Highly efficient and narrowband blue light-emitting performance is extremely crucial for the optoelectronic applications of organic-inorganic hybrid perovskites. However, the not yet viable approach has been shown to simultaneously improve photoluminescence quantum yield (PLQY) and narrow linewidth of blue light emission. Herein, a new crystal rigidifying strategy is proposed as a viable dual-optimization avenue. Specifically, we perform a post-synthetic technique on hybrid cadmium halides and successfully convert zero-dimensional (0D) DMP-0-CdBr4 to one-dimensional (1D) DMP-1-CdBr3, accompanied by luminescent transformation from sky-blue (470 nm) to deep-blue (432 nm) emissions. The structural evolution from discrete block to infinite chain significantly enhances the crystal rigidity, which results in narrower emission linewidth (89 to 50 nm) and increased color purity (74.5% to 96.7%). Synchronously, the PLQY also realizes a notable enhancement from 14.0% to 52.3%. Systematical characterizations demonstrate that enhanced crystal rigidity simultaneously weakens the electron-phonon interaction and slows down nonradiative decay, which narrows the emission linewidth and boosts the PLQY. The highly efficient light-emitting performance enables them as excellent down-conversion blue phosphors to fabricate solid-state LED giving bright warm white light with high color rendering index of 95.4. This work paves a novel structural optimization way to rationally design or fine-tune high-performance blue-light emitting halides. 相似文献
Tricrilactones A–H ( 1 – 8 ), a new family of oligomeric 10-membered macrolides featuring collectively five unique ring skeletons, were isolated from a hitherto unexplored fungus, Trichocladium crispatum. Compounds 1 and 7 contain two unconventional bridged (aza)tricyclic core skeletons, 2 , 3 , 5 , and 6 share an undescribed tetracyclic 9/5/6/6 ring system, 4 bears an uncommon 9/5/6/10/3-fused pentacyclic architecture, and 8 is a dimer bridged by an unexpected C−C linkage. Their structures, including absolute configurations, were elucidated by spectroscopic analysis, quantum chemical calculations, and X-ray diffraction analysis. Importantly, the absolute configuration of the highly flexible side chain of 1 was resolved by the asymmetric synthesis of its four stereoisomers. The intermediate-trapping and isotope labeling experiments facilitated the proposal of the biosynthetic pathway for these macrolides. In addition, their antiosteoporosis effects were evaluated in vivo (zebrafish). 相似文献
A powerful approach to generate multilevel superposition state in A-type manifold of levels is proposed. In the analysis, we introduce a group of rotations to transform the coupled system to a simpler form, which involves one coupled and several decoupled, dark states in the ground state manifold. Then an arbitrary superposition state of initial and final states can be created. In particular, when the Rabi frequencies of the Stokes pulses have equal magnitudes, a superposition state (equal population of the (n - 2) superposition states) will be generated. A numerical simulation of coherence generation is given. It is shown that a small transient population in metastable state decreases as the intensity of Stokes pulses increases. Experimental implementation in Neon atom is given. 相似文献
Y2.6−xCa0.4+xZrxV0.2Fe4.8−xO12 (Zrx:YCaVIG) ferrite materials have been prepared by an oxide process. The phase formation and microstructure were analyzed by X-ray diffraction and scanning electron microscopy, respectively. The effects of Zr4+ substitution on phase compositions, sintering properties, microstructures and electromagnetic properties were investigated. The results indicate that all the sintered specimens with different Zr4+ contents show a single garnet structure. The addition of ZrO2 can gradually increase the lattice constant, and lower the sintering temperature and the theoretical density. With the increase of Zr4+ content, the dielectric loss (tan δε) and coercivity (Hc) decrease and then slightly increase, which is due to the variation of the microstructure. But the saturation magnetization (4πMs) shows the opposite variation compared to the former two properties. However, the dielectric constant (εr) remains stable and remanence (Br) monotonically declines. Finally, the specimen of Y2.3Ca0.7Zr0.3V0.2Fe4.5O12 sintered at 1350° possesses the optimum electromagnetic properties: εr=14.8, tan δε=1.35×10−3, 4πMs=1638 Gs, Br=596 Gs, Hc=0.75 Oe and ΔH (ferromagnetic resonance linewidth)=66 Oe. 相似文献
The nitrile functionality is a key building block in synthetic chemistry, and has wide applications in pharmaceuticals. However, traditional methodologies for the synthesis of nitriles are limited to harsh reaction conditions. Herein, we report a new and efficient access to aryl nitriles by an electrochemical synthesis. Compared with the conventional synthetic methods, this electrochemical synthesis is more environmentally friendly and easier to handle. 相似文献
Ferroelectric poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE))/semiconducting poly(3-hexyl thiophene) (P3HT) blend systems have drawn great attention with their potential use for electronic applications, particularly non-volatile memory devices. It is essential to grasp a full understanding of the crystallization habits of the two polymers on different substrates for purposeful control of the structures of the blend and therefore the properties of the devices. Here, the effects of structure and morphology of the blend films generated at different substrate surfaces on the ferroelectric and switching properties of related devices are reported. It is identified that P(VDF-TrFE)/P3HT blend films prepared on graphene substrate show not only an obvious optimization in the ferroelectric behavior of P(VDF-TrFE), but also an enhancement of the charge transport within P3HT domains. By employing sandwich structure constructed by silver electrode and P3HT/P(VDF-TrFE) blend film on graphene substrate, high-performance ferroelectric memory devices have been obtained, which exhibit a great electrical switching behavior with high ON/OFF ratio of about 1000 and low coercive voltage of approximately 5 V. These findings provide useful guidance for fabricating high-performance ferroelectric memory devices.