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排序方式: 共有1193条查询结果,搜索用时 15 毫秒
1.
Hisatoyo Morinaga Natsumi Ogawa Mayu Sakamoto Hiroshi Morikawa 《Journal of polymer science. Part A, Polymer chemistry》2019,57(24):2466-2473
The thiol‐ene reaction between trans‐limonene oxide (trans‐LO) and ethane‐1,2‐dithiol in the presence of triethylborane affords a bio‐based bis‐functional epoxide (bis‐trans‐LO). The crosslinking reaction of bis‐trans‐LO with branched polyethyleneimine (BPEI; Mn = 600; BPEI600) at a feed ratio of bis‐trans‐LO/BPEI600 = 57/43 (wt/wt) yields the corresponding network polymer with Td10 (10% thermal decomposition temperature) of 304.7 °C in 98% yield. In contrast, negligible amounts of network polymer are obtained by the reaction of bis‐LO (bis‐functional epoxide derived from cis and trans‐LO) and BPEI600 regardless of the feed ratio. The mechanical strengths as measured by direct tensile tests of the network polymers derived from bis‐trans‐LO and BPEI600,1800 (Mn = 600 and 1800) were approximately 16 and 11 times higher than that of bis‐LO and BPEI1800, respectively. The tensile shear strengths of the metal‐to‐metal adhesive bonds induced by bis‐trans‐LO and BPEI600,1800 were 9.5 and 14.1 MPa, respectively. DMA revealed that the storage modulus of the network polymer derived from bis‐trans‐LO and BPEI1800 in the rubber region was higher than that of the material prepared from bis‐LO and BPEI1800, indicating higher crosslink density of the bis‐trans‐LO/BPEI1800 system. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 2466–2473 相似文献
2.
方永得 张玉虎 M.Oshima Y.Toh 周小红 M.Koizumi A.Osa A.Kimura Y.Hatsukawa T.Morikawa M.Nakamura M.Sugawara H.Kusakari 《中国物理 C》2006,30(2):99-104
利用在束γ谱学实验技术, 通过173Yb(19F,4nγ)反应
布居了188Au的高自旋态, 并对其准粒子带结构进行了研究. 基于实验测量结果, 对原有的双奇核188Au能级纲图做了较大的修改. 通过系统性比较, 对15+以上的能级结构进行了讨论. 相似文献
3.
Tetsuro Saeki Takahiro Tamesue Shizuma Yamaguchi Kazuya Sunada 《Applied Acoustics》2004,65(2):203-210
This paper focuses on masking speech with meaningless steady noise as a way of realizing a comfortable sound environment. As a basis for research, meaningless steady noise at minimum sound pressure levels for masking of male or female meaningful speech is considered, based on psychological experiments using a method of adjustment. From the results, band-limited pink noise can be selected as the most effective noise for masking of speech. In the case of speech with a lower sound pressure level, the sound pressure level of the meaningless steady noise needs to be a little higher. 相似文献
4.
We have recently reported on dodecamer peptides (HPPMDFHKAMTR, CHPQPLKSRNPL) which recognize 52-58th and 197-203rd amino acid sequences of glucose oxidase (GOx) by screening via a phage random peptide library. In this study, a side-chain protected peptide monomer (PPM) was synthesized using two peptides (HPPMDFHKAMTR, SHPQPLKSRNPL) and acryloyl chloride. The peptide-conjugated polymer (PCP) was copolymerized with PPMs and N,N-diethylacrylamide (DEAA). The affinity of PCPs to GOx was estimated using surface plasmon resonance detection. This study suggests that PCP is a valuable molecular recognition biomolecule. 相似文献
5.
6.
Takanari Yasui Takeshi Ohtsuka Tetsu Suzuki Shigeki Okajima Kazuya Nakayama Mitsuru Tomioka Katsuhiro Kamimura Takeo Namekata Hiroaki Minamide Hiromasa Ito 《International Journal of Infrared and Millimeter Waves》2006,27(2):199-210
A new, wide-band, high-speed and high-sensitivity THz detector has been developed. The prototype detector consists of a parabolic
cylindrical mirror, a long wire antenna and a Schottky barrier diode. Direct detection measurements have shown a stable sensitivity
of 150 ± 50 V/W for 1–2 THz without any adjustments. The long wire antenna was fixed at the focus of parabolic cylindrical
mirror then it has been realized less operation steps, easy coupling to the external THz signals and a dramatic enhancement
in the practicality of this system. The optically polished mirror and frosted surface one showed comparable sensitivities,
thus easy polishing and less cost mirror fabrication can be applied for this system. The radiation pattern showed a maximum
radiation angle of approximately 23° with its dominant main lobe, which was attributed to the wire antenna character and confirmed
good agreements with classical antenna theory. 相似文献
7.
8.
Gui-Chang Wang Ling Jiang Yoshitada Morikawa Junji Nakamura Zun-Sheng Cai Yin-Ming Pan Xue-Zhuang Zhao 《Surface science》2004,570(3):205-217
The adsorption behavior and thermal activation of carbon dioxide on the Cu(1 1 1), Cu(1 0 0), and Cu(1 1 0) surfaces have been investigated by means of density functional theory calculations and cluster models and periodic slabs. According to the cluster models, the optimized results indicate that the basis set of C and O atoms has a distinct effect on the adsorption energy, but an indistinct one on the equilibrium geometry. For the CO2/Cu(hkl) adsorption systems studied here, the final structure of adsorbed CO2 is near linear and the preferred modes for the adsorption of CO2 onto the Cu(1 1 1), Cu(1 0 0), and Cu(1 1 0) surfaces are the side-on adsorption at the cross bridge site with an adsorption energy of 13.06 kJ/mol, the side-on adsorption at the short bridge site (13.54 kJ/mol), and the end-on adsorption on the on-top site with C–O bonds located along the short bridge site (26.01 kJ/mol), respectively. However, the calculated adsorption energies from periodic slabs are lower as compared to the experimental data as well as the cluster model data, indicating that the periodic slab approach of generalized gradient approximation in the density function theory may be not suitable to obtain quantitative information on the interaction of CO2 with Cu(hkl) surfaces. 相似文献
9.
Maki Onoda Takefumi Uchiyama Ken-Ichi Mawatari Kiyoko Kaneko Kazuya Nakagomi 《Analytical sciences》2006,22(6):815-817
A simple batch method for the fluorometric determination of hydrogen peroxide using phosphine-based fluorescent reagents has been developed. A rapid, mild and selective derivatization reaction was achieved by adding sodium tungstate dihydrate to the reaction mixture of hydrogen peroxide and a phosphine-based fluorescent reagent. When 4-diphenylphosphino-7-methylthio-2,1,3-benzoxadiazole was used as a reagent, the derivatization reaction was completed after 2 min at room temperature. The calibration curve was linear between 12.5 and 500 ng hydrogen peroxide in a 10 microL sample solution. This method is accurate and has potential for on-line applications. 相似文献
10.