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Amel Zitouni Abdelkrim Gouasmia Sabrina Bouguessa Lakhémici Kaboub Louiza Boudiba 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):1744-1754
A new series of tetrathiafulvalene (TTF) molecules with extended π-system was prepared by using a Wittig reaction to generate the TTF key. The process of deprotection-alkylation of thiolates provided access to a wide variety of molecules. The study of their reducing power was carried out by cyclic voltammetry. Charge transfer complexes have also been chemically prepared by using TCNQ as an electron acceptor; the electrical conductivity of their compressed powders shows insulator behavior. The IR spectra of the TCNQ salts were recorded and used to characterize and estimate the degree of charge transfer of these complexes. GRAPHICAL ABSTRACT 相似文献
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Lakhemici Kaboub Jean‐Marc Fabre Laure Vendier Jean‐Pierre Legros 《Acta Crystallographica. Section C, Structural Chemistry》2010,66(8):o429-o432
A new bis‐TTF donor (TTF is tetrathiafulvalene) containing a pyridine diester spacer, namely bis{2‐[(6,7‐tetramethylene‐3‐methylsulfanyltetrathiafulvalen‐2‐yl)sulfanyl]ethyl} pyridine‐2,6‐dicarboxylate–tetracyanoquinodimethane–dichloromethane (2/1/2), 2C33H33NO4S12·C12H4N4·2CH2Cl2, has been synthesized and its electron‐donating ability determined by cyclic voltammetry. The electrical conductivity and crystal structure of this donor–acceptor (DA) complex with TCNQ (tetracyanoquinodimethane) as the acceptor are presented. The TCNQ moiety lies across a crystallographic inversion centre. In the crystal structure, TTF and TCNQ entities are arranged in alternate stacks; this feature, together with the bond lengths of the TCNQ molecule, suggest that the expected charge transfer has not occurred and that the D and A entities are in the neutral state, in agreement with the poor conductivity of the material (σRT = 2 × 10−6 S cm−1). 相似文献
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We report the synthesis and properties of eight new tetrathiafulvalene (TTF) derivatives containing two different functionalities, prepared with the aim of obtaining stable organic materials. The four acetoxyphenyl- and four hydroxyphenyl TTFs were synthesized via Wittig-type condensations. The electrochemical properties of these redox-active molecules were studied by cyclic voltammetry. Charge transfer complexes with tetracyanoquinodimethane (TCNQ) were prepared by chemical redox reactions. The complexes have been proven to give conducting materials. The UV-VIS and IR spectra of the TCNQ salts were recorded and used to characterize and estimate the degree of charge transfer of these complexes. 相似文献
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Meriam Boumedjout Amel Bendjeddou Lakhmici Kaboub Abdelkrim Gouasmia Didier Villemin 《Phosphorus, sulfur, and silicon and the related elements》2016,191(6):891-897
A new series of bis-fused tetrathiafulvalene containing functional groups was synthesized. The synthesis was carried out by using routes involving cross coupling, reduction, and oxidation reactions. The identity of these new donors is confirmed by 1 H NMR spectroscopy, mass spectrometry, and elemental analysis. We have used the cyclic voltammetry in order to determine the character π-donors of these molecules and to verify the reversibility of the redox process involved. Molecular orbital diagram has been calculated using density-functional calculations. Charge transfer complexes with tetracyanoquinodimethane (TNQ) were prepared by chemical redox reactions. 相似文献
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Malfant I Rivasseau K Fraxedas J Faulmann C de Caro D Valade L Kaboub L Fabre JM Senocq F 《Journal of the American Chemical Society》2006,128(17):5612-5613
Metallic thin films of the single-component, neutral, molecular solid Ni(tmdt)2 have been prepared by electrocrystallization on passivated silicon substrates. Metallicity is achieved down to 6 K despite the polycrystalline morphology. 相似文献
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