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1.
A self-consistent model of the development of dendrites and partial discharges in a dielectric solid under a variable voltage
is suggested. Dendrites originate at sites with the enhanced local field strength and also where the dielectric is broken
down under the action of partial discharges. The numerical simulation is used to quantitatively describe the space-time dynamics
of the dendrites and partial discharges in epoxy resin for the tip-plane electrode configuration. The simulated data are compared
with electrical measurements of partial discharges and with optical images of dendrite growth under the same conditions. 相似文献
2.
Katrin Leschke 《Annals of Global Analysis and Geometry》1997,15(1):51-69
On every isoparametric submanifold M a connection with parallel second fundamental form is constructed geometrically such that M is an orbit of an s-representation if and only if the connection is a canonical one. If the rank of M is greater than one this connection is in case of homogeneity the canonical connection of the reductive decomposition given
by the orbit of s-representation.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
3.
P. Schwab A. Kochemasov R. Kullmer D. Bäuerle 《Applied Physics A: Materials Science & Processing》1992,54(2):166-169
Pulsed-laser deposition of YBa2Cu3O7 in N2O permits lowering of the substrate temperature with respect to deposition in O2 atmosphere. Additional photodissociation of N2O near the substrate surface deteriorates the superconducting properties of deposited films.On leave from: Institute of Applied Physics of the Academy of Sciences of the USSR, SU-603600 Nishni Nowgorod, USSR 相似文献
4.
C. Donzaud S. Czajkowski P. Armbruster M. Bernas C. Böckstiegel P. Dessagne H. Geissel E. Hanelt A. Heinz C. Kozhuharov C. Miehé G. Münzenberg M. Pfützner W. Schwab C. Stéphan K. Sümmerer L. Tassan-Got B. Voss 《The European Physical Journal A - Hadrons and Nuclei》1998,1(4):407-426
Projectile fission of 750 AMeV 238U-ions interacting with a Pb target was studied by means of the spectrometer FRS, GSI-Darmstadt. One of the two fission fragments
was detected with a transmission of few percent and identified in mass and charge. Low-energy fission (E* < 25 MeV) events were selected by their magnetic rigidity. Whereas the production of asymmetric fission events is dominated
by the GDR excitation, very asymmetric fission and symmetric fission take place after a GQR or DGDR excitation or after a
nuclear interaction. Cross sections of more than 250 isotopes were measured. Isotopic distributions of low-energy fission
were reconstructed for elements from Se to Te. The fission modes SI, SII and SL were clearly shown in these distributions
and in the mass and TKE distributions. Charge polarization and mass dispersion were deduced for each fission mode. Finally,
the characteristics of the low-energy fission process explain the production rates of neutron-rich species.
Received: 14 July 1997 / Revised version: 6 October 1997 相似文献
5.
We describe a convergent synthesis of eight 1,3,5- and 1,2,4,5-substituted benzene derivatives with long rigid arms containing 4-pyridyl, 2,2'-bipyridyl, and 2,2'-bipyrimidyl termini, meant to be used as trigonal or tetragonal connectors for the construction of large molecular structures. The synthesis involved copper-free Pd-mediated coupling of terminal acetylenes to aryl halides. First, one of the termini of 1,3-diethynylbicyclo[1.1.1]pentane was coupled with a brominated aza heterocycle, and second, 3 equiv of the resulting extended arm were coupled with 1,3,5-triiodobenzene or 4 with 1,2,4,5-tetraiodobenzene. An improved large-scale synthesis for 1,3-diethynylbicyclo[1.1.1]pentane is described. The structures of two of the arms were determined by single-crystal X-ray analysis. Several long molecular rods with 4-pyridyl termini were obtained as byproducts, and a single-crystal X-ray structure is reported for the shortest of these. 相似文献
6.
Preparation and physical and chemical properties of 3-ethinyl-2,4-diformyl-pentandial (3 a) and its salts are described.3 a contains 2 malonaldehyde groups. Starting from3 a, 4H-pyranes, 4H-dihydropyridines, dipyrazoles, diisoxazoles, bisdiazepines and vinamidine derivates are obtained.
Mit 1 Abbildung 相似文献
Mit 1 Abbildung 相似文献
7.
Colour Effects in Oxidic and Other Mn2+ Compounds – the Ligand Field Spectra of Mixed Crystals MgO/MnO, CaO/MnO, and of MnAl2O4 The colour intensity and the shift of the hue is examined for mixed crystals Mg1?xMnxIIO and Mn1?yIICayO in dependence of the Mn2+-concentration and interpreted in terms of Mn2+? Mn2+ pair interactions and variations of the Mn? O bond length, respectively. The experimental band positions (sextet-quartet transitions) could be fitted quantitatively – also in case of Mn2+ in tetrahedral (MnAl2O4) and dodecahedral oxygen coordination (Mn3Al2Ge3O12, MnY2Mg2Ge3O12) – by means of crystal field calculations. The obtained ligand field parameters are discussed in comparison with data for octahedral Mn2+ ions with H2O, F? and Cl? as ligands. 相似文献
8.
Graham DL Lowe PN Grime GW Marsh M Rittinger K Smerdon SJ Gamblin SJ Eccleston JF 《Chemistry & biology》2002,9(3):375-381
The formation of complexes between small G proteins and certain of their effectors can be facilitated by aluminum fluorides. Solution studies suggest that magnesium may be able to replace aluminum in such complexes. We have determined the crystal structure of RhoA.GDP bound to RhoGAP in the presence of Mg(2+) and F(-) but without Al(3+). The metallofluoride adopts a trigonal planar arrangement instead of the square planar structure of AlF(4)(-). We have confirmed that these crystals contain magnesium and not aluminum by proton-induced X-ray emission spectroscopy. The structure adopted by GDP.MgF(-) possesses the stereochemistry and approximate charge expected for the transition state. We suggest that MgF3(-) may be the reagent of choice for studying phosphoryl transfer reactions. 相似文献
9.
The laccase catalyzed oxidative dimerization of salicylic esters, a rare example of a laccase-catalyzed carbon-carbon bond formation, was studied. This reaction allows the use of air as stoichiometric oxidant and proceeds in aqueous solution. The preparative scope and the mechanism of the method, which provides a new and convenient access to functionalized biaryls under mild conditions, were investigated. 相似文献
10.
Rigorous regio- and stereospecific labeling experiments are performed to demonstrate the operation of the previously suggested operation of ‘isotopically sensitive branching’ in FeI-mediated C? H bond activation. For the hexane-1,6-diol/Fe+-complex, it is shown that dehydrogenation involves specifically the central C(3)/C(4) position, and the study of the stereospecifically labeled D ,L - and meso-[3,4-D2]-isotompomers 1e and 1f demonstrates that dehydrogenation proceedes via two competing pathways (i.e. ‘anti’- vs. ‘syn’-route). The contribution of these routes to the product formation is – due to a kinetic isotope effect – controlled by the relative configuration at the labeled positions C(3)/C(4). For the D ,L -form 1e , we estimate a ratio of 49:1 in favor of the ‘anti’-route; due to an isotope effect, this ratio drops to 4.3:1 for the meso-form 1f . 相似文献