A guide to use fluorinated aromatic bulky cations for stable and high-performance 2D/3D perovskite solar cells: The more fluorination the better?

While serious stability issues impede the commercialization of perovskite solar cells(PSCs),twodimensional(2 D) perovskites based on fluorinated bulky cations have emerged as more intrinsically stable materials.However,the influence of fluorination degree of the bulky aromatic cation on the performance of resulting PSCs has not been scrutinized.Here,2 D perovskites(FxPEA)2 PbI₄(x=1,2,3,5) are grown in situ on the surface of the three-dimensional(3 D) perovskite and demonstrate effecti...     

Forelli-Rudin type theorem in pluriharmonic Bergman spaces with small index

It is proved that the Bergman type operatorT, is a bounded projection from the pluriharmonic Bergman spaceL ^p (B)∩h(B) onto Bergman spaceL ^p (B) ∩ H(B) for 0p 1 ands (p¹-1)(n+1). As an application it is shown that the Gleason’s problem can be solved in Bergman space L^P(B)∩H(B) for 0p 1. Project supported by the National Natural Science Foundation of China (Grant No. 19871081) and the Doctoral Program Foundation of the State Education Commission of China.     

Coefficient multipliers of mixed norm space in the ball Dedicated to Professor Sheng GONG on the occasion of his 75th birthday

In the paper, we characterize the coefficient multiplier spaces of mixed norm spaces (Hp,q((?)1),Hu,v((?)2)) for the values of p, q, u, v in three cases: (i)0相似文献   

Singular Integrals in Several Complex Variables (I)—Henkin Integrals of Strictly Pseudoconvex Domain

对于多复变数强拟凸域的Henkin-Ramirez核或Stein-Kerzman核所定义的Cauchy型积分，本文指出：可以有多种形式的Plemelj公式，甚至Cauchy型积分的极限值可以等于某种Cauchy主值，这些都显示了多复变数函数与单复变数函数本质上的不同。     

Gleason’s problem in weighted Bergman space on egg domains

It is shown that on the egg domains:

High-performance Pt-NiO nanosheet-based counter electrodes for dye-sensitized solar cells

High-performance counter electrodes for dye-sensitized solar cells (DSSCs) are fabricated with platinum-nickel oxide (Pt-NiO) nanosheets as catalytic materials. Firstly, the Pt-Ni nanosheets are synthesized via galvanic replacement reaction between pre-synthesized Ni nanosheets and an aqueous H₂PtCl₆ solution. Secondly, after thermal treatment in air, the Pt-Ni alloys are turned to Pt-NiO nanosheets. The related data of cyclic voltammetry, electrochemical impedance spectroscopy, and Tafel polarization reveal that Pt-NiO counter electrodes show highly catalytic activity and low charge transfer resistance. The DSSC with Pt-NiO counter electrode exhibits power conversion efficiency (PCE) of 8.40 %, which is lower than that of the DSSC containing commercial available Pt counter electrode (9.15 %) under full sunlight illumination (100 mW cm^?2, AM1.5G). However, owing to the extremely high transparency of Pt-NiO counter electrode, when putting an Ag mirror behind the back side of the DSSC, the reflected light can bring great enhanced PCE (11.27 %).     

Preparation of (KBr‐KCl)(OH−):(F2+)H color center laser crystal series and their spectral characteristics

In order to adjust and broaden the absorption spectrum and emission spectrum of the (F₂⁺)H type color center so as to match up to the pumping and to fit in with the demand of application, a (KBr‐KCl)(OH⁻):(F₂⁺)H color center laser crystal series was prepared by the process of single crystal growth, additive coloration, anneal, and light aggregation at 290 K and 77 K. The spectral characteristics of (KBr‐KCl)(OH⁻) crystals are investigated. It is found that the absorption and emission band of the (F₂⁺)H color centers in KBr‐KCl complex host crystals has a considerable adjustment and extensions compared to the color centers in single KBr or KCl crystal. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Bergman type operators on a class of weakly pseudoconvex domains

A necessary and sufficient condition for the boundedness of the operator: $(T_{s,u,u} f)(\xi ) = h^{u + \tfrac{v}{a}} (\xi )\smallint _{\Omega _a } h^s (\xi ')K_{s,u,v} (\xi ,\xi ')f(\xi ')dv(\xi ') on L^p (\Omega _a ,dv_\lambda ),1< p< \infty $ , is obtained, where $\Omega _a = \left\{ {\xi = (z,w) \in \mathbb{C}^{n + m} :z \in \mathbb{C}^n ,w \in \mathbb{C}^m ,|z|^2 + |w|^{2/a}< 1} \right\},h(\xi ) = (1 - |z|^2 )^a - |w|^2 $ andK _x,u,v (ξ,ξ′).This generalizes the works in literature from the unit ball or unit disc to the weakly pseudoconvex domain ω _a . As an appli cation, it is proved thatf?L _H ^p (ω _a ,dv _λ) implies $h\tfrac{{|a|}}{a} + |\beta |(\xi )D_2^a D_z^\beta f \in L^p (\Omega _a ,dv_\lambda ),1 \leqslant p< \infty $ , for any multi-indexa=(α₁,?,α _n and ß = (ß₁, —ß). An interesting question is whether the converse holds.     

Localized Ligands Assist Ultrafast Multivalent-Cation Intercalation Pseudocapacitance

Rechargeable batteries based on multivalent cation (Mvⁿ⁺, n>1) carriers are considered potentially low-cost alternatives to lithium-ion batteries. However, the high charge-density Mvⁿ⁺ carriers generally lead to sluggish kinetics and poor structural stability in cathode materials. Herein, we report an Mvⁿ⁺ storage via intercalation pseudocapacitance mechanism in a 2D bivalve-like organic framework featured with localized ligands. By switching from conventional intercalation to localized ligand-assisted-intercalation pseudocapacitance, the organic cathode exhibits unprecedented fast kinetics with little structural change upon intercalation. It thus enables an excellent power density of 57 kW kg⁻¹ over 20000 cycles for Ca²⁺ storage and a power density of 14 kW kg⁻¹ with a long cycling life over 45000 cycles for Zn²⁺ storage. This work may provide a largely unexploited route toward constructing a local dynamic coordination microstructure for ultrafast Mvⁿ⁺ storage.