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1.
A simple and rapid procedure is proposed for the determination of chloride and free fluoride in tin electroplating fluid. Suppressor-column ion-chromatography is used after oxidation of hexafluorostannate(II) to hexafluorostannate(IV) with hydrogen peroxide. Concurrent determination of tin(II) and total tin then allows calculation of the concentrations of fluoride, hexafluorostannate(II) and hexafluorostannate(IV). 相似文献
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Mulder P Korth HG Pratt DA DiLabio GA Valgimigli L Pedulli GF Ingold KU 《The journal of physical chemistry. A》2005,109(11):2647-2655
The gas-phase O-H bond dissociation enthalpy, BDE, in phenol provides an essential benchmark for calibrating the O-H BDEs of other phenols, data which aids our understanding of the reactivities of phenols, such as their relevant antioxidant activities. In a recent review, the O-H BDE for phenol was presented as 90 +/- 3 kcal mol(-1) (Acc. Chem. Res. 2003, 36, 255-263). Due to the large margin of error, such a parameter cannot be used for dynamic interpretations nor can it be used as an anchor point in the development of more advanced computational models. We have reevaluated the existing experimental gas-phase data (thermolyses and ion chemistry). The large errors and variations in thermodynamic parameters associated with the gas-phase ion chemistry methods produce inconsistent results, but the thermolytic data has afforded a value of 87.0 +/- 0.5 kcal mol(-1). Next, the effect of solvent has been carefully scrutinized in four liquid-phase methods for measuring the O-H BDE in phenol: photoacoustic calorimetry, one-electron potential measurements, an electrochemical cycle, and radical equilibrium electron paramagnetic resonance (REqEPR). The enthalpic effect due to solvation, by, e.g., water, could be rigorously accounted for by means of an empirical model and the difference in hydrogen bond interactions of the solvent with phenol and the phenoxyl radical. For the REqEPR method, a second correction is required since the calibration standard, the O-H BDE in 2,4,6-tri-tert-butylphenol, had to be revised. From the gas-phase thermolysis data and three liquid-phase techniques (excluding the electrochemical cycle method), the present analysis yields a gas-phase BDE of 86.7 +/- 0.7 kcal mol(-1). The O-H BDE was also estimated by state-of-the-art computational approaches (G3, CBS-APNO, and CBS-QB3) providing a range from 86.4 to 87.7 kcal mol(-1). We therefore recommend that in the future, and until further refinement is possible, the gas-phase O-H BDE in phenol should be presented as 86.7 +/- 0.7 kcal mol(-1). 相似文献
3.
H. Budzikiewicz U. Schaller H. Korth G. Pulverer 《Monatshefte für Chemie / Chemical Monthly》1979,110(4):947-953
Alkyl and alkenyl quinolines (so-called Pyo-substances) and theirN-oxides were isolated fromPseudomonas aeruginosa. Structures proposed earlier could be confirmed; a new representative (Pyo V) is described.
IV. Mitt.:A. Römer, H. Budzikiewicz, H. Korth undG. Pulverer, Tetrahedron Letters1979, 509. 相似文献
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Mulder P Hemmink S De Heer MI Lupo M Santoro D Korth HG 《The Journal of organic chemistry》2001,66(20):6611-6619
In the presence of hydrogen donor solvents and at elevated temperatures, aromatic ketones can be selectively deoxygenated to the corresponding hydroaromatic compounds. The kinetics for reduction of 7H-benz[d,e]anthracen-7-one (benzanthrone, 6) into 7H-benz[d,e]anthracene (benzanthrene, 1) in 9,10-dihydroanthracene (3) solvent has been investigated in detail. The relatively slow hydrogenation of 6 is due to reversibility of the initial hydrogen-transfer step according to a reverse radical disproportionation (RRD). The dynamics could well be rationalized using the energetics of species computed by density functional theory (DFT). The application of hydrogen donors such as 1 as a hydrogen-transfer agent, although favorable in terms of a low benzylic carbon-hydrogen bond dissociation enthalpy, is limited due to the slow self-hydrogenation, which in case of 1 gives 5,6-dihydro-4H-benz[d,e]anthracene (7). 相似文献
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