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排序方式: 共有195条查询结果,搜索用时 31 毫秒
1.
Veličković Jelena Đ. Andrić Deana Roglić Goran Tešic Živoslav Lj. Milojković-Opsenica Dušanka M. 《平面色谱法杂志一现代薄层色谱法》2004,17(4):255-260
JPC – Journal of Planar Chromatography – Modern TLC - The chromatographic behavior of fourteen 1-arylpiperazine derivatives has been studied by thin-layer chromatography on both silica... 相似文献
2.
Veli B. Shakhmurov 《Journal of Mathematical Analysis and Applications》2007,327(2):1182-1201
The nonlocal boundary value problems for anisotropic partial differential-operator equations with a dependent coefficients are studied. The principal parts of the appropriate generated differential operators are nonself-adjoint. Several conditions for the maximal regularity and the fredholmness in Banach-valued Lp-spaces of these problems are given. These results permit us to establish that the inverse of corresponding differential operators belongs to Schatten q-class. Some spectral properties of the operators are investigated. In applications, the nonlocal BVP's for quasielliptic partial differential equations and for systems of quasielliptic equations on cylindrical domain are studied. 相似文献
3.
Veli B. Shakhmurov 《Journal of Mathematical Analysis and Applications》2004,292(2):605-620
This study focuses on nonlocal boundary value problems (BVP) for degenerate elliptic differential-operator equations (DOE), that are defined in Banach-valued function spaces, where boundary conditions contain a degenerate function and a principal part of the equation possess varying coefficients. Several conditions obtained, that guarantee the maximal Lp regularity and Fredholmness. These results are also applied to nonlocal BVP for regular degenerate partial differential equations on cylindrical domain to obtain the algebraic conditions that ensure the same properties. 相似文献
4.
D. M. Petrović-Djakov J. M. Filipović Lj. P. Vrhovac J. S. Veličković 《Journal of Thermal Analysis and Calorimetry》1996,46(6):1681-1686
The kinetics of the AIBN-initiated free radical bulk polymerization of fiveo-alkylphenyl methacrylates was studied by means of DSC in the temperature range 353–373 K, and the enthalpy of polymerization, the overall reaction rate constant and the activation energy were determined. The results were compared with those published recently on correspondingp-alkylaryl methacrylates. All measured reaction rate constants were found to increase with increasing temperature and to decrease with increasingo-alkyl substituent mass and size. It was shown thato-substituents influence the rates of polymerization to a greater extent thanp-substituents. At about 373 K, all differences in rate, most probably resulting from steric hindrance caused by the alkyl groups, disappear in both series, a phenomenon earlier observed for dimethyl phenyl methacrylates.This work was supported by the Ministry of Science of the Republic of Serbia. 相似文献
5.
Daniel R. Coulter Ranty H. Liang Salvador Di Stefano Jovan Moacanin Amitava Gupta 《Chemical physics letters》1982,87(6):594-598
Transient emission studies following pulse radiolysis of solid poly(1-vinyl naphthalene) show existence of excited monomers and two excimers. Quenching experiments indicate that excimers are not formed directly by recombination of ions but probably by trapping of migrating monomeric excitation in performed traps whose density is approximately one in 103. 相似文献
6.
New bidentate N-(2,6-di-phenyl-1-hydroxyphenyl) salicylaldimines bearing X = H and 3,5-di-t-butyl substituents on the salicylaldehyde ring, L
x
H, and their copper(II) complexes, Cu(L
x
)2, have been synthesized and characterized by i.r., u.v./vis., 1H-n.m.r., 13C-n.m.r., e.s.r. spectroscopy and magnetic susceptibility measurements. E.s.r. study has shown that chemical oxidation of Cu(L
x
)2 with PbO2 produces ligand-centered CuII-phenoxyl radical species. The complexes are easily reduced with PPh3
via intramolecular electron transfer from ligand to copper(II) to give unstable radical intermediates, which in time are converted to another stable secondary radical species. The analysis of e.s.r. spectra of Cu(L
x
)2 and generated radical intermediates are presented. 相似文献
7.
The quantitative electrochemical generation of bromine at a platinum electrode in acetic acid is described. Coulometric methods for the determination of hydroquinone and 2-methylhydroquinone are reported. The best results are obtained with 0.7–1.1 M potassium acetate solutions as supporting electrolyte, and biamperometric end-point detection. The effects of water and acetic anhydride on the accuracy of titrations are discussed. Determination of the formal redox potential of the Br2/Br- system in a 0.9 M potassium acetate solution in acetic acid showed that bromide is oxidized directly to bromine at a platinum electrode with 100% current efficiency. 相似文献
8.
Kasumov VT Köksal F 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(6):1151-1160
The synthesis, spectroscopy, and redox-reactivity towards PPh(3) of bis(3,5-di-t-butyl-1,2-benzoquinone 1-oximato)manganese(II), Mn(ox)(2), and its mixed-ligand complexes, Mn(ox)L(x) [L(x)=8-hydroxyquinolinato (L(1)), 2,2'-bipyridine (bpy) (L(2)), 1,10-Phenanthroline (phen) (L(3)) and N-(2-hydroxyphenyl)-3,5-di-t-butylsalicylaldiminato (L(4))] complexes, are presented. While some complexes exhibit solid-state ESR spectra they were ESR-silent in toluene or CHCl(3) at 300 K. The reduction of all ESR-silent complexes with an excess of PPh(3), independently from the nature of secondary L(x) ligands, results in the appearance of a six-line hyperfine coupling of 55Mn (I=5/2) (A(Mn)=95-100 G) and a seven-line radical signal, which was assigned to phosphiniminophenoxyl type radicals (g=2.0056-2.0075, A(P)=8. 5 G and A(N)=1.875 G). 相似文献
9.
The preparation and spectroscopic characterization of a series of new bis[N-(2,6-di-t-butyl-1-hydroxyphenyl)salicylaldiminato]nickel(II) complexes, [Ni(LX)2], bearing one or two OH and MeO substituents on the salicylaldehyde moiety, as well as radical species generated from these compounds by the oxidation with PbO2, are reported. The [Ni(LX)2] chelates, which appear to be tetrahedral in the solid state and in dioxane solution, are converted into a square-planar configuration in non-donor solvents. The OH-substituted complexes, unlike their MeO analogues, form six-coordinate adducts in pyridine, DMF and DMSO. These new compounds, unlike their analogues with electron-withdrawing substituents (Cl, Br, NO2), are easily oxidized by PbO2 to produce NiII-stabilized phenoxy radicals in which the unpaired electrons are delocalized over the ligand and do not couple with the second radical center. No e.s.r. signals were observed that could be attributed to a M = ±2 transition of the triplet state biradicals. 相似文献
10.
Matilda Vojnović Ana J. Šetrajčić-Tomić Siniša M. Vučenović Jovan P. Šetrajčić 《Optical and Quantum Electronics》2018,50(4):198
Recent research in nano-optical engineering and in nanomedicine as well, seeks for methods of construction of various types of nano-markers, nano-carriers, and ways to deliver drugs to the exactly determined regions of body. In this process it is important to find methods of recognition of certain types of molecules. It is obvious that optical recognition would be the easiest and the most effective way to do it. Our research presents a model of a molecular ultrathin crystalline film and generated exciton system inside it and corresponding methodology of analysis of their optical characteristics. Properties of these spatially very restricted structures are very sensitive to their surrounding surfaces. Using the two-time Green’s functions adapted for crystalline structures with symmetry breaking, and graphical-numerical software, we have calculated the energy spectra and possible exciton states. We have shown that the appearance and the presence of localized states on the surfaces and in the boundary layers of the film depend on the thickness of the film and the film surroundings, presented through the perturbation of parameters on surfaces. Optical properties in these structures demonstrate discrete and very selective resonant absorption spectra, depending on the perturbation on their surfaces. 相似文献