排序方式: 共有73条查询结果,搜索用时 15 毫秒
1.
V. A. Popov S. I. Lopatin L. Sh. Tsemekhman L. A. Pavlinova S. P. Kormilitsyn V. V. Barsegyan 《Russian Journal of Applied Chemistry》2003,76(10):1564-1567
Evaporation of chromium ore and concentrates was studied using high-temperature differential mass-spectrometry. The data obtained, concerning the component vapor pressures in evaporation of complex oxide systems in the range 1700-2100 K, can be used to calculate the evaporation loss in melting and to assess the possibility of utilization of the sublimates formed. 相似文献
2.
Zhivka J. Simeonova Kiril B. Gavazov Alexander V. Alexandrov 《Central European Journal of Chemistry》2006,4(2):258-265
The formation of a new ternary ion-associate complex of vanadium(V) with 2,3-dihydroxynaphthalene and iodonitrotetrazolium
chloride with a composition ratio of 1:2:1 is reported. The complex is quantitatively extracted from water into chloroform.
The molar absorptivity (ɛ) of the extract at λ
max=340 nm is 2.5 × 104 dm3/mol cm, and Beer’s law is obeyed for concentrations ranging from 0.1 to 0.9 μg/cm3 V(V). The following constants are determined: the extraction constant, the association constant, the distribution constant,
and the recovery factor. The effects of foreign ions and reagents are studied. A selective and sensitive method is developed
for determination of vanadium in steels. 相似文献
3.
Dmitri S. Kilin Kiril Tsemekhman Oleg V. Prezhdo Eduard I. Zenkevich Christian von Borczyskowski 《Journal of photochemistry and photobiology. A, Chemistry》2007,190(2-3):342-351
The observed resonance energy transfer in nanoassemblies of CdSe/ZnS quantum dots and pyridyl-substituted free-base porphyrin molecules [Zenkevich et al., J. Phys. Chem. B 109 (2005) 8679] is studied computationally by ab initio electronic structure and quantum dynamics approaches. The system harvests light in a broad energy range and can transfer the excitation from the dot through the porphyrin to oxygen, generating singlet oxygen for medical applications. The geometric structure, electronic energies, and transition dipole moments are derived by density functional theory and are utilized for calculating the Förster coupling between the excitons residing on the quantum dot and the porphyrin. The direction and rate of the irreversible exciton transfer is determined by the initial photoexcitation of the dot, the dot–porphyrin coupling and the interaction to the electronic subsystem with the vibrational environment. The simulated electronic structure and dynamics are in good agreement with the experimental data and provide real-time atomistic details of the energy transfer mechanism. 相似文献
4.
Kiril Kolikov Dragia Ivanov Georgi Krastev Yordan Epitropov Stefan Bozhkov 《Journal of Electrostatics》2012,70(1):91-96
In the paper we consider the problem of the electrostatic interaction between two charged conducting spheres with arbitrary electrical charges and radiuses. Using the image charges method we determine exact analytical formulas for the force F and for the potential energy W of the interaction between these two spheres as well as for the potential V of the electromagnetic field in an arbitrary point created by them. Our formulas lead to Coulomb’s law for point charges.We theoretically prove the experimentally shown fact that two spheres with the same type (positive or negative) of charges can also attract each other. 相似文献
5.
Physicochemical and adsorption properties of hypercross‐linked polystyrene with ultimate cross‐linking density
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Maria P. Tsyurupa Zinaida K. Blinnikova Yuri A. Borisov Mikhail M. Ilyin Tamara P. Klimova Kiril V. Mitsen Vadim A. Davankov 《Journal of separation science》2014,37(7):803-810
The paper describes unexpected properties of hypercross‐linked polystyrenes with ultimate cross‐linking degrees of 300, 400, and 500%, where three, four, or five methylene links, respectively, could bind each polystyrene phenyl ring to its spacious neighbors. The polymers exhibit a strong electron spin resonance signal, unusual spectra in IR, UV, and visible ranges, and they are not typical dielectrics. The nonfunctionalized hypercross‐linked polymers absorb significant amounts of inorganic acids, salts, and bases due to interactions of protons or other cations with electron‐donating fragments of the aromatic network with the high extent of mutual connectivity and also due to dispersion interactions of anions with the polymer matrix. 相似文献
6.
In this work a class of nondissipative curves in Hilbert spaces whose correlation functions have a limit ast± is presented. These curves correspond to a class
of nondissipative basic operators that are a coupling of a dissipative operator and an antidissipative one. The wave operators and the scattering operator for the couple (A
*, A) (
) are obtained. The present work is a continuation and a generalization of the investigations of K.Kirchev and V.Zolotarev [1, 2, 3] on the model representations of curves in Hilbert spaces where the respective semigroup generator is a dissipative operator. This article includes four parts. A new form of the triangular model of M.S. Livic ([4, 5]) for the considered operators is introduced in the first part by the help of a suitable representation of the selfadjoint operatorL. This allows us to describe the studied class of nondissipative curves. The second part studies some results concerning the application of the analogue for multiplicative integrals of the well-known Privalov's theorem ([6]) about the limit values in the scalar case. This analogue is a reconstruction of measure by limit values in Stieltjes-Perron's style and it is obtained by L.A. Sakhnovich ([7]). Another problem, considered in the second part is the analogue inC
m
of the classical gamma-function and several properties for further consideration. In the third part the asymptotics of the studied curves corresponding to the nondissipative operators-couplings of a dissipative and an antidissipative operator with absolutely continuous real spectra and the limits of their correlation functions are obtained In the fourth part a scattering theory of a couple (A
*, A) with a nondissipative operatorA from
is constructed as in the selfadjoint case ([8, 9, 10]) and in the dissipative case ([7]). These results show an interesting new effect: the studied nondissipative case is near to the dissipative one.Partially supported by Grant MM-810/98 of MESC 相似文献
7.
Kiril Datchev 《Geometric And Functional Analysis》2014,24(3):740-747
We give an elementary proof of Burq’s resolvent bounds for long range semiclassical Schrödinger operators. Globally, the resolvent norm grows exponentially in the inverse semiclassical parameter, and near infinity it grows linearly. We also weaken the regularity assumptions on the potential. 相似文献
8.
Sigrid Blömeke Lynn Paine Richard T. Houang Feng-Jui Hsieh William H. Schmidt M. Teresa Tatto Kiril Bankov Tenoch Cedilllo Leland Cogan Shin Il Han Marcella Santillan John Schwille 《ZDM》2008,40(5):749-762
The study "Mathematics Teaching in the 21st Century (MT21)" focuses beyond others on the measurement of teachers’ general pedagogical knowledge (GPK). GPK is regarded as a latent construct embedded in a larger theory of teachers’ professional competence. It is laid out how GPK was defined and operationalized. As part of an international comparison GPK was measured with several complex vignettes. In the present paper, the results of future mathematics teachers’ knowledge from four countries (Germany, South Korea, Taiwan, and the US) with very different teacher-education systems are presented. Significant and relevant differences between the four countries as well as between future teachers at the beginning and at the end of teacher education were found. The results are discussed with reference to cultural discourses about teacher education. 相似文献
9.
Eric J. Bylaska Kiril Tsemekhman Scott B. Baden John H. Weare Hannes Jonsson 《Journal of computational chemistry》2011,32(1):54-69
Semi‐local functionals commonly used in density functional theory (DFT) studies of solids usually fail to reproduce localized states such as trapped holes, polarons, excitons, and solitons. This failure is ascribed to self‐interaction which creates a Coulomb barrier to localization. Pragmatic approaches in which the exchange correlation functionals are augmented with small amount of exact exchange (hybrid‐DFT, e.g., B3LYP and PBE0) have shown to promise in rectifying this type of failure, as well as producing more accurate band gaps and reaction barriers. The evaluation of exact exchange is challenging for large, solid state systems with periodic boundary conditions, especially when plane‐wave basis sets are used. We have developed parallel algorithms for implementing exact exchange into pseudopotential plane‐wave DFT program and we have implemented them in the NWChem program package. The technique developed can readily be employed in Γ‐point plane‐wave DFT programs. Furthermore, atomic forces and stresses are straightforward to implement, making it applicable to both confined and extended systems, as well as to Car‐Parrinello ab initio molecular dynamic simulations. This method has been applied to several systems for which conventional DFT methods do not work well, including calculations for band gaps in oxides and the electronic structure of a charge trapped state in the Fe(II) containing mica, annite. © 2010 Wiley Periodicals, Inc. J Comput Chem, 2010 相似文献
10.
Conversion of organosulfur components (COS and CS2) in catalytic processing of a real reduced sulfurous gas was experimentally studied. 相似文献