全文获取类型
收费全文 | 7793篇 |
免费 | 218篇 |
国内免费 | 18篇 |
专业分类
化学 | 5125篇 |
晶体学 | 27篇 |
力学 | 112篇 |
数学 | 1251篇 |
物理学 | 1514篇 |
出版年
2020年 | 68篇 |
2019年 | 67篇 |
2018年 | 70篇 |
2017年 | 50篇 |
2016年 | 159篇 |
2015年 | 147篇 |
2014年 | 170篇 |
2013年 | 278篇 |
2012年 | 265篇 |
2011年 | 343篇 |
2010年 | 182篇 |
2009年 | 171篇 |
2008年 | 319篇 |
2007年 | 302篇 |
2006年 | 292篇 |
2005年 | 327篇 |
2004年 | 255篇 |
2003年 | 238篇 |
2002年 | 202篇 |
2001年 | 134篇 |
2000年 | 126篇 |
1999年 | 113篇 |
1998年 | 83篇 |
1997年 | 97篇 |
1996年 | 100篇 |
1995年 | 102篇 |
1994年 | 87篇 |
1993年 | 89篇 |
1992年 | 99篇 |
1991年 | 83篇 |
1990年 | 103篇 |
1989年 | 66篇 |
1988年 | 85篇 |
1987年 | 88篇 |
1986年 | 60篇 |
1985年 | 126篇 |
1984年 | 83篇 |
1983年 | 82篇 |
1982年 | 92篇 |
1981年 | 88篇 |
1980年 | 75篇 |
1979年 | 86篇 |
1978年 | 87篇 |
1977年 | 73篇 |
1976年 | 100篇 |
1975年 | 94篇 |
1974年 | 69篇 |
1973年 | 65篇 |
1970年 | 52篇 |
1966年 | 49篇 |
排序方式: 共有8029条查询结果,搜索用时 15 毫秒
1.
2.
Ralf Freund Christos Allagiannis Peter Schnholzer Karl Bernauer 《Helvetica chimica acta》1994,77(3):615-621
A crude hydrate 6 and a crystalline hemiacetal 7 of glyoxylamide 4 were prepared from crotonamide 5 (Scheme 2). Particularly hemiacetal 7 , but also 6 and the ‘dimer’ 8 (obtained from 7 ) may serve as homochiral auxiliaries. The structure of 8 was determined by X-ray analysis. By arenesulfonyl halides, tryptimines 12–14 of 4 were diastereoselectively transformed into spirotricycles 15–17 and 19 . 相似文献
3.
4.
Hana Macková Daniela Králová Daniel Horák 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5884-5898
The aim of this study was to develop novel thermally responsive polymer microspheres with magnetic properties. Dispersion and inverse emulsion copolymerization of N‐isopropylacrylamide (NIPAAm) and N,N′‐methylenebisacrylamide (MBAAm) was investigated in the presence of γ‐Fe2O3 nanoparticles. The resulting microspheres were characterized in terms of morphology, size, polydispersity, iron content, and temperature‐dependent swelling using optical microscopy, transmission electron microscopy, scanning electron microscopy, QELS, and AAS. The effects of several variables, such as the concentration of γ‐Fe2O3, MBAAm crosslinking agent, Span 80 surfactant, 2,2′‐azobis(2‐methyloctanenitrile) (AMON) initiator, and polymerization temperature on the properties of the microspheres were studied. Swelling and thermoresponsive behavior of the microspheres containing γ‐Fe2O3 nanoparticles were also investigated. The microspheres contained about 8 wt % of iron. The presence of magnetic nanoparticles and their concentration changes did not have any significant effect on the temperature sensitivity of the composites. The particles gradually shrink into an increasingly collapsed state when the temperature is raised to 40 °C since the increase in temperature weakens the hydration and PNIPAAm chains gradually become more hydrophobic, which leads to the collapse of the particles. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5884–5898, 2007 相似文献
5.
Karl Gustafson 《Numerical Linear Algebra with Applications》2004,11(7):649-659
Given the operator product BA in which both A and B are symmetric positive‐definite operators, for which symmetric positive‐definite operators C is BA symmetric positive‐definite in the C inner product 〈x, y〉C? This question arises naturally in preconditioned iterative solution methods, and will be answered completely here. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
6.
Time structure of iodine laser pulse in the free running mode of operation was studied using the power amplifier of laser system PERUN as the laser oscillator. Two characteristic shapes of laser pulse correspond to different regimes of laser operation, the existence of which is ascribed to the critical concentration of I2 molecules. Simultaneously an additional chemical pumping was proved at least in the initial phase of photodissociation and in a late-time lasing after the end of flashlamps pumping light. 相似文献
7.
Karl Gruber Christoph Kratky 《Journal of polymer science. Part A, Polymer chemistry》2004,42(3):479-486
Hydroxynitrile lyases catalyze the reversible cleavage of α-cyanohydrins to yield hydrocyanic acid and the corresponding aldehyde or ketone. Besides its biological interest, this class of enzymes is also of relevance in industrial biocatalysis for the enantioselective condensation of HCN with a variety of aldehydes and ketones. Several distinctly different types of hydroxynitrile lyases (HNLs) are known, which must have originated through convergent evolution from different ancestral proteins. Three-dimensional structural data are known for three classes of hydroxynitrile lyases. Insights into the reaction mechanisms emerged from a combination of structural, enzyme kinetic, spectroscopic, and molecular modeling data. For all three types of HNLs, mechanisms involving acid–base catalysis were proposed. In members belonging to the α,β-hydrolase type, the amino acid residues of the catalytic triad presumably act as general acid/base, whereas for flavine adenine dinucleotide (FAD)-dependent HNLs a single histidine residue fulfills this function. In the third type of HNL—which is related to carboxypeptidase—acid–base catalysis involves the carboxylate of the C-terminal residue. The catalytic relevance of a positive electrostatic potential in the active site was suggested in some of the mechanistic proposals. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 479–486, 2004 相似文献
8.
Nis Halland Tore Hansen Karl Anker Jrgensen 《Angewandte Chemie (International ed. in English)》2003,42(40):4837-4837
9.
A Variable Neighborhood Search for the Multi Depot Vehicle Routing Problem with Time Windows 总被引:6,自引:0,他引:6
Michael Polacek Richard F. Hartl Karl Doerner Marc Reimann 《Journal of Heuristics》2004,10(6):613-627
The aim of this paper is to propose an algorithm based on the philosophy of the Variable Neighborhood Search (VNS) to solve Multi Depot Vehicle Routing Problems with Time Windows. The paper has two main contributions. First, from a technical point of view, it presents the first application of a VNS for this problem and several design issues of VNS algorithms are discussed. Second, from a problem oriented point of view the computational results show that the approach is competitive with an existing Tabu Search algorithm with respect to both solution quality and computation times. 相似文献
10.
W. B. Krätzig 《Archive of Applied Mechanics (Ingenieur Archiv)》1993,64(1):1-19
Übersicht Konsistente Schalentheorien lassen sich in einer besonders anschaulichen Weise durch lineare Approximation der Erhaltungssätze eines als Multi-Direktor-Körper beschriebenen, dreidimensionalen Kontinuums herleiten. Im vorliegenden Beitrag entstchen auf diesem Wege bestmögliche, in Geschwindigkeiten formulierte innere Schalengleichungen für beliebig große Deformationen und willkürliche, in eine Leistungsaussage einpaßbare Materialgesetze. Dabei finden Schub- und Querdeformationen Berücksichtigung. Der optimale Charakter der Schalentheorie mit gleichen Unschärfen in allen Einzelbeziehungen wird durch den Herleitungsgang sichergestellt und durch Einschrankungen mittels lokaler Tensornormen bewiesen.
Best interior shell equations including transverse shear deformations and thickness changes
Summary Consistent shell theories can be derived in a particular correct manner by linear approximation of conservation laws of a three-dimensional continuum, described as a multi-director-body. In the present paper best interior shell equations-formulated in velocities—are developed, valid for arbitrarily large deformations and rather optional material laws, incorporating shear distorsions and thickness changes. The optimal character of the theory is guaranteed by the derivation process and proven by bounding techniques using tensor norms.相似文献