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1.
Caesium carbonate supported on hydroxyapatite‐encapsulated Ni0.5Zn0.5Fe2O4 nanocrystallites as a novel magnetically basic catalyst for the one‐pot synthesis of pyrazolo[1,2‐b]phthalazine‐5,10‐diones
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Behrooz Maleki Samaneh Barat Nam Chalaki Samaneh Sedigh Ashrafi Esmail Rezaee Seresht Farid Moeinpour Amir Khojastehnezhad Reza Tayebee 《应用有机金属化学》2015,29(5):290-295
A novel nanomagnetic basic catalyst of caesium carbonate supported on hydroxyapatite‐coated Ni0.5Zn0.5Fe2O4 magnetic nanoparticles (Ni0.5Zn0.5Fe2O4@HAP‐Cs2CO3) was prepared. This new catalyst was fully characterized using Fourier transform infrared spectroscopy, transmission and scanning electron microscopy, X‐ray diffraction and vibrating sample magnetometry techniques, and then the catalytic activity of this catalyst was investigated in the synthesis of 1H‐pyrazolo[1,2‐b]phthalazine‐5,10‐dione derivatives. Also, Ni0.5Zn0.5Fe2O4@HAP‐Cs2CO3 could be reused at least five times without significant loss of activity and could be recovered easily by applying an external magnet. Thus, the developed nanomagnetic catalyst is potentially useful for the green and economic production of organic compounds. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
2.
The regiochemistry of 1,3-dipolar cycloaddition reactions of C-phenyl carbamoyl-N-phenyl nitrone with some dialkyl-substituted 2-benzylidenecyclopropane-1,1-dicarboxylates as dipolarophile was investigated using density functional theory-based reactivity indexes and activation energy calculations at B3LYP/6-31G(d) level of theory. Analysis of the geometries and bond orders at the TS structures associated with the different reaction pathways shows that these 1,3-dipolar cycloaddition reactions occur via an asynchronous concerted mechanism. Analysis of the local electrophilicity and nucleophilicity indexes based on Parr functions only for reaction between 1 + 2a and based on Fukui functions only for 1 + 2b gives correct regioselectivity. The theoretical results obtained in the work clearly predict the regiochemistry of the isolated cycloadducts and agree to experimental results. 相似文献
3.
Hossein Eshghi Ali Javid Amir Khojastehnezhad Farid Moeinpour Fatemeh F. Bamoharram Mehdi Bakavoli Masoud Mirzaei 《催化学报》2015,(3)
A novel magnetic acidic catalyst comprising Preyssler (H14[NaP5W30O110]) heteropoly acid support‐ed on silica coated nickel ferrite nanoparticles (NiFe2O4@SiO2) was prepared. The catalyst was character... 相似文献
4.
Silica gel-supported polyphosphoric acid(PPA-SiO2) was found to be an efficient catalyst for the one-pot four-component Hantzsch condensation reaction of aryl aldehydes,dimedone,ethyl acetoacetate and ammonium acetate to afford the corresponding polyhydroquinoline derivatives in high yields.The main advantages of the present approach are short reaction times,clean reaction profiles,simple experimental and workup procedures. 相似文献
5.
Amir Khojastehnezhad Abolghasem Davoodnia Mehdi Bakavoli Niloofar Tavakoli‐Hoseini Mohsen Zeinali‐Dastmalbaf 《中国化学》2011,29(2):297-302
A simple, efficient and green method for the synthesis of 14‐aryl‐14H‐dibenzo[a,j]xanthenes by a one‐pot condensation reaction of β‐naphthol and aryl aldehydes using silica gel‐supported polyphosphoric acid (PPA/SiO2), an effective and reusable catalyst, under solvent‐free conditions is described. The present methodology offers several advantages, such as a simple procedure with an easy work‐up, short reaction times, high yields, and the absence of any volatile and hazardous organic solvents. 相似文献
6.
Amir Khojastehnezhad Hossein Eshghi Farid Moeinpour Arastou Raoufi 《Journal of the Iranian Chemical Society》2016,13(9):1629-1634
The mechanism (regioselectivity) of [3+2] cycloaddition reaction of indan-1-one enamines (1ad–1ce) with aryl nitrile oxide (2) has been investigated by density functional theory-based reactivity indices and activation energy calculations at B3LYP/6-31G(d) level of theory in the gas phase. Thermodynamic and kinetic parameters of the possible 3-regio/4-regio regioisomeric pathways have been determined. In all cases, the 3-regio pathways are more favorable compared to the 4-regio alternatives. Our results show that these cycloadditions follow an asynchronous one-step mechanism with a nonpolar character. Theoretical data are in good agreement with the experimental results. 相似文献
7.
Amir Khojastehnezhad Hossein Eshghi Farid Moeinpour Mehdi Bakavoli Mohammad Izadyar Javad Tajabadi 《Structural chemistry》2016,27(4):1041-1047
The mechanism (regio- and stereoselectivity) of 1,3-dipolar cycloaddition (1,3-DC) of 2-ethylthio-4-phenyl-1-azetin 1 with benzonitrile oxide 2a, 2-aminobenzonitrile oxide 2b and 2-azidobenzonitrile oxide 2c has been investigated by density functional theory-based reactivity indices and activation energy calculations at B3LYP/6-31G(d,p) level of theory in the gas and solvent phase. Thermodynamic and kinetic parameters of the possible ortho/meta regioisomeric and endo/exo stereoisomeric pathways have been determined. In order to rationalize complete endo selective fashion provided by these 1,3-DC cycloadditions, a natural steric analysis between NLMOs i,j for TS1ox and TS1on and also a second-order interaction energy, E 2, analysis between the donor–acceptor orbitals in these TSs were carried out. In all cases, the ortho pathways are more favorable compared to the meta alternatives and it is found that the endo pathway is preferred. Our results show that these cycloadditions follow an asynchronous one-step mechanism with a nonpolar character. Theoretical data are in good agreement with the experimental results. 相似文献
8.
Farzaneh Tajfirooz Abolghasem Davoodnia Mehdi Pordel Mahmoud Ebrahimi Amir Khojastehnezhad 《应用有机金属化学》2018,32(1)
New functionalized magnetic core–shell nanoparticles, CuFe2O4@SiO2‐OP2O5H, were prepared by grafting of phosphorus pentoxide on CuFe2O4@SiO2 nanoparticles and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, energy‐dispersive X‐ray analysis, inductively coupled plasma optical emission spectrometry and vibrating sample magnetometry. The catalytic activity of CuFe2O4@SiO2‐OP2O5H as a novel catalyst was evaluated in the synthesis of 1,8‐dioxo‐octahydroxanthenes under solvent‐free conditions. The results showed that the catalyst has high activity and the desired products are obtained in high yields within short reaction times. The catalyst is readily recovered using magnetic decantation and can be used at least four times without noticeable deterioration in catalytic activity. 相似文献
9.
Marziyeh Rohaniyan Abolghasem Davoodnia S. Ali Beyramabadi Amir Khojastehnezhad 《应用有机金属化学》2019,33(5)
New Schiff base (SB) functionalized graphene oxide (GO) nanosheets containing phosphomolybdic counter‐anion H2PMo12O40¯ (H2PMo) were successfully prepared by grafting of 3‐aminopropyltriethoxysilane (APTS) on GO nanosheets followed by condensation with benzil and finally reaction with phosphomolybdic acid (H3PMo12O40, denoted as H3PMo) and characterized using Fourier transform infrared (FT‐IR) spectroscopy, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), particle size distribution, energy‐dispersive X‐ray (EDX) analysis, EDX elemental mapping, and inductively coupled plasma optical emission spectrometry (ICP‐OES). The prepared new nanomaterial, denoted as GO‐SB‐H2PMo, was shown to be an efficient heterogeneous catalyst in one‐pot, three‐component reaction of β‐naphthol, aldehydes, and dimedone, giving high yields of tetrahydrobenzo[a]xanthene‐11‐ones within short reaction times. The catalyst is readily recovered by simple filtration and can be recycled and reused several times with no significant loss of catalytic activity. 相似文献
10.
A covalently cross‐linked graphene oxide (GO) as a catalyst was prepared by a cross‐linking process using the nucleophilic reaction of zirconium (IV)‐coordinated 5,10,15,20‐tetrakis (aminophenyl)porphyrin (ZrPPh) with carboxyl groups of the edges of GO (GO‐ZrPPh). The chemical structure of catalyst was characterized by different analyses such as FT‐IR, SEM, TEM, EDS, ICP, TGA and UV. All analyses confirm the occurrence of successfully covalent immobilization of ZrPPh on the GO. Also, TEM and SEM images show that ZrPPh has been immobilized in the both of the edges and the basal plane of GO. The activity of the catalyst was studied for the synthesis of 3,4‐dihydropyrimidin‐2(1H)‐ones via Biginelli reaction. The cross‐linked catalyst is able to catalyze the reaction in short reaction times and good to excellent yields. 相似文献