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1.
Graham R. Knox Peter L. Pauson Debra Willison 《Journal of organometallic chemistry》1993,450(1-2):177-184
Phenylazoferrocene undergoes nickelation and palladation exclusively on the phenyl group. Lithium phenylazocyclopentadienide has been converted into derivatives of Mo, Mn, Fe, Ru and Rh. 相似文献
2.
We evaluate the financial performance of most of the branch offices of a large European savings bank for a recent accounting
period. We employ a complementary pair of nonparametric techniques to evaluate their financial performance, in terms of their
ability to conserve on the expenses they incur in building their customer bases and providing customer services. We find variation
in the ability of branch offices to perform this task, and agreement on the identity of the laggard branches. We then employ
parametric techniques to determine that the list of indicators on which their financial performance is evaluated can be reduced
without statistically significant loss of information to bank management. Both findings suggest ways in which the bank can
increase the profitability of its branch network.
A previous version of this paper was presented at CORE, Université Catholique de Louvain, Louvain-la-Neuve, Belgium, where
we received many helpful comments from the audience. We are grateful to three referees for their helpful comments as well. 相似文献
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J. H. Knox 《Chromatographia》1988,26(1):329-337
Summary Four Capillary Electroseparation methods are distinguished. All have an ultimate efficiency limited only by axial diffusion and are in principle capable of achieving 106 plates in <1 hour.The main limitation to performance arises from Ohmic heating of the electrolyte. While forced convection at 10ms–1 is recommended to keep tubes cool, the parabolic temperature profile within the electrolyte limits the tube bore which can be used. A simple limiting expression is derived: (dc/m)3 (E/kV m–1)3 (c/mol dm–3) <3.3×109.Values of constants underlined 相似文献
5.
Exposure of ent-kaura-2,16-dien-19-ol (1) or its succinate (2) to resuspended mycelia of G. fujikuroi has produced a complex mixture of acids which after methylation gave the esters of two C19 (24) and (30) and five C20 gibberellins (4, 11, 20, 32 and 33). The triester (32) and the lactone ester (24) have been prepared before from the esters of gibberellin A13 (8) and gibberellin A4 (26) respectively. The structures of the other metabolites were assigned on spectroscopic data and by chemical transformations. Thus the lactone diester (4) has been converted to the known keto triester (6). The epoxide (11) has been related to gibberellin A14 (14) and the aldehyde (33) has been related to gibberellin A13 trimethyl ester (8) by way of the triol (34). Selective de-epoxidation of the 16,17-epoxy function in diepoxides has provided a route from the dienes (20 and 24) to the epoxides (11 and 30) respectively, but not from the ester of gibberellin A5 (23) to that of gibberellin A6 (29). On the other hand the latter can be obtained by epoxidation of gibberellin A5 methyl ester trifluoroacetate. Backfeeding experiments carried out with the epoxy diacid (12), the diene diacid (21) and the derived diol (39) indicate pathways connecting the various metabolites. The natural gibberellins A5 and A6 were shown to be formed in some of the backfeeding experiments. 相似文献
6.
S L Logunov P P Knox N I Zakharova B N Korvatovsky V Z Paschenko A A Kononenko 《Journal of photochemistry and photobiology. B, Biology》1990,5(1):41-47
Using picosecond absorption spectroscopy it has been shown that in Rhodobacter sphaeroides reaction centres the substitution of the primary quinone acceptor (QA), ubiquinone-10, by other quinone species (with redox potentials higher or lower than that of ubiquinone-10) has essentially no modifying effect on the reaction centre protein. The molecular relaxation processes that accompany the localization and stabilization of a photo-excited electron on the intermediate acceptor, bacteriopheophytin (I), are not affected, although the subsequent transfer of the electron from I to QA is slowed down. Consequently, this leads to a lower quantum efficiency of high rate of direct I-----QA reaction is normally due to the specificity of the primary quinone species and its binding site in the reaction centre protein which provide optimum steric and chemical conditions for an effective interaction between I and QA. 相似文献
7.
Measurements of dipole strengths of chlorophylls in solution are reviewed and correlated. The refractive index dependence is found to be expressible in a simple empirical fashion that does not rely on the concept of vacuum dipole strength. The index dependence in some respects contradicts the dependence expected on the basis of effective field theories. 相似文献
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