Experimental comparison of performance and emission characteristics of 4-stroke CI engine operated with Roselle and Jatropha biodiesel blends

The environmental degradation, combined with the continuous depletion of the world's fossil fuel reserves, has forced the search for alternative fuels. This study was performed to investigate the performance of novel biodiesels in the CI engine. The experiments were performed at three different compressions ratios (16:1, 17:1, 18:1) and four loading conditions (25%, 50%, 75%, 100%). Different types of fuels such as jatropha biodiesel (JB), roselle biodiesel (RB), and ternary biodiesel (TB) were prepared and analyzed. The thermal performance of different fuels was analyzed in terms of brake thermal efficiency (BTE), brake specific fuel consumption (BSFC), and exhaust gas temperature (EGT). The emission characteristics such as CO₂ emission, NO_x emission, and smoke emission were analyzed for all types of fuels. The results of these fuels in the engine were compared with mineral diesel (MD). The BTE was increased with increasing compression ratios and loads for all types of fuels. The BSFC was increased with increasing compression ratios but decreased with increasing loads. The increase in emission of NO_x was observed at higher compression ratios and loads. However, the CO₂ emission was decreased at higher loads and lower compression ratio. The performance curves achieved with a 20% jatropha biodiesel blend showed results that were approximate to those obtained with pure MD. The comparative analysis between different fuels showed that JB exhibit higher thermal performance as compared to other biodiesels. Therefore, JB can be a better alternative to conventional fuel.     

Synthesis and biological evaluation of <Superscript>99m</Superscript>Tc labeled aryl piperazine derivatives as cerebral radiotracers

The aim of this study is to develop cerebral radiotracers for central nervous system receptors imaging. The synthesis, characterization and biological evaluation of two aryl piperazine ^99mTc-radiocomplexes based on the piano stool motif [CpM(CO₃)] (Cp = cyclopentadienyl, M = ^99mTc/Re) is reported. The ^99mTc-radiocomplexes were obtained quickly (time < 5 min) with high radiochemical yields. The ^99mTc-radiocomplexes characterized by high performance liquid chromatography comparison with the rhenium surrogates have both a suitable lipophilicity and are able to cross the blood brain barrier with 0.43 ± 0.05 and 1.96 ± 0.06% ID/g of brain uptake, at 10 min post injection.     

Enantioselective Approach for Expanding the Three-Dimensional Space of Tetrahydroquinoline to Develop BET Bromodomain Inhibitors**

The pharmaceutical industry has a pervasive need for chiral specific molecules with optimal affinity for their biological targets. However, the mass production of such compounds is currently limited by conventional chemical routes, that are costly and have an environmental impact. Here, we propose an easy access to obtain new tetrahydroquinolines, a motif found in many bioactive compounds, that is rapid and cost effective. Starting from simple raw materials, the procedure uses a proline-catalyzed Mannich reaction followed by the addition of BF₃ ⋅ OEt₂, which generates a highly electrophilic aza-ortho-quinone methide intermediate capable of reacting with different nucleophiles to form the diversely functionalized tetrahydroquinoline. Moreover, this enantioselective one-pot process provides access for the first time to tetrahydroquinolines with a cis-2,3 and trans-3,4 configuration. As proof of concept, we demonstrate that a three-step reaction sequence, from simple and inexpensive starting compounds and catalysts, can generate a BD2-selective BET bromodomain inhibitor with anti-inflammatory effect.     

Two new alkaloids and a new polyphenolic compound from <Emphasis Type="Italic">Cotula coronopifolia</Emphasis>

Two new alkaloid derivatives of the 3-benzazocine skeleton (cotuzine A and B) and a new polyphenolic substance (3-(1,3-dihydroxyprop-2-yl)-4-hydroxyanisol) (corimen) have been isolated from the aerial part (stems, leaves) of the plant Cotula coronopifolia (L.). These three new structures were established by spectroscopic procedures (¹H, ¹³C, one- and two-dimensional NMR). The stereochemistry of the new alkaloids was established based on different NOE effects revealed on the NOESY spectrum. Mass spectrometry and IR spectroscopy were used to confirm these structures.     

On nonlinear diffusion problems with strong degeneracy

In this Note, we study the ‘triply’ degenerate problem: $b{(v)}_t?\mathrm{\Delta }g(v)+\mathrm{div}\Phi (v)=f$ on $Q:=(0,T)\times \Omega$, $b(v(0,?))=b(v_0)$ on Ω and $g(v)=g(a)$ ‘on some part of the boundary’ $(0,T)\times ?\Omega$, in the case of continuous nonhomogenous and nonstationary boundary data a. The functions $b,g$ are assumed to be continuous nondecreasing and to verify the normalisation condition $b(0)=g(0)=0$ and the range condition $R(b+g)=\mathbb{R}$. Using monotonicity and penalization methods, we prove existence of a weak entropy solution in the spirit of F. Otto (1996). To cite this article: K. Ammar, C. R. Acad. Sci. Paris, Ser. I 343 (2006).     

Mutagenic, antimutagenic and antioxidant activities of a new polyphenolic and a flavonoid substances isolated from Anagallis monelli

A new polyphenolic natural substance: 2,5-dihydroxy-benzoic acid 3'-formyl-5'-hydroxy-phenyl ester (1), Anamighrinal and 3-(O-alpha-L-rhamnosyl) quercetin (2) have been isolated from the methanolic aerial part extract of the plant Anagallis monelli by chromatographic separation. Their structures have been deduced essentially by one and two NMR spectroscopic procedures and mass spectrometry. Antioxidant, mutagenic, antimutagenic activities, of the natural products were realised and positive results were recorded.     

Thermal stability of hybrid nanofluid with viscous dissipation and suction/injection applications: Dual branch framework

The thermal stability of nanomaterials is quite necessary for controlling the heat and cooling phenomenon. It is worthy observed that much research has been focused scientists towards the thermal significance of nanoparticles with multidisciplinary engineering and industrial applications. On this end, this report explores the improved thermal mechanism water base material with interaction of hybrid nanofluid stretching and shrinking surface. The cooling and heat phenomenon is observed in presence of viscous dissipation. The hybrid nanofluid characteristics are inspected with combination of copper $\left(Cu\right)$ and aluminum oxide $\left(A{l}_2{O}_3\right)$ nanoparticles with stable prospective. The consideration of such hybrid nanoparticles is due to impressive thermal characteristics and stable thermal performances. Although some studies are focused by researchers on hybrid nanofluid, however the measurement of thermal stability is not claimed yet. The stretching and shrinking configuration specify the porous medium features. The problem is compiled into dimensionless structure which is further preceded via bvp4c scheme. The resultant ODEs are successfully numerically solved using the bvp4c solver technique. Under restricting conditions, numerical findings are compared to previously published results. Non-dimensional profiles of velocity and temperature are shown graphically. Furthermore, graphs and tables show the effects of the physical parameters used on the reduced skin friction and heat transfer rate. Dual branches are found in specified domain of suction factor.     

On nonlinear diffusion problems with strong degeneracy

In this paper, we study the “triply” degenerate problem: bt(v)−Δg(v)+divΦ(v)=f on Q:=(0,T)×Ω, b(v(0,⋅))=b(v₀) on Ω and “g(v)=g(a) on some part of the boundary (0,T)×∂Ω,” in the case of continuous nonhomogeneous and nonstationary boundary data a. The functions b,g are assumed to be continuous, locally Lipschitz, nondecreasing and to verify the normalization condition b(0)=g(0)=0 and the range condition R(b+g)=R. Using monotonicity and penalization methods, we prove existence of a weak renormalized entropy solution in the spirit of [K. Ammar, J. Carrillo, P. Wittbold, Scalar conservation laws with general boundary condition and continuous flux function, J. Differential Equations 228 (2006) 111-139].     

Solutions entropiques des problèmes non locauxEntropy solutions of nonlocal problems

We introduce a notion of entropy solution for the nonlocal problem $\text{C}\text{f+f=ψ}$ on $\text{?Ω}$, where $\text{ψ∈}\text{L}{}^1\text{(?Ω)}$ and $\text{C}$ is a nonlinear capacity operator. We prove its existence and uniqueness. This notion of solution allows also to solve a general elliptic problem with nonlinear boundary conditions. To cite this article: K. Ammar, C. R. Acad. Sci. Paris, Ser. I 334 (2002) 751–756.     

A Novel Energy-from-Waste Approach for Electrical Energy Production by Galvano–Fenton Process

A novel approach allowing the production of electrical energy by an advanced oxidation process is proposed to eliminate organic micropollutants (MPs) in wastewaters. This approach is based on associating the Galvano–Fenton process to the generation of electrical power. In the previous studies describing the Galvano–Fenton (GF) process, iron was directly coupled to a metal of more positive potential to ensure degradation of organic pollutants without any possibility of producing electrical energy. In this new approach, the Galvano–Fenton process is constructed as an electrochemical cell with an external circuit allowing recovering electrons exchanged during the process. In this study, Malachite Green (MG) dye was used as a model of organic pollutant. Simultaneous MG degradation and electrical energy production with the GF method were investigated in batch process. The investigation of various design parameters emphasis that utilization of copper as a low-cost cathode material in the galvanic couple, provides the best treatment and electrical production performances. Moreover, these performances are improved by increasing the surface area of the cathode. The present work reveals that the GF process has a potential to provide an electrical power density of about 200 W m⁻². These interesting performances indicate that this novel Energy-from-Waste strategy of the GF process could serve as an ecological solution for wastewater treatment.