排序方式: 共有4条查询结果,搜索用时 15 毫秒
1
1.
2.
3.
Samsonova A. D. Krasnodubskaya S. V. Tyurin Yu. M. 《Russian Journal of Electrochemistry》2004,40(6):646-652
The kinetics of anodic dissolution of aluminum films electrodeposited on platinum via direct aluminum electrooxidation without preliminary discharge of electrolyte components is studied. The process probably involves adatoms and clusters Al* on the electrode surfaces, with limiting stage Al* – e (A1+)ads. 相似文献
4.
Tyurin Yu. M. Samsonova A. D. Panicheva G. A. Krasnodubskaya S. V. 《Russian Journal of Electrochemistry》2003,39(7):743-752
The dissolution kinetics of M* anodes (M* = Al, Cd, Sn, Sb, Bi) during electrolysis of molten complexes M[Al2Et6] (M = Na, K, Rb, Et4N; = F, Cl) is studied. Parallel dissolution paths are discovered: through a limiting discharge of electrolyte components and through a limiting electrooxidation of adatoms and clusters of M* present at the electrode surface. Substantiated is a mechanism of electrosynthesis of ethyl derivatives M*Et
n
involving the formation of adsorbed complexes (M*Et1 k n – 1)ads via the scheme AlEt4
– + M* – e M*(Et)ads + (AlEt3); M*(Et)ads + (AlEt4
–) – e = M*(Et2)ads + (AlEt3); ...; M*(Et
n – 1)ads + (AlEt4
–) – e AlEt3 + M*Et
n
. 相似文献
1