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Tingting Chen Jassmin Lahbi Prof. Gianluigi Broggini Dr. Alexandre Pradal Prof. Giovanni Poli 《European journal of organic chemistry》2023,26(8):e202201493
Two previously unknown protocols for Pd-catalyzed allylic C−H sulfonylation of terminal alkenes have been developed. While the former consists of a direct Pd(II)-catalyzed oxidative C−H allylic sulfonylation in the presence of sulfinate anions, the latter involves a sequential one-pot Pd(II)-catalyzed C−H allylic acetoxylation followed by a Pd(0)-catalyzed sulfonylation. The scope of both protocols was studied on 25 examples. 相似文献
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