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Pu Duan Bo Zhi Luke Coburn Christy L. Haynes Klaus Schmidt-Rohr 《Magnetic resonance in chemistry : MRC》2020,58(11):1130-1138
The composition of fluorescent polymer nanoparticles, commonly referred to as carbon dots, synthesized by microwave-assisted reaction of citric acid and ethylenediamine was investigated by 13C, 13C{1H}, 1H─13C, 13C{14N}, and 15N solid-state nuclear magnetic resonance (NMR) experiments. 13C NMR with spectral editing provided no evidence for significant condensed aromatic or diamondoid carbon phases. 15N NMR showed that the nanoparticle matrix has been polymerized by amide and some imide formation. Five small, resolved 13C NMR peaks, including an unusual ═CH signal at 84 ppm (1H chemical shift of 5.8 ppm) and ═CN2 at 155 ppm, and two distinctive 15N NMR resonances near 80 and 160 ppm proved the presence of 5-oxo-1,2,3,5-tetrahydroimidazo[1,2-a]pyridine-7-carboxylic acid (IPCA) or its derivatives. This molecular fluorophore with conjugated double bonds, formed by a double cyclization reaction of citric acid and ethylenediamine as first shown by Y. Song, B. Yang, and coworkers in 2015, accounts for the fluorescence of the carbon dots. Cross-peaks in a 1H─13C HETCOR spectrum with brief 1H spin diffusion proved that IPCA is finely dispersed in the polyamide matrix. From quantitative 13C and 15N NMR spectra, a high concentration (18 ± 2 wt%) of IPCA in the carbon dots was determined. A pronounced gradient in 13C chemical-shift perturbations and peak widths, with the broadest lines near the COO group of IPCA, indicated at least partial transformation of the carboxylic acid of IPCA by amide or ester formation. 相似文献
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C. A. Laue D. Gates-Anderson T. E. Fitch 《Journal of Radioanalytical and Nuclear Chemistry》2004,261(3):709-717
This review focuses on dissolution/reaction systems capable of treating uranium metal waste to remove its pyrophoric properties.
The primary emphasis is the review of literature describing analytical and production-scale dissolution methods applied to
either uranium metal or uranium alloys. A brief summary of uranium's corrosion behavior is included since the corrosion resistance
of metals and alloys affects their dissolution behavior. Based on this review, dissolution systems were recommended for subsequent
screening studies designed to identify the best system to treat depleted uranium metal wastes at Lawrence Livermore National
Laboratory (LLNL).
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Klaus Altmann 《Semigroup Forum》1996,53(1):89-97
We introduce an invariant for semigroups with cancellation property. When the semigroup equals the set of lattice points in
a rational, polyhedral cone, then this invariant describes the torsion of the differential sheaf on the associated toric variety.
Finally, as an example, we present the case of two-dimensional cones (corresponding to two-dimensional cyclic quotient singularities). 相似文献
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