负动量压缩因子的环形对撞机磁聚焦结构的研究

探讨了设计负动量压缩因子(α_p<0)的正负电子对撞机储存环磁聚焦结构的可行性及方法.作为应用实例,说明了设计α_p<0的τ–粲工厂磁聚焦结构的可能性.     

Highly selective glycine phase-transfer catalysis using fluoroanthracenylmethyl cinchonidine catalysts

Fluoroanthracenylmethyl cinchonidine phase-transfer catalysts have been produced and explored for asymmetric glycine alkylation. The fluoroanthracenylmethyl precursors were made from aryloxazolidinones and aldehydes using an efficient electrophilic substitution with phosphorous pentoxide. The cinchonidine catalysts promote highly selective glycine alkylation under mild conditions. The 1,8-difluoroanthracenyl-10-methyl catalyst 6 (10 mol %) in toluene/THF with 50% aqueous KOH (−20 °C) promoted benzylation of glycine 1 to give 2 in 86% yield, 98% ee. Other electrophiles also gave excellent selectivity and reactivity.     

作图法处理数据及其不确定度的评定

作图法处理数据是大学物理实验训练内容之一。本文强调了作图法的作用与优点,较详尽的说明了作图法的具体规范以及如何用图线上的直线与斜率导出物理量的方法,最后给出作图法处理数据不确定度的一般方法。     

Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions

[reaction: see text] Catalyst formed from N,N-bis(2,6-diisopropylphenyl)dihydroimidazolium chloride and palladium(II) acetate (2 mol %) was used, without added base, to efficiently produce Heck coupled products with olefins and aryl diazonium tetrafluoroborate substrates. The reactions were performed at room temperature, giving product in 2-4 h with 80-90% yields for isolated materials. Diazonium ions, formed in situ directly from anilines, also couple under these conditions.     

衍射极限储存环物理设计研究进展

总结了国内外在衍射极限储存环(DLSR)物理设计方面的研究进展。为了在合理的周长范围内实现超低束流发射度,DLSR线性束流光学设计普遍采用紧凑型多二极铁消色散结构。在非线性动力学优化中,通常采用相移控制技术、解析和数值优化技术减小由色品六极铁导致的强非线性效应。DLSR束流接受度较小,主要考虑脉冲多极铁偏轴注入和快速冲击磁铁在轴注入两种注入方案。束流集体效应(尤其是束流内部散射和托歇克散射效应)随发射度降低而增强,需要采用束长拉伸、横向反馈等方法提高DLSR中束流的稳定性。     

An enhanced poly(vinylidene fluoride) matrix separator with high density polyethylene for good performance lithium ion batteries

A sponge-like poly(vinylidene fluoride)/high density polyethylene (PVDF/HDPE) separator exhibiting high ionic conductivity and transference number of Li⁺ ion for lithium ion battery has been prepared by non-solvent induced phase separation (NIPS) method. HDPE fillers with size smaller than 250 nm are prepared with moderated reverse phase emulsion. The ion conductivity of PVDF/HDPE separator saturated with 1.0 M LiPF₆–ethylene carbonate (EC)/dimethyl carbonate (DMC)/ethyl methyl carbonate (EMC) (1:1:1, v/v/v) can be up to 2.54 mS cm^?1 at 25 °C, which is higher than that of pristine PVDF separator (1.85 mS cm^?1). The transference number of lithium ion with PVDF/HDPE separator is 0.495, better than that with commercial PP separator (0.33) and pristine PVDF separator (0.27). What is more, LiCoO₂/Li cells assembled with PVDF/HDPE separator show good C-rate and cycling performance which indicates great potential in serving as a good candidate of polymer separator for lithium ion batteries application.     

负动量压缩因子磁聚焦结构在τ–粲工厂储存环设计中的应用

研究并提出了一个负动量压缩因子(α_p<0)τ–粲工厂储存环磁聚焦结构.对其束团拉伸的计算表明:在设计流强,束团长度将比自然束长短,束团长度不会拉伸.     

北京τ─粲工厂储存环磁聚焦结构的设计研究

对北京τ－粲工厂（BTCF）储存环磁聚焦结构设计中所涉及的一些关键物理问题作了探讨和研究，提出了可行性的方案．该方案的高亮度模式动力学孔径较大；单色模式的托歇克寿命较长、亮度较高；并且能兼容纵向极化束对撞模式．     

An enhanced poly(vinylidene fluoride) matrix separator with TEOS for good performance lithium-ion batteries

The low crystallinity poly(vinylidene fluoride)/tetraethyl orthosilicate silane (PVDF/TEOS) composite separator with a finger-like pore structure for lithium-ion battery has been successfully prepared by non-solvent-induced phase separation (NIPS) technique. The PVDF/TEOS composite separator shows the excellent wettability and electrolyte retention properties compared with Celgard 2320 separator. AC impedance spectroscopy results indicate that the novel PVDF/TEOS composite separator has ion conductivity of 1.22 mS cm⁻¹ at 25 °C, higher than that of Celgard 2320 separator (0.88 mS cm⁻¹). The lithium-ion transference number of PVDF composite separator added 0.7% TEOS was 0.481, better than that of Celgard 2400 (0.332). What is more, the lithium-ion batteries assembled with PVDF/TEOS composite separator show good cycling performance and rate capability.