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A simple and efficient route for the synthesis of oxepine‐, oxocine‐, oxepinone‐, and dioxocine‐angularly annulated flavone skeletons has been developed. The combined Claisen rearrangement and the ring‐closing metathesis are used as key steps for the construction of C7/C8–C6–C6 tricyclic core structures. 相似文献
3.
Jayaprakash KN Peng CG Butler D Varghese JP Maier MA Rajeev KG Manoharan M 《Organic letters》2010,12(23):5410-5413
Novel non-nucleoside alkyne monomers compatible with oligonucleotide synthesis were designed, synthesized, and efficiently incorporated into RNA and RNA analogues during solid-phase synthesis. These modifications allowed site-specific conjugation of ligands to the RNA oligonucleotides through copper-assisted (CuAAC) and copper-free strain-promoted azide-alkyne cycloaddition (SPAAC) reactions. The SPAAC click reactions of cyclooctyne-oligonucleotides with various classes of azido-functionalized ligands in solution phase and on solid phase were efficient and quantitative and occurred under mild reaction conditions. The SPAAC reaction provides a method for the synthesis of oligonucleotide-ligand conjugates uncontaminated with copper ions. 相似文献
4.
Giridharan Loganathan Suresh Krishnaraj Jayaprakash Muthumanickam Ravichandran K 《Journal of Chemometrics》2015,29(1):59-68
In order to bring out the nature of the factors influencing lake water composition, multivariate statistical analysis and trend analysis were performed based on the hydrochemical data of the study area, namely, South Chennai. Change in land use pattern and settlements along the banks of the lakes alters the quality and quantity of the surface water. In the present study, the R‐mode factor analysis and cluster analysis were applied to the geochemical parameters of the water to identify the factors affecting the chemical composition of the lake water. Dendograms of both the seasons give three major clusters, reflecting the groups of unpolluted to moderately polluted, polluted, and heavily polluted stations. The movement of stations from one cluster to another clearly brings out the seasonal variation in the chemical composition of the lake water. The complex hydrochemical data of the surface water were interpreted by condensing them into three major factors. Factor score analysis was used successfully to delineate the stations under study and the role of the contributing factors, and the nature of factors responsible for the variation in chemical composition of the water has been clearly brought out. Results of trend analysis using ArcGIS clearly indicate that the trend in water quality is deteriorating at a faster rate in the eastern part of the study area. It is understood that although natural shifts probably can account for some of the variation, it is most likely that human activities play a major role in affecting the water quality on a regional scale. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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P. Sangeetha P. Jayaprakash M. Nageshwari M. Peer Mohamed G. Vinitha M. Lydia Caroline 《Chinese Journal of Physics (Taipei)》2018,56(2):721-739
We synthesized noncentrosymmetric single crystals of L-phenylalanine nitrate (LPN) and tris L-(phenylalanine) L-phenylalaninium nitrate (TPLPN) by slow solvent evaporation technique. Both crystallized in monoclinic system with different acentric space groups namely P21 (LPN) and C2 (TPLPN) respectively. The IR and Raman spectral investigation was done for LPN and TPLPN and discussed. The UV-vis-studies accomplished the excitation wavelength of the grown crystals suitable to exhibit second harmonic generation signal. From the absorption data, remarkable optical properties such as direct band gap energy, Urbach energy, extinction coefficient were evaluated. The mechanical strength of the grown crystal was examined by Vickers micro hardness test. The temperature of decomposition was confirmed by TG/DSC analysis. Fluorescence emission spectrum of LPN and TPLPN were recorded and lifetime was also studied. The dielectric constant and dielectric loss of LPN and TPLPN has been determined as a function of frequency and temperature. Also the surface topologies of the crystallized salts were assessed by SEM studies. The third-order nonlinearities of LPN and TPLPN were determined by Z-scan technique with Nd: YAG at 532?nm and thereby from closed and open Z-scan data, third-order susceptibilities were calculated to be χ(3)?=?8.826?×?10?6 esu for LPN and χ(3)?=?2.552?×?10?7 esu for TPLPN. 相似文献
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K. R. Jayaprakash Yuli Starosvetsky Alexander F. Vakakis Maxime Peeters Gaetan Kerschen 《Nonlinear dynamics》2011,63(3):359-385
We study standing waves (nonlinear normal modes—NNMs) and band zones in finite granular chains composed of spherical granular
beads in Hertzian contact, with fixed boundary conditions. Although these are homogeneous dynamical systems in the notation
of Rosenberg (Adv. Appl. Mech. 9:155–242, 1966), we show that the discontinuous nature of the dynamics leads to interesting effects such as separation between beads, NNMs
that appear as traveling waves (these are characterized as pseudo-waves), and localization phenomena. In the limit of infinite
extent, we study band zones, i.e., pass and stop bands in the frequency–energy plane of these dynamical systems, and classify
the essentially nonlinear responses that occur in these bands. Moreover, we show how the topologies of these bands significantly
affect the forced dynamics of these granular media subject to narrowband excitations. This work provides a classification
of the coherent (regular) intrinsic dynamics of one-dimensional homogeneous granular chains with no pre-compression, and provides
a rigorous theoretical foundation for further systematic study of the dynamics of granular systems, e.g., the effects of disorders
or clearances, discrete breathers, nonlinear localized modes, and high-frequency scattering by local disorders. Moreover,
it contributes toward the design of granular media as shock protectors, and in the passive mitigation of transmission of unwanted
disturbances. 相似文献
9.
Jayaprakash KN Gillepsie AM Gunnoe TB White DP 《Chemical communications (Cambridge, England)》2002,(4):372-373
Deprotonation of [TpRu(CO)(PPh3)(NHPh)][OTf]2 yields the thermally unstable d4 imido complex [TpRu-(CO)(PPh3)(NPh)][OTf]; a computational study of the bonding of the imido complex provides a foundation for discussion of its instability in terms of pi-conflict. 相似文献
10.