首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1910篇
  免费   130篇
  国内免费   107篇
化学   1248篇
晶体学   38篇
力学   67篇
综合类   4篇
数学   245篇
物理学   545篇
  2023年   25篇
  2022年   38篇
  2021年   45篇
  2020年   36篇
  2019年   41篇
  2018年   48篇
  2017年   49篇
  2016年   43篇
  2015年   61篇
  2014年   82篇
  2013年   110篇
  2012年   123篇
  2011年   145篇
  2010年   93篇
  2009年   67篇
  2008年   114篇
  2007年   108篇
  2006年   117篇
  2005年   89篇
  2004年   100篇
  2003年   68篇
  2002年   57篇
  2001年   35篇
  2000年   34篇
  1999年   27篇
  1998年   16篇
  1997年   26篇
  1996年   23篇
  1995年   21篇
  1994年   24篇
  1993年   10篇
  1992年   18篇
  1991年   13篇
  1990年   14篇
  1989年   11篇
  1988年   8篇
  1986年   10篇
  1985年   13篇
  1984年   17篇
  1983年   9篇
  1982年   16篇
  1981年   12篇
  1980年   25篇
  1979年   10篇
  1978年   10篇
  1977年   16篇
  1976年   10篇
  1975年   11篇
  1974年   10篇
  1973年   9篇
排序方式: 共有2147条查询结果,搜索用时 15 毫秒
1.
2.
Satz 41 in Hasse's monograph [4] is modified because of the incorrectness of Satz 29. We investigate unit indices of imaginary abelian number fields of type (2,2) and (2,2, 2), some of which give counterexamples to Satz 41. We moreover give a relation between unit indices of certain imaginary fields of type (2,22) and those of their real cyclic subfields.  相似文献   
3.
Let d, k and n be three integers with k3, d4k−1 and n3k. We show that if d(x)+d(y)d for each pair of nonadjacent vertices x and y of a graph G of order n, then G contains k vertex-disjoint cycles converting at least min{d,n} vertices of G.  相似文献   
4.
In this paper we first give a lower bound on multiplicities for Buchsbaum homogeneous k-algebras A in terms of the dimension d, the codimension c, the initial degree q, and the length of the local cohomology modules of A. Next, we introduce the notion of Buchsbaum k-algebras with minimal multiplicity of degree q, and give several characterizations for those rings. In particular, we will show that those algebras have linear free resolutions. Further, we will give many examples of those algebras.  相似文献   
5.
6.
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007  相似文献   
7.
Model and empirical study on some collaboration networks   总被引:8,自引:0,他引:8  
In this paper we present an empirical study of a few practical systems described by cooperation networks, and propose a model to understand the results obtained. We study four non-social systems, which are the Bus Route Networks of Beijing and Yangzhou, the Travel Route Network of China, Huai-Yang recipes of Chinese cooked food, and a social system, which is the Collaboration Network of Hollywood Actors. In order to explain the results related to the degree distribution, act-degree distribution and act-size distribution (especially about the degree distribution, which may be better fitted using a stretched exponential distribution (SED)), we suggest a simple model to show a possible evolutionary mechanism for the emergence of such networks. The analytic and numerical results obtained from the model are in good agreement with the empirical results.  相似文献   
8.
In this paper we discuss the approximation of life distributions by exponential ones. The main results are: (1) F NBUE, where its mean is 1, we have , 0, where = 1 - 2/2, 2 being the second moment ofF. The inequality is sharp. (2) In the case ofFIFR, the upper bound is . (3) For the HNBUE class, the upper bound is min . Furthermore, the improved upper bound is . In addition, we show 0} |\bar G(t) - e^{ - t} | \leqslant \sqrt {\frac{\rho }{2}} $$ " align="middle" border="0"> , where (4) For the IMRL class, the upper bound is /(1+) ([1]). Here we give a simple proof.Project supported by the National Natural Science Fund of China.  相似文献   
9.
10.
The interactions of serum albumins such as human serum albumin (HSA) and bovine serum albumin (BSA) with emodin, rhein, aloe-emodin and aloin were assessed employing fluorescence quenching and absorption spectroscopic techniques. The results obtained revealed that there are relatively strong binding affinity for the four anthraquinones with HSA and BSA and the binding constants for the interactions of anthraquinones with HSA or BSA at 20 degrees C were obtained. Anthraquinone-albumin interactions were studied at different temperatures and in the presence of some metal ions. And the competition binding of anthraquinones with serum albumins was also discussed. The Stern-Volmer curves suggested that the quenching occurring in the reactions was the static quenching process. The binding distances and transfer efficiencies for each binding reactions were calculated according to the F?ster theory of non-radiation energy transfer. Using thermodynamic equations, the main action forces of these reactions were also obtained. The reasons of the different binding affinities for different anthraquinone-albumin reactions were probed from the point of view of molecular structures.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号