排序方式: 共有49条查询结果,搜索用时 296 毫秒
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制备了甘氨酸-壳聚糖复合膜修饰玻碳电极(Gly-CTS/GCE),研究了抗坏血酸(AA)和尿酸(UA)在该修饰电极上的电化学行为。结果表明在pH=5.59的磷酸盐缓冲溶液中,AA、UA在Gly-CTS/GCE上均产生灵敏的不可逆氧化峰,其峰电流与浓度在一定范围内呈良好的线性关系。对AA和UA混合溶液平行测定7次,相对标准偏差分别为4.6%、2.9%,表明该电极重现性和稳定性良好。AA、UA在Gly-CTS/GCE电极上的氧化峰峰电位相差340mV,据此可实现对二者的同时检测,并可应用于实际样品测定。 相似文献
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We measured ratios of van der Waals potential coefficients (C3) for different atoms (Li, Na, K, and Rb) interacting with the same surface by studying atom diffraction from a nanograting. These measurements are a sensitive test of atomic structure calculations because C3 ratios are strongly influenced by core electrons and only weakly influenced by the permittivity and geometry of the surface. Our measurement uncertainty of 2% in the ratio C(3)(K)/C(3)(Na) is close to the uncertainty of the best theoretical predictions, and some of these predictions are inconsistent with our measurement. 相似文献
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C70X2(X=H,F, Cl)的稳定性和电子光谱 总被引:1,自引:0,他引:1
用INDO方法研究C70H2四种异构体的稳定性, 表明其最稳定异构体为1, 9-C70H2和7, 8-C70H2, 两者能量差为16.3KJ.mol^-^1, 与实验值及ab initio计算值接近; 光谱计算表明, 其特征吸收峰与实验值一致。在此基础上预测C70F2和C70Cl2的稳定性和电子光谱, 表明C70F2四种异构体的稳定性顺序与C70H2一致, 而C70Cl2则以21, 42-异构体最为稳定。二者的电子光谱与C70H2极其相似只是在500nm以上有细微差别。 相似文献
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Hans-Joachim Knlker Helmut Goesmann Rüdiger Klauss 《Angewandte Chemie (International ed. in English)》1999,38(5):702-705
The photochemical exchange of all three carbonyl ligands with acetonitrile converts tricarbonyliron–diene complexes into the very labile triacetonitrile-iron–diene complexes. These easily demetalate in high yields to the corresponding free ligands on injection of air at −30°C [Eq. (1)]. The novel demetalation procedure is applied to the tricarbonyliron complexes of cyclopentadienones, cyclohexa-1,3-dienes, and buta-1,3-dienes. 相似文献
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Ulrike Kant Tobias Klauss Jürgen Voigt Matthias Weber 《Journal of Evolution Equations》2009,9(4):637-659
We treat the time evolution of states on a finite directed graph, with singular diffusion on the edges of the graph and glueing
conditions at the vertices. The operator driving the evolution is obtained by the method of quadratic forms on a suitable
Hilbert space. Using the Beurling–Deny criteria we describe glueing conditions leading to positive and to submarkovian semigroups,
respectively. 相似文献
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Klauss H.-H. Baabe D. Mienert D. Birke M. Luetkens H. Litterst F. J. Hücker M. Büchner B. Cheong S. W. 《Hyperfine Interactions》2001,136(3-8):711-715
We report zero field μSR experiments on the lanthanum nickelate La2−x
Sr
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NiO4+δ system with strontium doping level x between 0 and 0.6. In a single crystal with x=0.33 the internal field distribution shows two separated signals reflecting the antiferromagnetic domains and the non magnetic
antiphase domain walls in the spin and charge ordered state below 190 K. Below 70 K a broadening of the low field line is
observed. A similar behavior is observed in polycrystalline samples with 0.2≤x≤0.5.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献
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