Reaction of 2-substituted 4,4-dimethyl-5-methylene-1,3-dioxolanes with dichlorocarbene and certain transformations of adducts obtained

A series of derivatives of 4,4-dimethyl-5-methylene-1,3-dioxolane has been synthesized, and their reaction with dichlorocarbene, obtained under interphase catalysis conditions, has been studied. The adducts obtained undergo thermal isomerization into dichloroethylidene derivatives.     

Structural and thermodynamic features of complexes formed by DNA and synthetic polynucleotides with dodecylamine and dodecyltrimethylammonium bromide

Complex formation of native and denatured DNA, single-stranded polyribonucleotides poly(A) and poly(U), as well as double-stranded poly(A).poly(U) with dodecylamine (DDA) and dodecyltrimethylammonium bromide (DTAB) has been studied by UV-, CD-, IR-spectroscopy and fluorescence analysis of hydrophobic probe pyrene. DDA and DTAB were shown to bind cooperatively with DNA and polyribonucleotides, resulting in the formation of complexes containing hydrophobic micelle-like clusters. Critical aggregation concentration (CAC) of DDA and DTAB shifts sharply to lower values (30-50 times) in the presence of DNA and polynucleotides as compared to critical micelle concentration (CMC) of free DDA and DTAB in solution. The analysis of binding isotherms within the frame of the model of cooperative binding of low-molecular ligands to linear polymers allowed us to determine the thermodynamic parameters of complex formation and estimate the contribution of electrostatic interaction of positively charged heads of amphiphiles with negatively charged phosphate groups of DNA and polyribonucleotides, and hydrophobic interaction of aliphatic chains to complex stability. Electrostatic interaction was shown to make the main contribution to the stability of DNA complexes with DDA, while preferential contribution of hydrophobic interactions is characteristic of DTAB complexes with DNA. The opposite effect of DDA and DTAB on the thermal stability of DNA double helix was demonstrated from UV-melting of DNA-while DTAB stabilizes the DNA helix, DDA, to the contrary, destabilizes it. The destabilizing effect of DDA seems to originate from the displacement of intramolecular hydrogen bonds in complementary Watson-Crick A.T and G.C base pairs with intermolecular H-bonds between unsubstituted DDA amino groups and proton-accepting sites of nucleic bases.     

Reactions of 1-halo-3-methyl-2,3-epoxybutane with alcohols

The reaction of 1-bromo(or chloro)-3-methyl-2,3-epoxybutane with alcohols in the presence of the alkali metal alkoxides leads to the formation of epoxy ethers by direct replacement of the halogen atoms without participation of the epoxide ring.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 878–880, July, 1981.     

On the possibility of implementation of Kohn’s theorem in the case of ellipsoidal quantum dots

An electron gas in a strongly oblated ellipsoidal quantum dot with impenetrable walls is considered. Influence of the walls of the quantum dot is assumed to be so strong in the direction of the minor axis (the OZ axis) that the Coulomb interaction between electrons in this direction can be neglected and considered as two-dimensional, coupled. On the basis of geometric adiabaticity we show that in the case of a few-particle gas a powerful repulsive potential of the quantum dot walls has a parabolic form and localizes the dot in the geometric center of the structure. Due to this fact, conditions occur to implement the generalized Kohn theorem for this system.     

Quantum model of the prolate spheroidal Thomson hydrogen atom

In a uniformly charged prolate spheroidal Thomson hydrogen atom the electron states have been investigated. It has been shown from the mathematical point of view that the problem is equivalent to a spheroidal hydrogen atom in a parabolic potential with the cylindrical symmetry. In the framework of adiabatic approximation, the energy of ground state has been calculated. Comparison with the case of uncharged spheroidal quantum dot has been made, and the analytical form of wave function of electron has been also obtained.     

Comparative study of the effect of antiturbulent additives for hydrocarbon liquids

Hydrodynamic and physicochemical studies of petrosoluble samples of antiturbulent additives of colloidal form are performed. The component composition of the dispersion medium and the active component content in each sample are determined. It is shown that the highest antiturbulent efficiency among studied agents of decreasing the hydrodynamic resistance is inherent to a petrosoluble additive with the numerical value of the “concentration semieffect” C _DRmax/2 = 0.0013 kg/m³. Recommendations for optimum applications of antiturbulent additives in energy saving in oil and oil product transport technologies are developed.     

Light-induced glass cutting

Theoretical and experimental results on light-induced method for thermal cleaving of brittle materials by the example of silicate glasses are presented. Physical fundamentals of the controlled distribution of thermal fields induced by laser radiation causing compression and tension processes in a material resulting in material cleavage with a zero cut width are developed.     

Method of molecular distribution functions in the description of adsorption processes in nanoscale structures

The short-range order during gas adsorption by micropores can be described based on integral equations of statistical mechanics for partial distribution functions. The assumptions necessary for correct analysis of physical sorption are considered, and adsorption characteristics of carbon nanofibers in relation to hydrogen are calculated.     

Optical absorption in a narrow-band InSb cylindrical layered nanowire in the presence of strong electrostatic field

On the example of InSb we consider the influence of a strong homogeneous electrostatic field on the state of carriers in a narrow-band quantized cylindrical layer in the case of Kaine dispersion law. Explicit expressions for the energy spectrum and wave function envelopes of charge carriers in the heterolayer are obtained. It is shown that under action of the strong external field the rotational motion, with respect to angular variables, of charge carriers becomes oscillatory in a narrow cone of the azimuth angle. We have obtained corresponding selection rules and calculated the threshold frequencies of absorption for interband and intraband electro-optical transitions in the layer. The threshold frequencies are determined by the geometric sizes of the sample and the magnitude of the external field.