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It is shown that as far as the linear diffusion equation meets both time- and space-translational invariance, the time dependence of a moment of degree α is a polynomial of degree at most equal to α, while all connected moments are at most linear functions of time. As a special case, the variance is an at most linear function of time.  相似文献   
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A simple, highly sensitive, accurate and selective method for the determination of trace amounts of Ni2+ ions in water samples is proposed. The method is based on the separation and preconcentration of Ni2+ on an octadecyl-bonded silica (ODBS) membrane disk modified by a recently synthesized Schiff’s base N,N′-bis (3-methylsalicylidene) ortho phenylene diamine (MSOPD) at pH 7. The synthesis of this extractant ligand is also described. The retained nickel on the membrane was eluted with 2×5 ml 0.5 M HNO3 and measured by flame atomic absorption spectrometry (FAAS) at 232.0 nm. The extraction efficiency and the influence of the type and least amount of eluent for the stripping of Ni2+ from the disks, pH, flow rates of sample solution and eluent, amount of MSOPD, effect of other ions, and breakthrough volume were evaluated. The maximum capacity of the membrane disks modified by 3 mg of MSOPD was found to be 146±4 μg Ni2+. The 3σ limit of detection of the method was 30 ng per 1000 ml and also an enrichment factor of 250 was obtained. The proposed method has been applied to the determination of nickel in several water samples with satisfactory results.  相似文献   
4.
Multi-species reaction-diffusion systems, with nearest-neighbor interaction on a one-dimensional lattice are considered. Necessary and sufficient constraints on the interaction rates are obtained, that guarantee the closedness of the time evolution equation for E n(t)'s, the expectation value of the product of certain linear combination of the number operators on n consecutive sites at time t. The constraints are solved for the single-species left-right-symmetric systems. Also, examples of multi-species system for which the evolution equations of E n(t)'s are closed, are given. Received 25 September 2002 / Received in final form 3 December 2002 Published online 14 February 2003 RID="a" ID="a"e-mail: mamwad@iasbs.ac.ir  相似文献   
5.
The most general reaction-diffusion model on a Cayley tree with nearest-neighbor interactions is introduced, which can be solved exactly through the empty-interval method. The stationary solutions of such models, as well as their dynamics, are discussed. Concerning the dynamics, the spectrum of the evolution Hamiltonian is found and shown to be discrete, hence there is a finite relaxation time in the evolution of the system towards its stationary state.  相似文献   
6.
This article reviews some of the applications of physics to the solution of archaeological problems. The use of magnetic, resistivity and electromagnetic surveying techniques for the location of buried features is described. Various methods of age determination are outlined while the problems associated with radiocarbon dating of organic material and thermoluminescent dating of pottery are discussed in detail. The techniques, including petrological examination, chemical analysis and isotopic analysis, employed in the physical examination of archaeological artefacts are described. Examples of the application of these techniques in establishing the source of the raw materials used in pottery, metal and stone implements and in elucidating the techniques of manufacture of pottery and metal objects are also given.  相似文献   
7.
The large-N behavior of Yang–Mills and generalized Yang–Mills theories in the double-scaling limit is investigated. By the double-scaling limit, it is meant that the area of the manifold on which the theory is defined, is itself a function of N. It is shown that phase transitions of different orders occur, depending on the functional dependence of the area on N. The finite-size scalings of the system are also investigated. Specifically, the dependence of the dominant representation on A, for large but finite N is determined.  相似文献   
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By using the path integral method, we calculate the Green functions of the field strength of Yang-Mills theories on arbitrary nonorientable surfaces in Schwinger-Fock gauge.We show that the non-gauge invariant correlators consist of a free part and an almost x-independent part. We also show that the gauge invariant n-point functions are those corresponding to the free part, as in the case of orientable surfaces.  相似文献   
10.
Journal of Analytical Chemistry - A highly efficient solid-phase extraction (SPE) column filled with a silica-based strong anion exchange sorbent was reported in the current study. The fabricated...  相似文献   
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