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Zaharescu M. Jitianu A. Brăileanu A. Madarász J. Novák CS. Pokol G. 《Journal of Thermal Analysis and Calorimetry》2003,71(2):421-428
Hybrid materials with different amounts of organics permanently bound on the inorganic network obtained in the TEOS-MTEOS
(tetraethoxysilan-methyltriethoxysilan) system are used for obtaining coatings with different optical and mechanical properties.
To study the thermal stability of the mentioned materials, compositions with different molar ratios of the precursors were
prepared. The influence of the solvent and water amounts on the gelation process was also investigated. The gels obtained
were characterised by IR spectrometry and their decomposition temperatures were determined by DTA/TG. Thermal stability of
the gels is rather influenced by their composition than the conditions of the gelation process.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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J. Somlai B. Kanyár R. Bodnár CS. Németh Z. Lendvai 《Journal of Radioanalytical and Nuclear Chemistry》1996,207(2):437-443
A significant dose contribution on the population could be derived from coal slags used as isolation material. Extremely high natural activities are measured in the coal slag, derived from the region of the settlement Ajka, Hungary. In some buildings monitored, the elevated -doses were nearly 5–10 times higher than the world average ones. The annual average indoor radon concentrations from the slag exceeded 400 Bq/m3 and in some cases up to 1200 Bq/m3. Due to the elevated exposure and the radon concentrations in the dwellings the annual dose was estimated to 8–24 mSv/y more than 5–10 times of the world average one. 相似文献
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A. GARAY S. DEMETER K. KOVÁCS G. HORVÁTH ÁGNES FALUDI-DÁNIEL 《Photochemistry and photobiology》1972,16(2):139-144
Abstract— Circular dichroism (CD) spectra were studied in System I particles prepared by digitonin fragmentation of chloroplasts of normal maize and carotenoid-deficient mutants. CD bands of pigment molecules were found to be higher in particles than in solutions. This phenomenon was most pronounced for the particles containing the carotenoid composition of normal chloroplast lamellae. The CD signal of chlorophylls bound to particles of carotenoid-deficient chloroplasts was closer to that found in solutions. This indicates that aggregation and/or binding of chlorophylls in carotenoid-deficient mutants may be less extensive than in normal chloroplasts. 相似文献
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Mono‐, di‐ and trimethylated homologues of isoprenoid tetraether lipid cores in archaea and environmental samples: mass spectrometric identification and significance
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Chris Knappy Daniela Barillà James Chong Dominic Hodgson Hugh Morgan Muhammad Suleman Christine Tan Peng Yao Brendan Keely 《Journal of mass spectrometry : JMS》2015,50(12):1420-1432
Higher homologues of widely reported C86 isoprenoid diglycerol tetraether lipid cores, containing 0–6 cyclopentyl rings, have been identified in (hyper)thermophilic archaea, representing up to 21% of total tetraether lipids in the cells. Liquid chromatography‐tandem mass spectrometry confirms that the additional carbon atoms in the C87‐88 homologues are located in the etherified chains. Structures identified include dialkyl and monoalkyl (‘H‐shaped’) tetraethers containing C40‐42 or C81‐82 hydrocarbons, respectively, many representing novel compounds. Gas chromatography‐mass spectrometric analysis of hydrocarbons released from the lipid cores by ether cleavage suggests that the C40 chains are biphytanes and the C41 chains 13‐methylbiphytanes. Multiple isomers, having different chain combinations, were recognised among the dialkyl lipids. Methylated tetraethers are produced by Methanothermobacter thermautotrophicus in varying proportions depending on growth conditions, suggesting that methylation may be an adaptive mechanism to regulate cellular function. The detection of methylated lipids in Pyrobaculum sp. AQ1.S2 and Sulfolobus acidocaldarius represents the first reported occurrences in Crenarchaeota. Soils and aquatic sediments from geographically distinct mesotemperate environments that were screened for homologues contained monomethylated tetraethers, with di‐ and trimethylated structures being detected occasionally. The structural diversity and range of occurrences of the C87‐89 tetraethers highlight their potential as complementary biomarkers for archaea in natural environments. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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The distance function \({\varrho(p, q) ({\rm or} d(p, q))}\) of a distance space (general metric space) is not differentiable in general. We investigate such distance spaces over \({\mathbb{R}^n}\), whose distance functions are differentiable like in case of Finsler spaces. These spaces have several good properties, yet they are not Finsler spaces (which are special distance spaces). They are situated between general metric spaces (distance spaces) and Finsler spaces. We will investigate such curves of differentiable distance spaces, which possess the same properties as geodesics do in Finsler spaces. So these curves can be considered as forerunners of Finsler geodesics. They are in greater plenitude than Finsler geodesics, but they become geodesics in a Finsler space. We show some properties of these curves, as well as some relations between differentiable distance spaces and Finsler spaces. We arrive to these curves and to our results by using distance spheres, and using no variational calculus. We often apply direct geometric considerations. 相似文献
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The equationbelongs to the class of linear functional equations. The solutions form a linear space with respect to the usual pointwise operations. According to the classical results of the theory they must be generalized polynomials. New investigations have been started a few years ago. They clarified that the existence of non-trivial solutions depends on the algebraic properties of some related families of parameters. The problem is to find the necessary and sufficient conditions for the existence of non-trivial solutions in terms of these kinds of properties. One of the earliest results is due to Z. Daróczy [1]. It can be considered as the solution of the problem in case of n = 2. We are going to take more steps forward by solving the problem in case of n = 3.
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$$\sum^{n}_ {i=0} a_{i}f(b_{i}x + (1 - b_{i})y) = 0$$
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Atmospheric pressure chemical ionization liquid chromatography-tandem mass spectrometry (APCI LC-MS/MS) of tetraether lipid cores of archaeal origin reveals distinct dissociation pathways for three classes of core lipid extracted from Methanobacter thermautotrophicus. Within these classes, two isobaric tetraether lipids, one a scarcely reported lipid constituent of M. thermautotrophicus and the other an artefact formed during extraction from cultured cells, were identified and distinguished via their MS(2) spectra. APCI LC-MS/MS discriminates different tetraether core lipid types and isobaric species and reveals the mass of the constituent biphytanyl chains within the tetraether cores, albeit without full elucidation of their structures. Furthermore, the method allows direct estimation of the relative proportions of tetraether core lipids from chromatographic peak area measurement, allowing rapid profiling of these compounds in microbiological and environmental extracts. 相似文献
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The behaviour ofS-matrix for potentials generating bound states in continuum in the neighbourhood of the positive bound state energies is studied.
It is shown that unlike the case of usual negative energy bound states, theS-matrix does not have a pole at the positive bound state energy but becomes unity at the energy corresponding to bound states
in continuum. Calculations ofS-waveS-matrix for a local potential constructed by Stillinger and Herrick and a separable nonlocal potential constructed by the
present authors verify these results. Our results indicate that the bound states embedded in continuum constructedvia the von Neumann and Wigner procedure cannot be interpreted as resonances with zero width. 相似文献