different amounts of porosity have been prepared by sintering of NiO-Ce0.9Gd0.1O1.95 (NiO-GDC) nanopowders and further reduction. The NiO-GDC nanopowders were synthesized by chemical route and the different pore density was obtained by modifying the processing conditions (calcining and adjustment of carbonous remains).Ni-GDC cermets were obtained from the sintered NiO-GDC composites using reduction treatment at 700 °C for 3 h in reducing atmosphere (5 vol.% H2–95 vol.% Ar). After the reduction process, tubes with 25–32% porosity were obtained. Gas permeability and Hg porosimetry studies were used to evaluate permeability, pore distribution and pore density. Electrical conductivity studies of the cermets were also performed. 相似文献
8.
在航空航天领域,为了加速系统设计及测试进度,通常需要进行半实物实时仿真,即控制器用实物,受控对象采用数学模型。本文开发出了基于Matlab/Simulink的两相传热模块,并用其搭建了某机械泵驱动两相回路的实时动态模型。通过与实验的对比,验证了模型的可靠性,表明该模型满足实时要求,可以在下一步用于半实物仿真。 相似文献
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10.
J. J. Larrea D. R. Sanchez F. J. Litterst E. M. Baggio-Saitovitch 《Hyperfine Interactions》2005,161(1-4):237-246
57Fe Mössbauer spectroscopic studies of iron ludwigite Fe3O2BO3 performed between 4 and 450 K allow the discussion of magnetic spin arrangements and the dynamics of electronic configurations of iron. The observed magnetic transitions are related to charge ordering. 相似文献