全文获取类型
收费全文 | 4848篇 |
免费 | 171篇 |
国内免费 | 44篇 |
专业分类
化学 | 3134篇 |
晶体学 | 75篇 |
力学 | 103篇 |
数学 | 708篇 |
物理学 | 1043篇 |
出版年
2023年 | 28篇 |
2022年 | 73篇 |
2021年 | 120篇 |
2020年 | 93篇 |
2019年 | 94篇 |
2018年 | 99篇 |
2017年 | 83篇 |
2016年 | 177篇 |
2015年 | 138篇 |
2014年 | 170篇 |
2013年 | 312篇 |
2012年 | 302篇 |
2011年 | 349篇 |
2010年 | 199篇 |
2009年 | 216篇 |
2008年 | 281篇 |
2007年 | 290篇 |
2006年 | 241篇 |
2005年 | 201篇 |
2004年 | 199篇 |
2003年 | 160篇 |
2002年 | 139篇 |
2001年 | 89篇 |
2000年 | 83篇 |
1999年 | 61篇 |
1998年 | 54篇 |
1997年 | 46篇 |
1996年 | 48篇 |
1995年 | 50篇 |
1994年 | 47篇 |
1993年 | 39篇 |
1992年 | 42篇 |
1991年 | 33篇 |
1990年 | 41篇 |
1989年 | 45篇 |
1988年 | 32篇 |
1987年 | 19篇 |
1986年 | 29篇 |
1985年 | 36篇 |
1984年 | 38篇 |
1983年 | 24篇 |
1982年 | 20篇 |
1981年 | 32篇 |
1980年 | 23篇 |
1979年 | 21篇 |
1978年 | 24篇 |
1977年 | 25篇 |
1976年 | 22篇 |
1975年 | 19篇 |
1974年 | 15篇 |
排序方式: 共有5063条查询结果,搜索用时 15 毫秒
1.
2.
Dr. Yogesh Kumar Maurya Dr. Pingchun Wei Takahide Shimada Dr. Kazuhisa Yamasumi Dr. Shigeki Mori Prof. Dr. Ko Furukawa Dr. Hajime Kusaba Prof. Dr. Tatsumi Ishihara Prof. Dr. Yongshu Xie Dr. Masatoshi Ishida Prof. Dr. Hiroyuki Furuta 《化学:亚洲杂志》2021,16(7):743-747
A facile synthetic strategy towards conformationally stable chiral chromophores based on dimeric porphyrinoids has been established. A peculiar class of face-to-face intramolecularly interlocked corrole dimers were formed by the oxidative C−C coupling linked at the inner carbon sites upon simple treatment of copper(II) ions. Their intrinsic electronic structures were modulated by the peripheral corrole ring annulations, which lead to distinct optical properties and redox profiles. The stereogenic carbon centers implemented in the confused corrole skeleton provided a rationale for designing novel chiral materials. 相似文献
3.
Prof. Piotr Bałczewski Dr. Emilia Kowalska Dr. Ewa Różycka-Sokołowska Dr. Joanna Skalik Dr. Krzysztof Owsianik Dr. Marek Koprowski Dr. Bernard Marciniak Dr. Dariusz Guziejewski Prof. Witold Ciesielski 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(62):14148-14161
The highly substituted mono-aryl/alkylthio-(hetero)acenes prepared in this study have been found to be thermally more stable (Tdecomp.=331–354 °C) than the known di-aryl/alkylthio-substituted acenes by an average of 25 °C. They are also much more photostable at 254 and 365 nm (in both argon and air) than the parent anthracene and other reported anthracenes. The most photostable aryl/alkylthio-anthracenes at 254 nm were found to be 60–70 (in air) and 130 (in argon) times more stable in solution than the unsubstituted anthracene, and much more stable than known EDG/EWG-substituted anthracenes (EDG=electron-donating group, EWG=electron-withdrawing group) with an extended aromatic core. Furthermore, the acenes showed significantly higher photostability at 365 nm in both air and argon. The anthracenes were obtained by the novel thio-Friedel–Crafts/Bradsher cyclization reaction of hitherto unknown [o-(1,3-dithian-2-yl)aryl](aryl)methyl thioethers. The developed approach provides a general access to mono-aryl/alkylthio-substituted (hetero)acene frameworks containing at least three fused (hetero)aromatic rings. The characteristic feature of this approach, which leads to highly substituted acenes, is that the substituents, unlike in other methods, may be introduced at an early stage of the synthesis. DFT and TD-DFT calculations confirmed the stabilizing role of the aryl/alkylthio substituent in the mono-aryl/alkylthio-substituted anthracenes, which are the most stable anthracenes prepared to date. Their high photostability is mainly due to the quenching of singlet oxygen by the acene and the quenching of the acene S1 state by molecular oxygen. 相似文献
4.
Summary Carbon deposits on the surface ofRu/Fe2O3 catalysts used in the water-gas shift reaction have been investigated by Auger Electron Spectrometry. A correlation has been
found between the thickness of the carbon deposit and the catalytic activity in WGSR. The carbon deposit covers the metallic
active centers and blocks their contact with reagents. The dotting of the iron oxide support with sodium has been found to
reduce the amount of carbon deposit. . 相似文献
5.
6.
Jem‐Kun Chen I‐Kuan Lin Fu‐Hsiang Ko Chih‐Feng Huang Kuo‐Shen Chen Chia‐Hao Chan Feng‐Chih Chang 《Journal of Polymer Science.Polymer Physics》2004,42(22):4063-4074
Polybenzoxazine (PBZZ) thin films can be fabricated by the plasma‐polymerization technique with, as the energy source, plasmas of argon, oxygen, or hydrogen atoms and ions. When benzoxazine (BZZ) films are polymerized through the use of high‐energy argon atoms, electronegative oxygen atoms, or excited hydrogen atoms, the PBZZ films that form possess different properties and morphologies in their surfaces. High‐energy argon atoms provide a thermodynamic factor to initiate the ring‐opening polymerization of BZZ and result in the polymer surface having a grid‐like structure. The ring‐opening polymerization of the BZZ film that is initiated by cationic species such as oxygen atoms in plasma, is propagated around nodule structures to form the PBZZ. The excited hydrogen atom plasma initiates both polymerization and decomposition reactions simultaneously in the BZZ film and results in the formation of a porous structure on the PBZZ surface. We evaluated the surface energies of the PBZZ films polymerized by the action of these three plasmas by measuring the contact angles of diiodomethane and water droplets. The surface roughness of the films range from 0.5 to 26 nm, depending on the type of carrier gas and the plasma‐polymerization time. By estimating changes in thickness, we found that the PBZZ film synthesized by the oxygen plasma‐polymerization process undergoes the slowest rate of etching in CF4 plasma. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4063–4074, 2004 相似文献
7.
Krzysztof Pawaowski 《K-Theory》1998,13(1):41-55
The paper presents a procedure for constructing smooth actions of finite perfect groups on spheres with fixed point sets having certain prescribed properties (Theorem A); in particular, having any prescribed configuration of Chern and Pontryagin numbers (Corollary C). The main ingredients used are equivariant thickening and equivariant surgery. 相似文献
8.
We study condensation of ethanol-hexanol vapour by numerical solution of kinetic equations. The number of droplets formed
in unit volume is computed within self-consistent classical model. It is shown that formation of ethanol-rich droplets prevails
at the initial stage of nucleation process, but in the stationary state formation of droplets near the saddle point (on cluster
formation energy surface) plays the dominant role.
Presented at the 6th Joint Seminar “Development of Materials Science in Research and Education”, Karlštejn, Czech Republic,
17–19 September 1996.
This work was supported by Grant No. A1010615 of the Grant Agency of the Academy of Sciences of the Czech Republic. 相似文献
9.
Lj. D. R. Kočinac 《Proceedings of the Steklov Institute of Mathematics》2006,252(1):122-137
Recent progress in selection principles theory is discussed and is illustrated mainly by the Hurewicz covering property and
its strong version, the Gerlits-Nagy property GN(*). Some results that have not been published elsewhere are given with proofs. 相似文献
10.
Hyperfine Interactions - The giant magnetoresistance (GMR) effect was an epoch-making discovery in the field of magnetic materials research. In this article, studies on magnetic multilayered... 相似文献