全文获取类型
收费全文 | 1048篇 |
免费 | 47篇 |
国内免费 | 2篇 |
专业分类
化学 | 827篇 |
晶体学 | 8篇 |
力学 | 10篇 |
数学 | 124篇 |
物理学 | 128篇 |
出版年
2023年 | 8篇 |
2022年 | 13篇 |
2021年 | 19篇 |
2020年 | 18篇 |
2019年 | 14篇 |
2018年 | 16篇 |
2017年 | 13篇 |
2016年 | 38篇 |
2015年 | 36篇 |
2014年 | 37篇 |
2013年 | 63篇 |
2012年 | 90篇 |
2011年 | 87篇 |
2010年 | 74篇 |
2009年 | 67篇 |
2008年 | 86篇 |
2007年 | 64篇 |
2006年 | 73篇 |
2005年 | 55篇 |
2004年 | 37篇 |
2003年 | 24篇 |
2002年 | 37篇 |
2001年 | 7篇 |
2000年 | 9篇 |
1999年 | 11篇 |
1998年 | 8篇 |
1997年 | 13篇 |
1996年 | 11篇 |
1995年 | 3篇 |
1994年 | 8篇 |
1993年 | 12篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1979年 | 2篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1964年 | 1篇 |
1957年 | 1篇 |
1943年 | 1篇 |
1933年 | 1篇 |
1929年 | 1篇 |
1926年 | 1篇 |
1901年 | 1篇 |
排序方式: 共有1097条查询结果,搜索用时 15 毫秒
1.
A protocol to correct for intra‐ and interspecific variation in tail hair growth to align isotope signatures of segmentally cut tail hair to a common time line
下载免费PDF全文
![点击此处可从《Rapid communications in mass spectrometry : RCM》网站下载免费的PDF全文](/ch/ext_images/free.gif)
2.
Reactions of the hydrated electron, H atoms, 2-propanol, and methanol radicals with the TiO2 nano-particles have been studied either directly or by competition kinetics. The radicals were produced by radiolysis of 2-propanol, t-butanol, or methanol aqueous solutions in acid pH's. The reactions involve electron injection to the conduction band. As expected, the t-butanol radical is inert towards TiO2 under our conditions, while the other reducing radicals react with TiO2. The reactivity decreases in the order: eaq−>H>CH3COHCH3>CH2OH. Two TiO2 nanocrystallite sizes, with average diameters of 1.0 and 4.7 nm were compared. For equal concentrations (in terms of TiO2 molecules), the rate of electron injection shows relatively little dependency on particle size. The rates of interfacial electron transfer and transfer coefficient are also reported. 相似文献
3.
The dynamic Young modulus (E) of magnetic Nd2Fe14B+αFe nanocomposites is investigated with mechanical spectroscopy techniques (vibrating reed configuration, f≈1.5 kHz <10−6). Reduced values of E are obtained (88–152 GPa) as compared with that predicted by the rule of mixtures for the composite (164 GPa). Three contributions to this reduction are briefly discussed: a large volume fraction of the specimen with grain boundary like structure; internal pores, resulting from the high cooling rate during processing (106 K/min) and magneto-mechanical effects. Even when porosity is identified as the principal cause of modulus reduction, magnetic effects are also detected. 相似文献
4.
Katrin Leschke 《Annals of Global Analysis and Geometry》1997,15(1):51-69
On every isoparametric submanifold M a connection with parallel second fundamental form is constructed geometrically such that M is an orbit of an s-representation if and only if the connection is a canonical one. If the rank of M is greater than one this connection is in case of homogeneity the canonical connection of the reductive decomposition given
by the orbit of s-representation.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
5.
Agnes Kurucz 《Algebra Universalis》2002,47(4):409-424
We show that in many cases the decision problems for varieties of cylindric algebras are much harder than those for the corresponding relation algebra reducts. We also give examples of varieties of cylindric and relation algebras which are algorithmically more complicated than the subvarieties of their representable algebras. 相似文献
6.
Szantai E Ronai Z Szilagyi A Sasvari-Szekely M Guttman A 《Journal of chromatography. A》2005,1079(1-2):41-49
The investigation of the genetic background and phenotype structures of complex diseases, such as cardiovascular or psychiatric disorders and tumors, is one of the most scrutinized fields of the post genomic era. Besides the multiplex analysis of genetic markers and polymorphisms throughout the whole genome, more and more attention is focused on the interaction between the etiological factors of these traits. Haplotype determination, rather than multiplex genotyping seems to be one of the first building blocks of this endeavor. This review focuses on the importance and theoretical background of haplotyping, and summarizes the recent examples of novel and emerging haplotyping techniques by capillary gel electrophoresis based DNA fragment analysis, a powerful tool for the examination of the inheritance of complex traits. 相似文献
7.
Agnes G. Nagy 《Journal of organometallic chemistry》1985,291(3):335-340
Polarizations, polarization ranges and ratios of polarization ranges for vinylene groups in seven series, namely chalcone derivatives, ferrocene analogues of chalcone, stilbene derivatives, ferrocene analogues of stilbene, and styrene derivatives, were studied. The polarization ranges spanning the intervals between 13C NMR chemical shifts of the derivatives substituted by p-NO2 and p-NMe2 groups are compared in these related compounds. The influence of the side-chain groups in the vinylene moiety and of the sign of the polarization on the substituent-effect are discussed. 相似文献
8.
9.
Graham DL Lowe PN Grime GW Marsh M Rittinger K Smerdon SJ Gamblin SJ Eccleston JF 《Chemistry & biology》2002,9(3):375-381
The formation of complexes between small G proteins and certain of their effectors can be facilitated by aluminum fluorides. Solution studies suggest that magnesium may be able to replace aluminum in such complexes. We have determined the crystal structure of RhoA.GDP bound to RhoGAP in the presence of Mg(2+) and F(-) but without Al(3+). The metallofluoride adopts a trigonal planar arrangement instead of the square planar structure of AlF(4)(-). We have confirmed that these crystals contain magnesium and not aluminum by proton-induced X-ray emission spectroscopy. The structure adopted by GDP.MgF(-) possesses the stereochemistry and approximate charge expected for the transition state. We suggest that MgF3(-) may be the reagent of choice for studying phosphoryl transfer reactions. 相似文献
10.
The laccase catalyzed oxidative dimerization of salicylic esters, a rare example of a laccase-catalyzed carbon-carbon bond formation, was studied. This reaction allows the use of air as stoichiometric oxidant and proceeds in aqueous solution. The preparative scope and the mechanism of the method, which provides a new and convenient access to functionalized biaryls under mild conditions, were investigated. 相似文献