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排序方式: 共有77条查询结果,搜索用时 15 毫秒
1.
G. Garcia-Belmonte J. Bisquert L. M. Navarro J. R. Jurado F. M. B. Marques 《Ionics》1995,1(5-6):377-383
In ionic conductors, long range-migrating charges are a main cause of polarization processes. This has complicated, up to
date, the study of ionic thermocurrents (ITC) in solid electrolytes. However, the method is appealing, as it probes directly
charge-formation phenomena that are important both from a scientific point of view and for applications.
This work reports on the observation of ITC in solid electrolytes. Under appropriate experimental conditions, the ITC response
of a zirconia sample electroded with platinum is a reproducible one, thus opening the way to a new characterization method
that may complement other well established methods, such as Impedance Spectroscopy and a number of electrochemical techniques.
The general trends of the response, which is composed of two well resolved ITC peaks, is discussed. One of them, taking place
at higher temperatures, conforms to the standard shape of a first order kinetics depolarization process.
Paper presented at the 2nd Euroconference on Solid State Ionics, Funchal, Madeira, Portugal, Sept. 10–16, 1995 相似文献
2.
J. Fontcuberta J. Jurado X. Obradors M. V. Cabañas M. Vallet J. M. Gonzalez-Calbet 《Zeitschrift für Physik B Condensed Matter》1992,87(1):21-28
This paper reports a detailed study of the electrical transport properties of good quality superconducting Y0.5Sm0.5Ba2Cu3O7 ceramic samples. Analyses of the dependence of resistance on temperature, the relations current-voltage and the magnetoresistance allows to identify:a) the mean field critical temperature (T
CO
=93.73±0.01 K);b) a power law behaviorVI
atT
CO
. The exponent jumps abruptly from 1 to 3, at a certain temperatureT
C
=93.276±0.005 K;c) an exponential inverse root-square temperature dependence of the resistivity in theT
C–T
CO
temperature range. These features, typically observed when topological excitations sets in two dimensional systems, can also be interpreted as a signature of a percolation process and a transition towards intergranular phase coherence. We analyze and discuss the relevance of both models to account for the experimental data. 相似文献
3.
Supercritical fluid chromatography with photodiode array detection for pesticide analysis in papaya and avocado samples 下载免费PDF全文
Norma S. Pano‐Farias Silvia G. Ceballos‐Magaña Jorge Gonzalez José M. Jurado Roberto Muñiz‐Valencia 《Journal of separation science》2015,38(7):1240-1247
To improve the analysis of pesticides in complex food matrices with economic importance, alternative chromatographic techniques, such as supercritical fluid chromatography, can be used. Supercritical fluid chromatography has barely been applied for pesticide analysis in food matrices. In this paper, an analytical method using supercritical fluid chromatography coupled to a photodiode array detection has been established for the first time for the quantification of pesticides in papaya and avocado. The extraction of methyl parathion, atrazine, ametryn, carbofuran, and carbaryl was performed through the quick, easy, cheap, effective, rugged, and safe methodology. The method was validated using papaya and avocado samples. For papaya, the correlation coefficient values were higher than 0.99; limits of detection and quantification ranged from 130–380 and 220–640 μg/kg, respectively; recovery values ranged from 72.8–94.6%; precision was lower than 3%. For avocado, limit of detection values were ?450 μg/kg; precision was lower than 11%; recoveries ranged from 50.0–94.2%. Method feasibility was tested for lime, banana, mango, and melon samples. Our results demonstrate that the proposed method is applicable to methyl parathion, atrazine, ametryn, and carbaryl, toxics pesticides used worldwide. The methodology presented in this work could be applicable to other fruits. 相似文献
4.
Ángela Martínez‐Peragón Dr. Delia Miguel Rocío Jurado Dr. José Justicia Prof. José M. Álvarez‐Pez Dr. Juan M. Cuerva Dr. Luis Crovetto 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(2):447-455
9‐Alkyl xanthenones with different aliphatic pendant groups have been easily prepared by means of nucleophilic addition of the corresponding Grignard derivative to a tert‐butyldimethylsilyl ether (TBDMS)‐protected 3,6‐dihydroxy‐xanthenone. The photophysical behavior of the new dyes has been explored by using absorption, steady‐state‐, and time‐resolved fluorescence measurements. We determined the equilibrium constants, visible spectral characteristics, fluorescence quantum yield, and decay times. Remarkably, they retain similar fluorescent properties of fluorescein including the characteristic phosphate‐mediated excited‐state proton‐transfer (ESPT) reaction. 6‐Hydroxy‐9‐isopropyl‐3H‐xanthen‐3‐one ( 5 ) was investigated in living cells; it presented a good permeability and efficient accumulation inside the cytosol. For the first time, we reported that the requirement of an aryl group at C‐9 is no longer needed and new fluorescent sensors can be therefore easily developed. 相似文献
5.
Human Y‐chromosome SNP characterization by multiplex amplified product‐length polymorphism analysis 下载免费PDF全文
Laura Smeldy Jurado Medina Marina Muzzio Marisol Schwab María Leticia Bravi Costantino Guillermo Barreto Graciela Bailliet 《Electrophoresis》2014,35(17):2524-2527
We designed an allele‐specific amplification protocol to optimize Y‐chromosome SNP typing, which is an unavoidable step for defining the phylogenetic status of paternal lineages. It allows the simultaneous highly specific definition of up to six mutations in a single reaction by amplification fragment length polymorphism (AFLP) without the need of specialized equipment, at a considerably lower cost than that based on single‐base primer extension (SNaPshot?) technology or PCR‐RFLP systems, requiring as little as 0.5 ng DNA and compatible with the small fragments characteristic of low‐quality DNA. By designation of two primers recognizing the derived and ancestral state for each SNP, which can be differentiated by size by the addition of a noncomplementary nucleotide tail, we could define major Y clades E, F, K, R, Q, and subhaplogroups R1, R1a, R1b, R1b1b, R1b1c, J1, J2, G1, G2, I1, Q1a3, and Q1a3a1 through amplification fragments that ranged between 60 and 158bp. 相似文献
6.
J. Benlliure T. Kurtukian-Nieto L. Audouin B. Blank F. Becker E. Casarejos D. Cortina M. Fernández-Ordóñez J. Giovinazzo D. Henzlova B. Jurado J. Pereira F. Rejmund K.-H. Schmidt O. Yordanov 《The European physical journal. Special topics》2007,150(1):309-310
The production of heavy neutron-rich nuclei is investigated using cold-fragmentation reactions.
More than 25 new heavy neutron-rich nuclei were produced in the fragmentation of 208Pb projectiles at 1 A GeV impinging a
beryllium target. The precise measurement of their production cross sections enables to benchmark the predictive power of
different
model calculations and make reliable predictions of the production rates expected in future radioactive beam facilities. 相似文献
7.
A. Gillibert A. Obertelli N. Alamanos M. Alvarez F. Auger R. Dayras A. Drouart G. de France B. Jurado N. Keeley V. Lapoux W. Mittig X. Mougeot L. Nalpas A. Pakou N. Patronis E. Pollacco F. Rejmund M. Rejmund P. Roussel-Chomaz H. Savajols F. Skaza Ch. Theisen 《The European physical journal. Special topics》2007,150(1):161-163
27Ne has been investigated through the one neutron transfer reaction 26Ne(d,p)27Ne in inverse
kinematics at 9.7 MeV/nucleon. The results support the existence of a low lying negative parity state
in 27Ne which is a signature of a reduced sd-fp shell gap in the N = 16 neutron rich region, at variance
with stable nuclei. 相似文献
8.
Jurado C Pedersen CS Moore BC 《The Journal of the Acoustical Society of America》2011,129(5):3166-3180
Psychophysical tuning curves (PTCs) were measured for sinusoidal signals with frequency f(s)?= 31.5, 40, 50, 63, and 80 Hz, using sinusoidal and narrowband-noise maskers. For the former, conditions were included where a pair of beating tones was added to reduce the use of cues related to beats. Estimates of each subject's middle-ear transfer function (METF) were obtained from equal-loudness contours measured from 20 to 160 Hz. With decreasing f(s), the PTCs became progressively broadened and markedly asymmetrical, with shallow upper skirts and steep lower skirts. For the sinusoidal maskers, the tips were more irregular than for narrowband-noise maskers or when beating tones were added. For f(s)?= 31.5 and 40 Hz, the tips of the PTCs always fell above f(s). Allowing for the METF so as to infer underlying filter shapes resulted in flatter lower skirts, especially below 40 Hz, and reduced the frequency at the tips for f(s) between 31.5 and 50 Hz; however, the tips did not fall below 40 to 50 Hz. The bandwidths of the PTCs increased with decreasing f(s) below 80 Hz. However, bandwidths remained roughly constant if the METF was included as part of auditory filtering for frequencies below 40 Hz. 相似文献
9.
D. Boilley A. Marchix B. Jurado K. -H. Schmidt 《The European Physical Journal A - Hadrons and Nuclei》2007,33(1):47-52
We propose a new formula for the saddle-to-scission time that is more general that the one based on Kramers' approach. Its
validity and applicability is then studied in detail. Such a formula is useful for the evaluation of the fission time of very
heavy nuclei. 相似文献
10.
JOSEF MÁLEK JINDŘICH NEČAS K. R. RAJAGOPAL 《Archive for Rational Mechanics and Analysis》2002,165(3):243-269
To describe the flows of fluids over a wide range of pressures, it is necessary to take into account the fact that the viscosity
of the fluid depends on the pressure. That the viscosity depends on the pressure has been verified by numerous careful experiments.
While the existence of solutions local-in-time to the equations governing the flows of such fluids are available for small,
special data and rather unrealistic dependence of the viscosity on the pressure, no global existence results are in place.
Our interest here is to establish the existence of weak solutions for spatially periodic three-dimensional flows that are
global in time, for a large class of physically meaningful viscosity-pressure relationships.
(Accepted May 1, 2002) Published online November 15, 2002
Communicated by S. S. ANTMAN 相似文献