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A new polymorph of tetraphenyldiboroxane [or oxybis(diphenylborane)], C24H20B2O, (Ia), has been found. It is monoclinic, like the already known form, (Ib), and can be refined in the same space group, namely P21/c, or in the equivalent setting P21/n. The molecular conformations of the two polymorphs differ in the rotations of two of the phenyl rings about the B—C bonds, leading to markedly different packing patterns and cell dimensions.  相似文献   
3.
The cross sections of neutrino and antineutrino quasielastic reactions \(vn \to \mu ^ - p,\bar vp \to \mu ^ + n,\bar vp \to \mu ^ + \Lambda\) were studied in the neutrino energy range between 3 and 30 GeV. In comparison withV-A theory axial mass parameters ofM A =(1.06±0.05±0.14) GeV/c2 from neutrino andM A =(0.71±0.10±0.20) GeV/c2 from antineutrino data were found. The total cross-section for the hyperon production process can be described byM A =1.0 GeV/c2.  相似文献   
4.
We present the final results from the search for μe pairs produced in neutrino interactions using the freon filled bubble chamber SKAT. The rate of μ? e + pairs to charged current events above the charm threshold is \(R_{\mu ^ - e^ + } = (4.8 \pm 1.1)10^{ - 3} \) . Assuming charm particle production to be the origin of the positron we calculate \(R_{\Lambda _c^ + } = (6.2 \pm 3.1)10^{ - 2} \) andR D =(2.8±0.9)10?2. We observe no considerable μ? e ? pair production above the background. In the regionE v >3 GeV,p μ,e >1.0 GeV/c andp μ>p e we find with a 90% confidence level the limit \(R_{\mu ^ - e^ - }< 1.7 10^{ - 4} \) .  相似文献   
5.
A method using liquid chromatography with tandem mass spectrometry was developed for the determination of 11 commonly used aminoglycoside antibiotics in meat. The proposed method is sufficiently sensitive (detection limits of 15 to 40 ppb for the various antibiotics) and highly selective. It is suitable for the quantitation and confirmation of aminoglycosides in a variety of matrixes (pork muscle, fish, and veal liver). Any multiresidue method for aminoglycosides must take into account their high affinity toward sample proteins and the significantly different pK values of the various analytes. The developed method uses a low-pH extraction with trichloracetic acid to ensure complete extraction of the analytes from the matrix. An anion-exchange step is used to remove the acid from the centrifuged extract. Aminoglycosides in this solution of low ionic strength can be quantitatively retained and afterwards eluted from a weak cation-exchanger solid-phase extraction (SPE) cartridge. The highly selective SPE steps produce clean extracts, which minimize possible suppression of the mass spectrometer signal.  相似文献   
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The well known theorem of Arnold and Moser gives (in most cases) an answer to the question of the stability of the equilibria of autonomous Hamiltonian systems which can be reduced to two degrees of freedom. To apply their theorem, the Hamiltonian has to be transformed into its Birkhoff normal form of order two. In this paper this transformation is reduced to the multiplication of polynomials, which can easily be performed algebraically on a computer. The conical precessions of a dynamically symmetric satellite in a circular orbit serve as an example.
Zusammenfassung Der bekannte Satz von Arnold und Moser liefert (auer in wenigen Ausnahmefällen) eine Antwort auf die Frage nach der Stabilität von Gleichgewichtslagen autonomer Hamiltonscher Systeme, die sich auf zwei Freiheitsgrade reduzieren lassen. Damit dieser Satz angewendet werden kann, mu die Hamiltonfunktion auf ihre Birkhoff-Normalform der Ordnung zwei transformiert werden. Diese Transformation wird hier auf Multiplikationen von Polynomen reduziert, die einfach, in symbolischer Weise, auf dem Computer ausgeführt werden können. Als Beispiel dienen die konischen Präzessionen eines dynamisch symmetrischen Satelliten auf einer Kreisbahn.
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8.
The action of ultra violet rays of 260 nm on aqueous solutions of bases, nucleosides and nucleotides of DNA at 77°K is studied by electron spin resonance. It is shown that the free radicals observed are similar, with a few noteworthy exceptions to those induced by X-rays, under the same conditions of temperature, in the solid state. Contrary to what might be excepted on the basis of the results obtained by X-rays, the variation in the yield in paramagnetic centres in each sequence studied does not seem to be important.  相似文献   
9.
Abstract— –The photosensitization of amino acids by proflavine is studied using the technique of electron spin resonance spectroscopy. The analysis of the line shape as a function of the incident microwave power (both in the presence and absence of oxygen) and the dependence of the numbers of free radicals on the intensity of the incident light allow one to suggest that two types of radicals are formed. One is formed by a biphotonic process, the nature of the radicals being the same as in the case of ionising radiation, while the other is probably the RO2 radical formed as a result of photodynamic action.  相似文献   
10.
Understanding the interaction of chiral ligands, alkynes, and alkenes with cobaltcarbonyl sources is critical to learning more about the mechanism of the catalytic, asymmetric Pauson-Khand reaction. We have successfully characterized complexes of the type [Co2(alkyne)(binap)(CO)4] (BINAP=(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine)) and shown that diastereomer interconversion occurs under Pauson-Khand reaction conditions when alkyne=HC[triple bond]CCO2Me. Attempts to isolate [Co2(alkyne)(binap)(CO)x] complexes with coordinated alkenes led to the formation of cobaltacyclopentadiene species.  相似文献   
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