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D. Rosmann K. -W. Klinkhammer A. Schmidt 《Monatshefte für Chemie / Chemical Monthly》1996,127(5):461-468
Zusammenfassung Arsen-tris(2,2-dimethylpropionat) (1) kristallisiert monoklin in der Raumgruppe P21/n mita=926.2,b=2158.6,c=983.7 pm, =94.92° undZ=4. As hat gegenüber O die Koordinationszahl 3+3. Antimontripropionat (2) kristallisiert monoklin in der Raumgruppe P21/c mita=930.2,b=863.0,c=1575.2 pm, =90.27 undZ=4. Die Moleküle sind intermolekular zu Ketten verknüpft, wodurch Sb die Koordinationszahl 3+3 (+3) erreicht.
Structure of arsen(III) and antimony(III) carboxylates
Summary Arsen-tris(2,2-dimethylpropionate) (1) crystallizes monoclinic in the space group P21/n witha=926.2,b=2158.6,c=983.7 pm, =94.92°, andZ=4. As has a coordination number of 3+3. Antimony tripropionate (2) crystallizes monoclinic in the space group P21/c witha=930.2,b=863.0,c=1575.2 pm, =90.27, andZ=4. The molecules are bridged to chains; therefore, Sb reaches the coordination number 3+3 (+3).相似文献
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(CH3)2SBr2 – Reactions and Structures (CH3)2SBr2 ( 1 ) is a donor acceptor complex (8-S-3 + 10-Br-2) which reacts with (CH3)2S(?O)NSi(CH3)3 to yield [(CH3)2S(O)?N? S(CH3)2]+Br? ( 2 ). With SbBr3 (CH3)2SBr+SbBr4? ( 3 ) can be isolated. 1 crystallizes monoclinic in the space group P21/c with a = 733.8, b = 734.2, c = 1132.7 pm, β = 92.8° and Z = 4. 2 crystallizes in the orthorhombic space group Pnma with a = 967.2, b = 793.3, c = 1168.3 pm and Z = 4. The SBr and BrBr force constants of 1 are compared with those of S2Br2, 3 and Br2 resp. The nmr and mass spectra of 1 and 2 are communicated. 相似文献
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F. Schaller W. Schwarz H.-D. Hausen K. W. Klinkhammer J. Weidlein 《无机化学与普通化学杂志》1997,623(9):1455-1466
Base-free Tris(trimethylsilyl)methyl Derivatives of Lithium, Aluminium, Gallium, and Indium Base-free LiR* (R*=-C(SiMe3)3) has been prepared from R*Cl and Li-metal in toluene at 85?90°C and used to synthesize the metallanes R*MMe2 with M = Al, Ga and In, respectively. The NMR (1H, 13C, 29Si) and the vibrational spectra of these trisyl compounds have been discussed. AlCl3 and LiR*(ratio 1 : 1) forms the metallate metallate Li[R*AlCl3]. The triclinic unit cell (space group P1 ) consists of a centrosymmetric assoziate, formed by four Li[R*AlCl3]- units with Al? Cl…?Li bridges, two pairs of Li-atoms differing in their chlorine-coordination and two disordered toluene molecules, inserted in the crystal lattice (R1wR2 =0,0444/0,1072). The reaction of GaCl3 with LiR* (I :1) gives the unusual sesquichloride (R*Ga(Cl1,33)Me0,67)3 in moderate yield. The X-ray structure determination shows a Ga3Cl3-skeleton with chairconformation and disordered, terminal gallium ligands (R1/wR2= 0,0646/0,2270). 相似文献
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A method is described for the determination of ten rare earth elements (La, Ce, Nd, Sm, Eu, Gd, Dy, Er, Yb, Lu) in natural waters by isotope-dilution mass spectrometry. A 1-l sample is used for sea water, and proportionately less for other natural waters. The rare earth elements are extracted by co-precipitation with hydrated iron (III) oxide and purified on a single cation-exchange column, with hydrochloric and nitric acids as eluents. Final measurements are from a triple Re/ Ta filament in the mass spectrometer, run automatically under computer control. Relative standard deviations are better than 4% for the analysis of standard solutions, with accuracy in the same range. The analytical blank is low ( <0.03 pmol, 4 pg, for Nd) producing a sample/blank concentration ratio greater than 100 for all ten rare earth elements when determined in a 1-l seawater sample. Concentration depth profiles are given for an ocean water and normalised abundance patterns for three natural waters. 相似文献
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Monolayers of 2-docosylamino-5-nitropyridine (DCANP) at the air/water interface were investigated by UV/Vis spectroscopy. The combination of this method with the classic constant-area relaxation technique yields insight into the longtime stability and the collapse behavior of monolayers. We have demonstrated that monolayers of DCANP are certainly stable under standard deposition conditions. At surface pressures above 20 mN/m monolayer instabilities lead to the formation of a three-dimensional head-to-head multilayered structure. 相似文献
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