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1.
Vinod Kumar Pragya Das R.P. Singh S. Muralithar R.K. Bhowmik 《The European Physical Journal A - Hadrons and Nuclei》2003,17(2):153-157
The fusion evaporation reaction 122Sn(14N, 4n)132La was used to populate the high-spin states of 132La at the beam energy of 60 MeV. A new band consisting of mostly E2 transitions has been discovered. This band has the interesting links to the ground state 2- and the isomeric state 6-. A new transition of energy 351 keV connecting the low-spin states of the positive-parity band based on the πh
11/2 ⊗ νh
11/2 particle configuration, has been found. This has played a very important role in resolving the existing ambiguities and inconsistencies
in the spin assignment of the band head.
Received: 12 August 2002 / Accepted: 18 March 2003 / Published online: 7 May 2003 相似文献
2.
R.G. Abhilash Kumar K. Vinod U. Syamaprasad 《Applied Physics A: Materials Science & Processing》2007,88(2):243-247
MgB2/Fe wires were prepared by electrical self-heating of in situ powder-in-tube wires for the first time at ambient conditions.
Characterization of the wires processed at 750 °C, 800 °C and 850 °C for 15 min by XRD, SEM, ϱ–T, susceptibility and JC measurements shows that the MgB2 formed is of high quality particularly with respect to phase purity and transport JC. The method considerably reduces the overall energy consumption vis-à-vis the production cost, simplifies the complexity
of the fabrication procedure and is promising for manufacture of high-quality MgB2 superconducting wires.
PACS 74.70.Ad; 74.62.Bf; 74.25.Fy; 74.25.Ha; 81.20.Hy 相似文献
3.
4.
R. Venkat narayan Vinod Kanniah Aruna Dhathathreyan 《Journal of Chemical Sciences》2006,118(2):179-184
Cobalt oxides were prepared by three different methods: (1) by reacting cobalt nitrate with oxalic acid, (2) co-precipitating
cobalt nitrate with sodium carbonate, and (3) using sodium dodecyl sulphate as organic surfactant. All three samples were
characterized before and after calcination by solvent extraction and the resulting products examined by IR spectroscopy. In
the case of method 3, the removal of surfactant was followed by TGA studies. Products from all three methods were identified
by XRD. Peaks in low angle XRD indicate the porous nature of the oxides. The morphology of the pores was studied by transmission
electron microscopy. Some irregular pore structures were obtained for samples from methods 1 and 2, with an average size of
4–6 nm. Only the product from method 3 using SDS as template showed ordered structure and optimum size, and Brunauer-Emmet-Teller
surface areas of the as-prepared, as well as the treated samples, exhibited H3 type hysteresis. The samples from the three
methods were used as catalysts in the oxidation reaction of cyclohexane under mild conditions and the catalytic efficiency
of the cobalt oxide was comparable with mesoporous cobalt oxides. 相似文献
5.
Summary Complexes of nickel(II) with N-(2-carboxyphenyl)benzamide (CPBH), 2-amino-N-(2-carboxyphenyl)benzamide (ACPBH), N-isoxazolyl benzamide (IB), N-anilinobenzamide (AB), N-(2-pyridyl)-3-carboxypropanamide (PCPA) and N-(2-pyridyl)-2-carboxybenzamide (PCBA) have been isolated and characterized by elemental analyses, magnetic susceptibility measurements, thermal studies, i.r. and electronic spectral studies. The electrochemical behaviour of some complexes has also been investigated. 相似文献
6.
Total synthesis of (-)-lentiginosine was achieved from D-mannitol using highly stereoselective reactions. Similarly, (+)-lentiginosine was synthesized from L-tartaric acid. 相似文献
7.
The adducts formed from methyl vinyl ketone and the 2-hydromethylene derivatives of cyclooctane and cyclodecanone can be cyclised to spiroketones containing the same number of C atoms. The spiroketone from cyclooctanone possesses a single UV maximum at 227 nm; the cyclodecanone compound has a further absorption at ca 246 nm. The constitution and stereochemistry of the ketols produced from the adducts under mild cyclising conditions have been investigated. 相似文献
8.
Chemometric analysis of groundwater quality data of alluvial aquifer of Gangetic plain, North India 总被引:10,自引:0,他引:10
Kunwar P. Singh Amrita Malik Vinod K. Singh Dinesh Mohan Sarita Sinha 《Analytica chimica acta》2005,550(1-2):82-91
Water quality data set from the alluvial region in the Gangetic plain in northern India, which is known for high fluoride levels in soil and groundwater, has been analysed by chemometric techniques, such as principal component analysis (PCA), discriminant analysis (DA) and partial least squares (PLS) in order to investigate the compositional differences between surface and groundwater samples, spatial variations in groundwater composition and influence of natural and anthropogenic factors. Trilinear plots of major ions showed that the groundwater in this region is mainly of Na/K-bicarbonate type. PCA performed on complete data matrix yielded six significant PCs explaining 65% of the data variance. Although, PCA rendered considerable data reduction, it could not clearly group and distinguish the sample types (dug well, hand-pump and surface water). However, a visible differentiation between the water samples pertaining to two watersheds (Khar and Loni) was obtained. DA identified six discriminating variables between surface and groundwater and also between different types of samples (dug well, hand pump and surface water). Distinct grouping of the surface and groundwater samples was achieved using the PLS technique. It further showed that the groundwater samples are dominated by variables having origin both in natural and anthropogenic sources in the region, whereas, variables of industrial origin dominate the surface water samples. It also suggested that the groundwater sources are contaminated with various industrial contaminants in the region. 相似文献
9.
Summary CuII complexes of the [CuL2(SO4)]·nH2O and [CuL(SO4)(H2O)2]·nH2O type, where L = benzoylhydrazine (PhCONHNH2; BH) or iso-propanone benzoylhydrazone (PhCONHN:CMe2; IBH), L= iso-nicotinoylhydrazine (NC5H4CONHNH2; INH) or isopropanone iso-nicotinoylhydrazone (NC5H4CONHN: CMe2; IINH); n = 0–2, were prepared and characterized by elemental analyses, molar conductances, and electronic, e.s.r. and i.r. spectral measurements. The electronic and e.s.r. spectra suggest a tetragonally distorted octahedral geometry in the solid state as well as in DMSO solution. The e.s.r. data also reveal an axial symmetry for most of the complexes in the solid state and in DMSO solution at 300 and 77 K, while the complex of IBH is isotropic at 300 K. The Ms = 2 transition observed for this complex suggests that it is a dimer. BH and INH bond to CuII through the C-O and NH2 groups, whereas IBH and IINH bond through C-O and C-N groups. 相似文献
10.
Sengupta Soumitra K. Pandey Om P. Srivastava Bimal K. Sharma Vinod K. 《Transition Metal Chemistry》1998,23(4):349-353
The reactions of bis(cyclopentadienyl)titanium(IV)/zirconium(IV) dichloride with a new class of organometallic thiosemicarbazones (LH), derived by condensing acetylferrocene with substituted thiosemicarbazides, have been studied and two types of bimetallic products, viz. [Cp2M(L)Cl] (M = Ti or Zr) and [CpZr(L)3], have been isolated. On the basis of various physicochemical and spectral studies, five- and seven-coordinate structures have been assigned to these derivatives, respectively. Attempts have been made to establish a correlation between biological activity and the structures of the products. 相似文献