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1.
I. V. Korobka A. I. Voloshina E. V. Kuznetsov 《Chemistry of Heterocyclic Compounds》1984,20(11):1214-1218
1-Methyl-2-benzopyrylium salts with a free position of the heteroring primarily form substituted chrysenes. In alkaline media this process does not proceed through the intermediate formation of 1,5-diketones.For Communication 26, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1472–1476, November, 1984. 相似文献
2.
E. P. Olekhnovich I. V. Korobka O. Ya. Borbulevych A. B. Larionov A. V. Chernoivanov O. V. Shishkin V. G. Arsen ev L. P. Olekhnovich 《Russian Chemical Bulletin》1998,47(11):2229-2233
1,3-Diethoxy-4,6-di(ethoxymethylene)-5,5-dimethylcyclohexenylium perchlorate (6a) was synthesized from 1,3-diethoxy-5,5-dimethylcyclohexenylium perchlorate by successive introduction of ethoxymethylene
groups. Perchlorate6a was also obtained from dimedone in one preparative step. Compound6a was studied by X-ray diffraction analysis. The bond lengths in the fragment containing the C(1)–C(4) and C(6) atoms of the
six-membered ring of the cation are substantially equalized and close to the Carom-Carom bond length. Apparently, this fact indicates that the positive charge is primarily delocalized over the aromatic system.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2300–2304, November, 1998. 相似文献
3.
I. V. Korobka I. V. Shcherbakova E. V. Kuznetsov 《Chemistry of Heterocyclic Compounds》1982,18(9):902-905
The behavior of 2-benzopyrylium salts with a CH2 group in the 1 position at pH 7 was studied, and it was established that they undergo recyclization to -naphthols under these conditions. A mechanism for the conversion is proposed. One of the intermediates, viz., 3-hydroxy-1-tetralone, was isolated.See [1] for communication 25.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1184–1187, September, 1982. 相似文献
4.
The influence of white and color noise on the outcome of the entanglement swapping process is investigated in a four-qubit system. Critical degree of noise in initial state, that could destroy entanglement in a result state is presented. The entanglement characteristics, such as concurrence, tangle, etc. are compared. Results could be helpful for experiments regarding entanglement swapping as conditions for initial quantum entangled states, to obtain entangled result state. 相似文献
5.
I. V. Korobka Yu. V. Revinskii E. V. Kuznetsov 《Chemistry of Heterocyclic Compounds》1985,21(7):754-758
It is shown that the conversion of 1-methyl-2-benzopyrilium salts into chrysenes in basic media occurs via an intermediate dimeric pseudobase. The properties of this have been examined, and mechanisms are proposed for its formation and conversion into chrysenes.For No. 27, see [1].Translated from Khimiya Geterotsiklichesklkh Soedinenii, No. 7, pp. 910–914, July, 1985. 相似文献
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7.
Yu. A. Zhdanov S. V. Verin I. V. Korobka E. V. Kuznetsov 《Chemistry of Heterocyclic Compounds》1988,24(9):974-978
The conversion of 2-benzopyrylium salts to benz [a] anthracenes, which proceeds through prior dimerization of a new type, was observed. An intermediate dimer was isolated, its properties were studied, and assumptions regarding the mechanisms of its formation and conversion to benz [a] anthracenes, cenes were expressed.See [1] for Communication 32.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1185–1189, September, 1988. 相似文献
8.
Bulgarevich S. B. Bren' D. V. Movshovich D. Ya. Filippov S. E. Olekhnovich E. P. Korobka I. V. 《Russian Journal of General Chemistry》2002,72(9):1446-1452
The conformations of some 2,4,6-triarylpyridines, 2-aryl-4-phenyl-6-tert-butylpyridines, and the corresponding pyridinium cations in dioxane and acetonitrile solutions were determined from the Cotton-Mouton effect. These systems are nonplanar; the angles by which the aryl substituents at positions 2 and 6 of the heteroring are turned relative to the heteroring plane are close to those observed in biphenyl and its p-substituted derivatives; these angles depend on substituents in the rings and, in the case of cations, at the pyridinium nitrogen atom. 相似文献
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10.
Olekhnovich E. P. Boroshko S. L. Korobka I. V. Metelitsa A. V. Olekhnovich L. P. 《Russian Journal of Organic Chemistry》2001,37(4):527-538
1,3-Diethoxy-2-R-5,5-R',R'-1-cyclohexenylium perchlorates in condensation with 2-hydroxyarylaldehydes under dehydration conditions give rise to 3-ethoxy-1,2-dihydroxanthylium perchlorates that with the second molecule of 2-hydroxyarylaldehyde afford 13H-chromeno[3,2-b]xanth-5-ylium perchlorates, and with primary and secondary amines yield 3-(R2,R3-amino)-1,2-dihydroxanthylium perchlorates. The condensation of 2-bromodimedone with salicylaldehydes in triethyl orthoformate and perchloric acid medium furnished 6-bromo-13,13-dimethyl-13H-chromeno[3,2-b]xanth-5-ylium perchlorates. The latter compounds show strong fluorescence in 530-630 nm region with 0.48-0.98 quantum efficiency. Under similar conditions the dimedone and 2-acetyldimedone afford with 2-hydroxyarylaldehydes tris-condensation products: 2,10-dimethoxy-6-(3-methoxy-6-oxo-2,4-cyclohexadienylidenemethyl)-7,7-dimethyl-7H-chromeno[2,3-a]-xanth-13-ylium perchlorate and 2,10-dimethoxy-6-(6-methoxychromylium-2-yl)-13,13-dimethyl-13H-chromeno[3,2-b]xanth-5-ylium diperchlorate respectively. 相似文献