全文获取类型
收费全文 | 43408篇 |
免费 | 6894篇 |
国内免费 | 5409篇 |
专业分类
化学 | 31350篇 |
晶体学 | 631篇 |
力学 | 2499篇 |
综合类 | 484篇 |
数学 | 4634篇 |
物理学 | 16113篇 |
出版年
2024年 | 136篇 |
2023年 | 840篇 |
2022年 | 1496篇 |
2021年 | 1637篇 |
2020年 | 1771篇 |
2019年 | 1707篇 |
2018年 | 1398篇 |
2017年 | 1430篇 |
2016年 | 2011篇 |
2015年 | 1952篇 |
2014年 | 2452篇 |
2013年 | 3202篇 |
2012年 | 3859篇 |
2011年 | 3848篇 |
2010年 | 2788篇 |
2009年 | 2654篇 |
2008年 | 2994篇 |
2007年 | 2654篇 |
2006年 | 2519篇 |
2005年 | 2045篇 |
2004年 | 1631篇 |
2003年 | 1339篇 |
2002年 | 1213篇 |
2001年 | 977篇 |
2000年 | 852篇 |
1999年 | 893篇 |
1998年 | 760篇 |
1997年 | 627篇 |
1996年 | 616篇 |
1995年 | 545篇 |
1994年 | 474篇 |
1993年 | 436篇 |
1992年 | 364篇 |
1991年 | 327篇 |
1990年 | 302篇 |
1989年 | 215篇 |
1988年 | 161篇 |
1987年 | 115篇 |
1986年 | 127篇 |
1985年 | 93篇 |
1984年 | 53篇 |
1983年 | 54篇 |
1982年 | 50篇 |
1981年 | 28篇 |
1980年 | 14篇 |
1979年 | 12篇 |
1973年 | 4篇 |
1971年 | 6篇 |
1970年 | 6篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Dr. Kyung-Seok Kang Dr. Krishnan A. Iyer Prof. Dr. Jeffrey Pyun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(35):e202200115
In this concept review, the fundamental and polymerization chemistry of inverse vulcanization for the preparation of statistical and segmented sulfur copolymers, which have been actively developed and advanced in various applications over the past decade is discussed. This concept review delves into a discussion of step-growth polymerization constructs to describe the inverse vulcanization process and discuss prepolymer approaches for the synthesis of segmented sulfur polyurethanes. Furthermore, this concept review discusses the advantages of inverse vulcanization in conjunction with dynamic covalent polymerization and post-polymerization modifications to prepare segmented block copolymers with enhanced thermomechanical and flame retardant properties of these materials. 相似文献
2.
Tian Jie Yang Weifeng Chen Min Zheng Minfang Chen Ding Qiu Yusheng 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):1039-1049
Journal of Radioanalytical and Nuclear Chemistry - This study presents a time-efficient method of analysing 210Pb, 210Bi, and 210Po in natural waters. The optimum pH (1.00), temperature... 相似文献
3.
Potential Analysis - We establish some exact asymptotic results for a matching problem with respect to a family of beta distributions. Let X1,…,Xn be independent random variables with common... 相似文献
4.
Gürbüzbalaban Mert Ruszczyński Andrzej Zhu Landi 《Journal of Optimization Theory and Applications》2022,194(3):1014-1041
Journal of Optimization Theory and Applications - We consider a distributionally robust formulation of stochastic optimization problems arising in statistical learning, where robustness is with... 相似文献
5.
Hua Saixiang Zhu Huichao Wang Xiao Wu Mingyuan Wu Qingyun Liu Jiuyi Yang Jianjun Zhang Jianan 《Cellulose (London, England)》2022,29(13):7465-7475
Cellulose - Ultraviolet (UV) protective cotton fabric is a convenient and reliable way to protect human body from sunlight. Herein, a polymerizable UV-absorber,... 相似文献
6.
This study is to numerically test the interfacial instability of ferrofluid flow under the presence of a vacuum magnetic field. The ferrofluid parabolized stability equations(PSEs) are derived from the ferrofluid stability equations and the Rosensweig equations, and the characteristic values of the ferrofluid PSEs are given to describe the ellipticity of ferrofluid flow. Three numerical models representing specific cases considering with/without a vacuum magnetic field or viscosity are created to mathematically examine the interfacial instability by the computation of characteristic values. Numerical investigation shows strong dependence of the basic characteristic of ferrofluid Rayleigh-Taylor instability(RTI) on viscosity of ferrofluid and independence of the vacuum magnetic field.For the shock wave striking helium bubble, the magnetic field is not able to trigger the symmetry breaking of bubble but change the speed of the bubble movement. In the process of droplet formation from a submerged orifice, the collision between the droplet and the liquid surface causes symmetry breaking. Both the viscosity and the magnetic field exacerbate symmetry breaking. The computational results agree with the published experimental results. 相似文献
7.
Yi-Tong Xu Tian-Yang Zhang Zheng Li Xiang-Nan Liu Yuan-Cheng Zhu Wei-Wei Zhao Hong-Yuan Chen Jing-Juan Xu 《Electroanalysis》2022,34(6):947-955
Photoelectrochemical (PEC) cytosensors, a combination of the PEC process and the living-cell assay, have emerged as a powerful tool in the analytical and biological science. This mini review provides a brief introduction of this arena and summaries the key steps about the development of PEC cytosensors with representative examples, followed by future prospects based on our own opinions. 相似文献
8.
Nonlinear Dynamics - The nonlinear modes of a non-conservative nonlinear system are sometimes referred to as damped nonlinear normal modes (dNNMs). Because of the non-conservative... 相似文献
9.
Kai Cheng Xiao-Shuai Zhang Jie An Cheng Li Ruo-Yun Zhang Run Ye Prof. Dr. Bang-Jiao Ye Prof. Dr. Bo Liu Prof. Dr. Yuan-Di Zhao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(31):7553-7560
Given their superior penetration depths, photosensitizers with longer absorption wavelengths present broader application prospects in photodynamic therapy (PDT). Herein, Ag2S quantum dots were discovered, for the first time, to be capable of killing tumor cells through the photodynamic route by near-infrared light irradiation, which means relatively less excitation of the probe compared with traditional photosensitizers absorbing short wavelengths. On modification with polydopamine (PDA), PDA-Ag2S was obtained, which showed outstanding capacity for inducing reactive oxygen species (increased by 1.69 times). With the addition of PDA, Ag2S had more opportunities to react with surrounding O2, which was demonstrated by typical triplet electron spin resonance (ESR) analysis. Furthermore, the PDT effects of Ag2S and PDA-Ag2S achieved at longer wavelengths were almost identical to the effects produced at 660 nm, which was proved by studies in vitro. PDA-Ag2S showed distinctly better therapeutic effects than Ag2S in experiments in vivo, which further validated the enhanced regulatory effect of PDA. Altogether, a new photosensitizer with longer absorption wavelength was developed by using the hitherto-unexplored photodynamic function of Ag2S quantum dots, which extended and enhanced the regulatory effect originating from PDA. 相似文献
10.
Bingjie Chen Dr. Lianhai Zu Dr. Yao Liu Dr. Ruijing Meng Yutong Feng Prof. Chengxin Peng Feng Zhu Tianzi Hao Jiajia Ru Prof. Yonggang Wang Prof. Jinhu Yang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(8):3161-3166
Incorporating nanoscale Si into a carbon matrix with high dispersity is desirable for the preparation of lithium-ion batteries (LIBs) but remains challenging. A space-confined catalytic strategy is proposed for direct superassembly of Si nanodots within a carbon (Si NDs⊂C) framework by copyrolysis of triphenyltin hydride (TPT) and diphenylsilane (DPS), where Sn atomic clusters created from TPT pyrolysis serve as the catalyst for DPS pyrolysis and Si catalytic growth. The use of Sn atomic cluster catalysts alters the reaction pathway to avoid SiC generation and enable formation of Si NDs with reduced dimensions. A typical Si NDs⊂C framework demonstrates a remarkable comprehensive performance comparable to other Si-based high-performance half LIBs, and higher energy densities compared to commercial full LIBs, as a consequence of the high dispersity of Si NDs with low lithiation stress. Supported by mechanic simulations, this study paves the way for construction of Si/C composites suitable for applications in future energy technologies. 相似文献