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Budnikova Yu. H. Kafiyatullina A. G. Sinyashin O. G. Abdreimova R. R. 《Russian Chemical Bulletin》2003,52(4):929-938
In the presence of white phosphorus the redox potentials of the copper ions change and the potential of the reduction wave of CuI/Cu0 shifts noticeably toward more positive values. The CuI—P4 complex is characterized by a lower value of the electrochemical gap, that is, higher polarizability and reactivity compared to those of the free CuI cation. Phosphorus esters can be synthesized from P4 and ethanol. The latter is in the composition of the copper(ii) complexes, which act as a catalyst-charge mediator. 相似文献
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Yu. G. Budnikova A. G. Kafiyatullina Yu. M. Kargin O. G. Sinyashin 《Russian Chemical Bulletin》2003,52(7):1504-1511
Electrochemical reduction of cobalt(ii) complexes containing -acceptor ligands (L = bpy, Ph2Ppy) proceeds through three consecutive reversible steps: one-electron transfer to form a more stable CoIL complex, transfer of two electrons at more negative potentials to form an anionic [NiL]– complex, and reduction of the ligand to the radical anion. The stability of the cobalt complexes with different ligands decreases in the series Ph2Ppy > Ph3P > bpy. 相似文献
3.
Budnikova Yu. G. Kafiyatullina A. G. Kargin Yu. M. Sinyashin O. G. 《Russian Journal of General Chemistry》2001,71(2):231-233
Organic halides undergo electrocatalytic reduction under the action of coordinately unsaturated with respect to 2,2'-bipyridine (bipy) complexes Co+
1bipy (at the first wave potentials) and coordinately saturated complexes Co-
1bipy2
- (at the second wave potentials). The logarithms of the apparent rate constants logk
a
p
p decrease with increasing difference in the reduction potentials of substrate and catalyst E
p
A-RX over a wide range of the motive forces of the process. 相似文献
4.
Budnikova Yu. H. Kafiyatullina A. G. Kargin Yu. M. Sinyashin O. G. 《Russian Chemical Bulletin》2002,51(9):1702-1708
The electrocatalytic reduction of organic halides by the [Nibpy]+complexes coordinationally unsaturated with bpy (at potentials of the first wave) and by the coordinationally saturated [Nibpy2]–complexes (at potentials of the second wave) was observed. The apparent rate constant of the process decreased with an increase in the difference of the reduction potentials of the substrate and catalyst in a large range of the driving force of the process. 相似文献
5.
Zagidullin A. A. Ganushevich Yu. S. Kafiyatullina A. G. Miluykov V. A. Sinyashin O. G. 《Russian Chemical Bulletin》2015,64(8):1986-1988
Russian Chemical Bulletin - The cycloaddition of 1-ethyl-3,4,5-triphenyl-1,2-diphosphacyclopenta-2,4-diene to acetylenes R1C≡CR2 (R1 = R2 = CO2Me; R1 = Ph, R2 = H) gives phosphinine along... 相似文献
6.
Yu. G. Budnikova D. I. Tazeev A. G. Kafiyatullina D. G. Yakhvarov V. I. Morozov N. K. Gusarova B. A. Trofimov O. G. Sinyashin 《Russian Chemical Bulletin》2005,54(4):942-947
Routes of white phosphorus activation in the coordination sphere of the nickel complexes with different ligands are shown.
The first route is based on the coordination of a P4 molecule with the metal, resulting in the deformation of the P4 tetrahedron without destruction. This case is characteristic of the NiX2L complexes, which are reduced at higher cathodic potentials (|Ered| > 0.9 V) (X = BF4, Br, and Cl; L is bpy in DMF, MeCN, and acetone; 2,9-dimethyl-1,10-phenanthroline (phen) and PPh3 in DMF and acetone). To cleave the P—P bonds in the P4 molecule, this complex should be reduced on the electrode. The second route is the oxidation of white phosphorus in the coordination
sphere of the NiII complex. It occurs when the complex has a sufficiently high oxidizing ability and is reduced rather easily (|Ered| < 0.9 V) (X = BF4, L is 1,1,1-tris(diphenylphosphinomethyl)ethane (triphos) in acetone; 1,1′,5,5′-bis[methylenedi(p-phenylene)]di(3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) (n2p2) in DMF; phen and PPh3 in MeCN). The P4 molecule opening is observed to form a new NiI complex containing the (P3) fragment, for example, [(triphos)Ni(P3)Ni(triphos)](BF4)2.
Dedicated to the Academician V. I. Minkin on the occasion of his 70th birthday.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 919–924, April, 2005. 相似文献
7.
Budnikova Yu. H. Kafiyatullina A. G. Balueva A. S. Kuznetsov R. M. Morozov V. I. Sinyashin O. G. 《Russian Chemical Bulletin》2003,52(11):2419-2423
Oxidation of white phosphorus in the coordination sphere of the nickel(ii) complex with 1,1,1-tris(diphenylphosphinomethyl)ethane and 1,1",5,5"-bis[methylenedi(p-phenylene)]di(3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) was shown to be possible and accompanied by the transformation of P4 into the -P3 ligand. The change in the nickel state was monitored by cyclic voltammetry, 31P NMR spectroscopy, ESR, and IR spectroscopy. 相似文献
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