全文获取类型
收费全文 | 760篇 |
免费 | 17篇 |
国内免费 | 4篇 |
专业分类
化学 | 512篇 |
晶体学 | 7篇 |
力学 | 37篇 |
数学 | 64篇 |
物理学 | 161篇 |
出版年
2020年 | 10篇 |
2019年 | 9篇 |
2018年 | 6篇 |
2016年 | 15篇 |
2015年 | 11篇 |
2014年 | 9篇 |
2013年 | 27篇 |
2012年 | 38篇 |
2011年 | 28篇 |
2010年 | 20篇 |
2009年 | 12篇 |
2008年 | 44篇 |
2007年 | 45篇 |
2006年 | 50篇 |
2005年 | 41篇 |
2004年 | 42篇 |
2003年 | 30篇 |
2002年 | 26篇 |
2001年 | 14篇 |
2000年 | 18篇 |
1999年 | 17篇 |
1998年 | 14篇 |
1997年 | 5篇 |
1996年 | 14篇 |
1995年 | 7篇 |
1994年 | 10篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1990年 | 7篇 |
1989年 | 11篇 |
1988年 | 9篇 |
1986年 | 5篇 |
1985年 | 11篇 |
1984年 | 9篇 |
1983年 | 7篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1979年 | 9篇 |
1978年 | 5篇 |
1977年 | 12篇 |
1976年 | 6篇 |
1975年 | 13篇 |
1974年 | 8篇 |
1973年 | 10篇 |
1972年 | 6篇 |
1970年 | 5篇 |
1968年 | 10篇 |
1967年 | 4篇 |
1966年 | 4篇 |
1965年 | 4篇 |
排序方式: 共有781条查询结果,搜索用时 15 毫秒
1.
E.‐A. McGonigle J. J. Liggat R. A. Pethrick S. D. Jenkins J. H. Daly D. Hayward 《Journal of Polymer Science.Polymer Physics》2004,42(15):2916-2929
For as‐extruded amorphous and biaxially orientated polyester films based on poly(ethylene terephthalate), poly(ethylene naphthalate), and copolymers containing poly(ethylene terephthalate) and poly(ethylene naphthalate) moieties, permeability, diffusion, and solubility coefficients are interpreted in terms of chain mobility. The influence of polymer morphology is determined by comparison of the data for as‐extruded amorphous sheets and materials produced with different biaxial draw ratios. The crystallinities of the samples were assessed using differential scanning calorimetry and density measurements. Changes in mobility at a molecular level were investigated using dielectric spectroscopy and dynamic mechanical thermal analysis. The study, in conjunction with our earlier work, leads to the conclusion that the key to understanding differences in gas transport is the difference in local chain motions rather than in free volume. This was illustrated by the permeability results for He, Ar, N2, and O2 in the range of polyesters. However, the permeability of CO2 was found to require alternative explanations because of polymer–penetrant interactions. For biaxially oriented samples, the differences in diffusivity are not only due to differences in local chain motions, but also additional constraints resulting from the increased crystallinity and chain rigidity—which also act to hinder segmental mobility. The effectiveness of the reduction in permeability in the biaxially oriented films is consequently determined by the ability of the polymer chains to effectively align and form crystalline structures. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2916–2929, 2004 相似文献
2.
Atomic emission detection of metallic species in aqueous solutions has been performed using a miniaturised plasma created within a planar, glass micro-fluidic chip. Detection was achieved using an Electrolyte as a Cathode Discharge source (ELCAD) in which the sample solution itself is used as the cathode for the discharge. To realise the ELCAD technique within a micro-fluidic device, a parallel liquid-gas flow was set up in a micro-channel and a glow discharge ignited between the flowing liquid sample surface and a metal wire anode. The detection of copper and sodium was achieved, using atmospheric pressure air as a carrier gas, by observation of atomic emission lines of copper at 324 nm, 327 nm, 511 nm, 515 nm and 522 nm and an atomic emission line of sodium at 589 nm using a commercially available miniaturised spectrometer. A total electrical power of less than 70 mW was required to sustain the discharge. A semi-quantitative, absolute detection limit of 17 nmol s(-1) was obtained for sodium with a sample flow rate of 100 microL min(-1) and an integration time of 100 ms in air at atmospheric pressure. The volume required for such detection is approximately 170 nL. Further analysis was performed with an Echelle spectrometer using both argon and air as a carrier gas. The geometry and flow rates used demonstrate the feasibility of integrating such micro-plasmas into other micro-fluidic devices, such as miniaturised CE devices, as a method of detection. The potential for using such micro-plasmas within highly portable miniaturised systems and mu-TAS devices is presented and discussed. 相似文献
3.
Two organoaluminium amides have been used to initiate the polymerizations of methyl methacrylate, acetaldehyde and n-butyraldehyde. Methyl methacrylate polymerized through the vinyl function to give amorphous products. The aldehydes reacted through the carbonyl group at low temperatures with high degrees of stereospecificity to give polymers with substantial crystallinity. The molecular weight of the polyacetaldehyde is very high. 相似文献
4.
A solid-phase extraction method is described for the separation of alachlor, atrazine and metolachlor from groundwater using solid-phase disposable columns. The method is rapid, reproducible and uses considerably fewer reagents than classical liquid-liquid methods. The average recoveries were greater than 90% for all three compounds. 相似文献
5.
Masakazu Uramoto Kimie Kobinata Kiyoshi Isono Tsutomu Higashijima Tatsuo Miyazawa Ellen E. Jenkins James A. McCloskey 《Tetrahedron》1982,38(11):1599-1608
New chitin synthetase inhibitors, neopolyoxins A, B, and C were isolated from the culture filtrate of Streptomyces cacaoi subsp. asoensis. Their absolute structures have been established on the basis of chemical and spectroscopic evidence. They are structural analogs of the polyoxins. As a nucleobase, neopolyoxin C possesses uracil, while neopolyoxins A and B contain the imidazoline moiety. A ring contraction reaction of pyrimidine nucleoside into imidazoline nucleoside played a key role in the structure determination of the nucleoside moiety. A similar transformation was suggested for the biosynthesis of neopolyoxins A and B. 相似文献
6.
7.
8.
9.
Singh SB Ball RG Bills GF Cascales C Gibbs JB Goetz MA Hoogsteen K Jenkins RG Liesch JM Lingham RB Silverman KC Zink DL 《The Journal of organic chemistry》1996,61(22):7727-7737
Farnesyl-protein transferase (FPTase) is an enzyme responsible for the farnesylation of Ras protein. Farnesylation is required for cell-transforming activity in several tumor-types, and therefore, inhibition of FPTase activity may be a potential target for anticancer drugs. Our continued search for novel inhibitors led to the isolation of a number of bicyclic resorcinaldehyde cyclohexanone derivatives named here cylindrols A(1) to A(4), cylindrols B and B(1), and a number of known compounds, from Cylindrocarpon lucidum. The compounds were isolated by bioassay-guided separation using Sephadex LH-20, silica gel, and reverse phase HPLC. Structures were elucidated by extensive application of 2D NMR and X-ray crystallography. The determination of absolute stereochemistry was accomplished by CD measurements. Chemical transformations of the most abundant compound resulted in a number of key derivatives which were critical for the evaluation of structure activity relationship. These compounds are members of ascochlorin family and showed a wide range of inhibitory activity (0.7 &mgr;M to >140 &mgr;M) against FPTase. The FPTase activity was noncompetitive with respect to both substrates. Isolation, structures, chemical transformations, and FPTase activity are discussed in detail. 相似文献
10.