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Georg Schwedt Dirk-Oliver Waldheim Klaus-Dietrich Neumann Kathrin Stein 《Fresenius' Journal of Analytical Chemistry》1993,346(6-9):659-662
Summary A method for metal speciation using an enzyme reactor is described. The enzyme urease is immobilized on a polymer support. The parameters of the inhibition procedure are investigated for the determination of copper in drinking and surface water samples. The results are compared with those obtained by atomic absorption spectrometry. It has been found that the enzyme urease was inhibited only by free copper ions.Dedicated to Professor Dr. Wilhelm Fresenius on the occasion of his 80th birthday 相似文献
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Immo Söllner Benjamin Gschösser Patrick Mai Benedikt Pressl Zoltán Vörös Gregor Weihs 《Foundations of Physics》2012,42(6):742-751
We present a new experimental approach using a three-path interferometer and find a tighter empirical upper bound on possible
violations of Born’s Rule. A deviation from Born’s rule would result in multi-order interference. Among the potential systematic
errors that could lead to an apparent violation we specifically study the nonlinear response of our detectors and present
ways to calibrate this error in order to obtain an even better bound. 相似文献
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Reaction Products of Chloromethoxiphosphines and Antimony (V) Chloride. Vibrational Spectra of the 1:1-adducts of Methoxiphosphoryl Compounds and Antimony (V) Chloride Chloromethoxiphosphines react with antimony(V) chloride in a redox process to yield the chloromethoxiphospllonium hexachloroantimonates(V) (CH3O)3PCl2+SbCl6? (II) and CH3OPCl3+SbCl6? (III). II, III, (CH3O)3PCl+SbCl6?(1) and (CH3O)4P+SbCl6? eliminate easily methyl chloride and give the addition compounds OP(OCH3)3·SbCl5(IV), OPCl(OCH3)2 · SbCl5 (V), OPCl2(OCH3)·SbCl5 (VI) and OPCl3·SbCl5 (VII). The vibrational spectra of IV, V nnd VI are discussed. 相似文献
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Adducts of Phosphoryl Compounds and SbCl5 Preparation and IR Spectra of 1:1 Addition Compounds from Chlorodimethylamino- resp. Chlorodimethylaminomethoxiphosphoryl Compounds and Antimony(V) Chloride The addition compounds (CH3O)2[(CH3)2N]PO · SbCl5 ( II ), (CH3O)[(CH3)2N]2PO · SbCl5 ( III ), [(CH3)2N]3PO · SbCl5 ( IV ), Cl2[(CH3)2N]PO · SbCl5 ( VI ), Cl[(CH3)2N]2PO · SbCl5 ( VII ), and Cl(CH3O)[(CH3)2N]PO · SbCl5 ( VIII ) are prepared by reaction of the phosphoryl compounds with antimony(V) chloride. The influence of the Lewis acid to the bonds of the phosphoryl compounds is discussed. The 31P-n.m.r. data of the adducts are communicated and compared with those of the free phosphoryl compounds. 相似文献
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The Vibrational Spectra of Dimethylamino Methoxiphosphoryl Compounds The vibrational spectra of the known compounds (CH3O)2[(CH3)2N]PO ( II ), (CH3O)[(CH3)2N]2PO ( III ), and (CH3O)[(CH3)2N]ClPO ( VI ) are communicated and assigned. The chemical shift of P atoms is listed. 相似文献
6.
Kolk A Pautke C Wiener E Schott V Wolff KD Horch HH Rummeny EJ 《Magnetic resonance imaging》2008,26(8):1167-1174
Objective
The cause of enophthalmos as a late complication after orbital reconstruction is poorly investigated. Multislice CT (MSCT) is usually employed for its assessment, in spite of limitations regarding soft tissue depiction/imaging, as well as the implication of radiation and production of artifacts. Magnetic resonance imaging (MRI) has been shown to be a valuable alternative. The aim of this study was to establish a bony and soft tissue orbital volume calculation method based on different high-resolution MRI sequences compared to MSCT.Materials and Methods
Thirty-seven patients were included in this prospective study investigating the origin of enophthalmos present 3–4 months after complex orbital reconstruction. Morphological and dimensional changes of the orbit, eye globes, extraocular muscles and fat content were investigated 3–4 months after surgery. To assess the site and size of bony and soft tissue changes in the traumatized orbits, we used MSCT and MR images as well as corresponding 3-D reconstructions.Results
All enophthalmic orbits revealed a significant bony volume increase compared to the contralateral side as well as a reduced sagittal eye projection. Mean orbital volume enlargements of 1.0 cm3 lead to 0.93 mm enophthalmos (P<.05). Hardly any fatty atrophy could be depicted by the different MRI techniques.Conclusions
For soft tissue depiction of the orbit, MRI was superior to MSCT. Particularly, proton density weighting proved to be the best sequence for soft tissue volume segmentation, allowing determination of the cause and degree of posttraumatic enophthalmos in reconstructed orbits. 相似文献
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