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1.
Eun-Ku Lee Kwang-Deog Jung Oh-Shim Joo Yong-Gun Shul 《Reaction Kinetics and Catalysis Letters》2004,83(1):25-30
The room temperature wet catalytic oxidation was conducted in a batch reactor with V/MgO catalyst. The XRD study of the catalyst
used indicated that V/MgO could not only oxidize H2S to sulfur selectively, but also prevent the sulfidation of metal oxide
effectively at the room temperature. The XPS study indicated that the H2S oxidation with V/MgO could proceed by a redox mechanism
(V5+↔ V4+) and that V3+ formation (V4+→ V3+), was responsible for the deactivation of V/MgO.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
2.
Mi-Hyun Lee Bhari Mallanna Nagaraja Prakash Natarajan Ngoc Thanh Truong Kwan Young Lee Sungho Yoon Kwang-Deog Jung 《Research on Chemical Intermediates》2016,42(1):123-140
PtSn/θ-Al2O3 catalysts with different amounts of K (0.14, 0.22, 0.49, 0.72, and 0.96 wt%) are prepared to investigate the K effects on the PtSn catalyst in propane dehydrogenation (PDH). KPtSn catalyst with 0.xx wt% K, 0.5 wt% Pt and 0.75 wt% Sn is designated as xx-KPtSn. PDH was performed at 873 K and a gas hourly space velocity (GHSV) of 53,000 mL/gcat h. The temperature-programmed desorption (NH3-TPD), temperature-programmed reduction (TPR) and CO chemisorption of the KPtSn catalysts with K added revealed the potassium addition blocked the acid sites, promoted the reduction of Sn oxide and decreased the Pt dispersion. The formations of cracking products and higher hydrocarbons on acid sites were suppressed by the K effect of blocking the acid sites. In contrast, K addition at more than 0.72 wt% rather increased cracking products and the amount of coke, resulting in the severe deactivation of catalysts. The high cracking products on the KPtSn catalysts with the high amount of K should not be related to the acid sites, because the acid sites were monotonously decreased with an increase in the amount of K. Instead, the potassium affected the characteristics of PtSn. The interaction between Pt and Sn could be weakened by enriching the reduced Sn, because the K component promoted the reduction of Sn oxide in the TPR experiments. Therefore, the 14-KPtSn catalyst with the low amount of K exhibits the highest stability and selectivity among the prepared KPtSn catalysts due to the compromise of the advantageous (blocking the acid sites) and bad (weakening the interaction between Pt and Sn) effects of the K addition in PDH. 相似文献
3.
The catalytic wet oxidation process is the most attractive process for small-scale hydrogen sulfide (H2S) removal from natural gas. The catalytic wet oxidation process is anticipated to be cost effective and simple so that it
can be used for treating sour gases containing small amounts of H2S and can be easily operated even in isolated sites. The development of effective catalyst is the key technology in the wet
catalytic oxidation of H2S. The scale of operation for the process has to be flexible so its use will not be limited by the flow rates of the gas to
be treated. The heterogeneous catalytic wet oxidation of H2S has been attempted on activated carbons, but the H2S removal capacity still shows the low removal efficiency. The catalytic wet oxidation of H2S was studied over Fe/MgO for an effective removal of H2S. In order to develop a sulfur removal technology, one has to know what surface species of catalyst are the most active.
This article discusses the following systematic studies: (i) the catalytic preparation to disperse Fe metal well on MgO support
for enhancing H2S removal capacity, (ii) the effect of the catalytic morphology on the activity of Fe/MgO for the H2S wet oxidation, (iii) the influence of precursor and support on the activity of Fe/MgO for catalytic wet oxidation of H2S to sulfur. 相似文献
4.
Eun-Ku Lee Kwang-Deog Jung Oh-Shim Joo Yong-Gun Shul 《Reaction Kinetics and Catalysis Letters》2004,82(2):241-246
Four different magnesium oxides were studied in the wet oxidation of H2S to sulfur. The H2S removal capacity of MgO in the catalytic wet oxidation strongly depends on the pore size distribution. The MgO with relatively
large pores (>100 ?) showed a high removal capacity of H2S. It is suggested that the large pore size favors H2S removal in the catalytic wet oxidation due to the limitation of diffusion.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
5.
Formation of cadmium hydroxide at room temperature onto glass substrates from an aqueous alkaline cadmium nitrate solution using a simple soft chemical method and its conversion to cadmium oxide (CdO) by thermal annealing treatment has been studied in this paper. The as-deposited film was given thermal annealing treatment in oxygen atmosphere at 450 °C for 2 h for conversion into cadmium oxide. The structural, surface morphological and optical studies were performed for as-deposited and the annealed films. The structural analyses revealed that as-deposited films consists of mixture of Cd(OH)2 and CdO, while annealed films exhibited crystalline CdO. From surface morphological studies, conversion of clusters to grains after annealing was observed. The band gap energy was changed from 3.21 to 2.58 eV after annealing treatment. The determination of elementals on surface composition of the core-shell nanoparticles of annealed films was carried out using X-ray photoelectron spectroscopy (XPS). 相似文献
6.
Eon-Young Lee Young-Kwon Park Oh-Shim Joo and Kwang-Deog Jung 《Reaction Kinetics and Catalysis Letters》2006,89(1):115-121
Summary The kinetic data of about 150 points for methanol dehydration were obtained at the temperature of 240~270oC, the GHSV of 25,000~120,000 (mL/gcat./h) and under atmospheric pressure. The data were fitted into six plausible equations. The kinetic equation derived from
the molecular adsorption of methanol on two sites fit the kinetic data best, however, that from the dissociative adsorption
of methanol could not be safely ruled out. The activation energy of 114.7 kJ/mol for methanol dehydration on γ-Al2O3 was obtained from the kinetic analysis. 相似文献
7.
Hyperfine Interactions - Al substituted CoAl x Fe1?x O4 (x=0.1, 0.2, 0.3, and 0.5) have been studied with X-ray and neutron diffraction, Mössbauer spectroscopy and magnetization... 相似文献
8.
Influence of copper precursors in the steam reforming of methanol over Cu/SnO2/SiO2 catalysts 总被引:1,自引:0,他引:1
Eun-Ku Lee Hyoung-Sik Kim Kwang-Deog Jung Oh-Shim Joo Yong-Gun Shul 《Reaction Kinetics and Catalysis Letters》2004,81(1):177-181
Cu/SnO2/SiO2 catalysts, prepared with three different copper precursors (copper nitrate, sulfate and chloride), were characterized and investigated for the steam reforming of methanol. Cu/SnO2/SiO2 catalyst, prepared with copper nitrate, showed the highest activity among the tested catalysts. The highest activity of the catalyst prepared with copper nitrate was ascribed to the highly dispersed Cu particles from CO adsorption experiment. The selectivity of methanol to H2 decreased with an increase in the amount of acid on the surface of Cu/SnO2/SiO2 catalysts from FT-IR experiments.This revised version was published online in December 2005 with corrections to the Cover Date. 相似文献
9.
Ji-Eun Lee Byung-Suk Jin Sung-Hoon Cho Sung-Hwan Han Oh-Shim Joo Kwang-Deog Jung 《Reaction Kinetics and Catalysis Letters》2005,85(1):65-71
Summary Degradation of humic acids by ozone was performed at room temperature in a stirred tank reactor with heterogeneous catalysts. Experimental results show that the ozonation with Fe/MgO induced a significant reduction in UV absorbance of humic acids, as compared to ozone alone. Fe/MgO was the most efficient catalyst in degradation humic acids in the presence of ozone. GPC (gel permeation chromatography) showed that humic acids with high molecular weight could be severely decomposed into organic compounds with low molecular weight by the Fe/MgO catalyst, indicating that humic acids could be catalytically decomposed. 相似文献
10.
Gul Rahman Ji yeon Lim Kwang-Deog Jung Oh-Shim Joo 《Electrochemistry communications》2010,12(10):1371-1374
Gold nanoparticles(AuNP) were electrodeposited on a glassy carbon(GC) which was electrochemically modified by potentiodynamic cyclic polarization in acidic medium. The AuNP deposits were characterized by scanning electron microscopy, cyclic voltammetry, chronoamperometry and linear sweep voltammetry. Results of these studies showed that very small sized AuNP are deposited with significantly high particle density which is attributed to the surface modification of GC. The resulted AuNP/GC electrode showed high catalytic activity for electrochemical reduction of NAD+ to NADH, indicating its potential for electrocatalytic applications. 相似文献