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Introduction It is important to research the mixed-ligand copper complexes containing bioligands,such as amino acids, nucleic acids and proteins,in exploring the functional mechanism of microelement copper in organism because the reaction of any micronutrient with two or more bioligands in the concentrated bioligands background gives mixed-ligand ternary complexes, which are more stable[1]and related with storage of substance and transportation of metal ions in the life process. 相似文献
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CHEN Mu-juan ZHOU Song-gen LI Mei LEI Chun-yan XIAO Rui JIANG La-sheng 《高等学校化学研究》2013,29(6):1094-1097
Two charged donor-acceptor [2]catenanes were synthesized by the cyclization of the π-acceptor 1,1 '-[1, 4-phenylenebis-(methylene)]bis(4,4'-bipyridinium)bis(hexafluorophosphate)(2) and bis(bromomethyl)benzene with the templates of the π-donor phenylene-diacetylene crown ethers la and lb in the yields of 31%, 35%, respectively. The mass spectra, 1H and 13C NMR spectra confirm that the phenylene-diacetylene crown ethers, with a nonaromatic ~r-system, successfully template the cyclization of CBPQT4+. The X-ray crystallography analysis shows that the CBPQT4+ ring encircles around the phenylene motif of the crown ethers, leaving the 1,3-butadiyne fragment out of the cavity of CBPQT4+ ring. The mechanically interlocked structure of [2]catenanes was stabilized by the cooperative effects of π-stacking and hydrogen bonding interactions. 相似文献
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ZHOUXiao-hua LEXue-yi LONGLa-sheng CHENShi 《高等学校化学研究》2005,21(1):119-122
It is important to research the mixed-ligand copper complexes containing bioligands, such as amino acids, nucleic acids and proteins, in exploring the functional mechanism of microelement copper in organism because the reaction of any micronutrient with two or more bioligands in the concentrated bioligands background gives mixed-ligand ternary complexes, which are more stable and related with storage of substance and transportationof metal ions in the life process. 相似文献
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Yong-Kai Deng Ya-Rui Zhao Han Xu Prof. Dr. Xiang-Jian Kong Prof. Dr. La-sheng Long Prof. Dr. Lan-Sun Zheng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(2):614-617
Incorporating metal clusters within the skeleton of the organic polymers through a click reaction cannot only effectively prepare cluster–polymer composites, but also effectively avoid the cluster aggregation. Herein, an azide-containing lanthanide–titanium oxo cluster of Eu8Ti10-N3 ( Eu8Ti10-N3 =[Eu8Ti10(μ3-O)14(H2O)4(OAc)2(tbba)30(paza)4(THF)2] ⋅ 4 THF ⋅ 8 H2O ( 1 ), Htbba=4-tert-butylbenzoic acid, Hpaza=4-azidobenzoate, HOAc=acetic acid, THF=tetrahydrofuran) through an in situ solvothermal reaction of 4-azidobenzoic acid and 4-tert-butylbenzoic acid. Reaction of 1 with PEG ( PEG =methoxypoly(ethyleneglycol)alkyne, 2000 g mol−1) through CuI-catalyzed click chemistry generates a lanthanide–polymer composite of Eu8Ti10-N3@PEG ( 2 ). Investigation with IR, 1H NMR and ICP-OES of 2 indicates that the structural integrity of 1 is maintained in 2 . Study of the luminescent properties of 1 and 2 reveals that the quantum yield of 1 itself basically remains unchanged in 2 . Significantly, the formation of 2 cannot only effectively prevent the cluster 1 from aggregation, but also greatly enhance its solubility and adhesion to the substrate. Owing to the solubility and adhesion of luminescent materials being the key to their practical application, present work is thus of great significance for the development of metal cluster–polymer composite luminescent materials. 相似文献
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本文首先建立了实值非负函数关于集值序增函数的集值Riemann-Stieltjes积分,并讨论了集值Riemann-Stieltjes积分的性质,给出了集值Riemann-Stieltjes可积的充要条件,最后引入了集值Riemann-Stieltjes随机积分. 相似文献
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药用百合提取液对羟自由基清除作用的研究 总被引:4,自引:0,他引:4
在Fenton反应产生羟自由基的稳定体系中,以溴邻苯三酚红为显色剂,用分光光度法测定吸光度的变化值,研究百合提取液在此体系中清除羟自由基的作用。通过常见抗氧化剂对羟自由基清除作用的对照试验表明,百合提取液对羟自由基有较好的清除效果,此法操作简便,稳定性好,测定快速,为开发百合复方保健品提供理论依据。 相似文献
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本文研究了离散参数集值序下鞅的Riesz分解及收敛性.利用集值序关系及集值鞅方法,给出了离散参数集值序下鞅的Riesz分解的存在性及唯一性定理.并获得离散参数集值序下鞅的收敛性定理. 相似文献
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引入数值函数关于B-值函数的R-S积分,研究了此类积分的性质及向量值R-S积分存在的几个充分条件,并给出了积分的收敛定理. 相似文献
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引入向量值函数关于实值函数的Riemann-Stieltjes积分,给出了向量值Riemann-Stieltjes可积的充要条件,并讨论了积分的收敛定理. 相似文献