排序方式: 共有20条查询结果,搜索用时 140 毫秒
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Ruoyu Hong * Jianmin Ding Guoliang Zheng College of Chemistry Chemical Engineering Soochow University Suzhou P. R. China Institute of Process Engineering Chinese Academy of Sciences Beijing P. R. China IBM HYDA/- C Highway North Rochester MN USA *Author to whom correspondence should be addressed. E-mail: rhong@suda.edu.cn 《中国颗粒学报》2004,2(5):207-214
1. Introduction1.1 Silica nanoparticles and synthesis methods Silica (SiO2) nanoparticles are widely used in industry asan active filler for polymer reinforcement, a rheologicaladditive in fluids, a free flow agent in powders, and anagent for chemical mechanical polishing during IC (inte-grated circuit) fabrication (Sniegowski & de Boer, 2000).Silica powder is also used for producing silicon carbide(Koc & Cattamanchi, 1998) or opaque silica aerosols (Leeet al., 1995). Many methods can … 相似文献
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Herma Dina Setiabudi Sugeng Triwahyono Aishah Abdul Jalil Nur Hidayatul Nazirah Kamarudin Muhammad Arif Ab Aziz 《天然气化学杂志》2011,20(5):477-482
The effect of iridium loading on the properties and catalytic isomerization of n-heptane over Ir-HZSM-5 is studied. Ir-HZSM-5 was prepared by impregnation method and subjected to isomerization process in the presence of flowing hydrogen gas. XRD and BET studies show that the presence of iridium stabilizes the crystalline structure of HZSM-5, leading to more ordered framework structure and larger surface area. TGA and FTIR results substantiate that iridium species interacts with OH group on the surface of HZSM-5. Pyridine FT-IR study verifies the interaction between iridium and surface OH group slightly increased the Bro¨nsted and Lewis acid sites without changing the lattice structure of HZSM-5. The presence of iridium and the increase of strong Lewis acid sites on HZSM-5 were found to bring an increase about 4.1%, 33.2% and 11.8% in conversion, selectivity and yield of n-heptane isomerization, respectively. 相似文献
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Shahrir Razey Sahamir Mohd Faizul Mohd Sabri Mohamand Syafie Mahmood Muhammad Akmal Bin Kamarudin Oussama Moutanabbir 《Liquid crystals》2018,45(4):522-535
The vibrational property of 2,3,6,7,10,11-hexakis(hexyloxy)triphenylene (HAT6) discotic liquid crystal (DLC) material is investigated in this research by using temperature-dependent Raman spectroscopy technique. One-dimensional (1D) charge transport mechanism in the DLC molecules is enabled in the columnar liquid crystalline (Dh) phase. The result indicates a high core-to-core correlation in the liquid crystal columnar phase, which has a ‘memory’ like effect that extends into isotropic phase at femtosecond timescale. This correlation is also confirmed through electrical conductivity measurement of DLCs, in which the electrical conductivity is enhanced in the DLC phase. DFT simulation was also carried out in order to elucidate the basic properties of HAT6 such as the band gap in the light of Raman spectra. An interesting outcome is that a freely unspecified boundary model produces in a more flexible molecule, resulting in a reduced band gap. Thus, this work provides an understanding of relationship between columnar order and electrical conductivity of HAT6 molecule, and potential strategy for design of DLCs in electronics application. 相似文献
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Su Kong Ngien Norhan Abd. Rahman Mustafa M. Bob Kamarudin Ahmad Radzuan Sa’ari Roland W. Lewis 《Transport in Porous Media》2012,92(1):83-100
Physical model experiments were conducted to observe the migration of light non-aqueous phase liquids (LNAPL) in a double-porosity
soil medium. The double-porosity characteristics of the soil were simulated through aggregation of kaolin which resulted in
well-defined intra-aggregate and inter-aggregate pores. Digital images were collected to monitor LNAPL (modeled by toluene)
migration. A special experimental setup was developed to enable the instantaneous capture of the LNAPL migration around the
whole soil column using a single digital camera. An image processing module was applied to the captured images and the results
plotted using a surface mapping programme. Events observed during the duration of the experiments were discussed. It was found
that the LNAPL flowed much faster in the aggregated soil as compared to a single-porosity soil. The wettability of the fluid
and the capillary pressure characteristics were demonstrated to be influential factors in immiscible fluids migration when
the soil fabric showed highly contrasting porosity values. 相似文献
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AH Karim AA Jalil S Triwahyono SM Sidik NH Kamarudin R Jusoh NW Jusoh BH Hameed 《Journal of colloid and interface science》2012,386(1):307-314
In this work, mesostructured silica nanoparticles (MSN(AP)) with high adsorptivity were prepared by a modification with 3-aminopropyl triethoxysilane (APTES) as a pore expander. The performance of the MSN(AP) was tested by the adsorption of MB in a batch system under varying pH (2-11), adsorbent dosage (0.1-0.5gL(-1)), and initial MB concentration (5-60mgL(-1)). The best conditions were achieved at pH 7 when using 0.1gL(-1) MSN(AP) and 60mgL(-1)MB to give a maximum monolayer adsorption capacity of 500.1mgg(-1) at 303K. The equilibrium data were evaluated using the Langmuir, Freundlich, Temkin, and Harkins-Jura isotherms and fit well to the Freundlich isotherm model. The adsorption kinetics was best described by the pseudo-second order model. The results indicate the potential for a new use of mesostructured materials as an effective adsorbent for MB. 相似文献
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In this paper, we consider nonlinear Schrödinger (NLS) equations, both in the anomalous and normal dispersive regimes, which govern the propagation of a single field in a fiber medium with phase modulation and fibre gain (or loss). The integrability conditions are arrived from linear eigen value problem. The variable transformations which connect the integrable form of modified NLS equations are presented. We succeed in Hirota bilinearzing the equations and on solving, exact bright and dark soliton solutions are obtained. From the results, we show that the soliton is alive, i.e. pulse area can be conserved by the inclusion of gain (or loss) and phase modulation effects. 相似文献
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Muhammad Akmal Kamarudin Ammar A. Khan Suhana Mohd Said Malik M. Qasim Timothy D. Wilkinson 《Liquid crystals》2018,45(1):112-121
The doping of polymer electrolytes (PEs) with liquid crystal (LC) materials has been shown to improve the performance of dye-sensitised solar cells (DSSCs). This is achieved by promoting ionic conduction and increasing optical path length through multiple-light scattering within the photovoltaic devices. In LCs, it is well known that the length of the alkyl chain plays an important role since the LC morphology and mesophase stabilisation depend strongly on the alkyl group. In this work, liquid crystal-polymer composite electrolytes (LC-PEs) are prepared using nematic LCs with different alkyl chain lengths. The morphology of the LC-PEs is investigated and correlated with their electrical properties. Subsequently, DSSCs are prepared using the LC-PEs as a direct example of its application. It is shown that increasing the alkyl chain length of the LCs reduces the efficiency of the solar devices. The longer alkyl chains are speculated to intertwine, thus trapping the mobile ions and reducing the bulk ionic conductivity. For the same reason, longer alkyl chain LCs are thought to be unable to passivate the TiO2 surface through the adsorption of cyanobiphenyl groups and hence the higher probability of back recombination reaction between the electrons in TiO2 and PE. 相似文献