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1.
Could simple intraannular-arm macrocyclic systems exist in enantiopure stable forms? The effective synthesis of two representative compounds of such a class, their resolution into enantiomers, and experiments justifying their stability toward racemization are presented. 相似文献
2.
I. D. Lomako M. I. Danil’kevich D. V. Karpinskiĭ I. I. Makoed 《Crystallography Reports》2008,53(2):278-284
The experimental and calculated values of the optical permittivity ε∞ have been analyzed and generalized with allowance for the oxygen concentration and possible valences of Fe and O ions in YIG single crystals. It is shown that the deficit of oxygen ions in the samples is accompanied by a decrease in ε∞. A decrease in the gradient of distribution of Ba ions over the sample thickness decreases the difference between the calculated and experimental values. It is revealed that the ratio of the number of valence electrons to the number of core electrons, with regard to their polarizabilities, is proportional to the ratio of the incoherent and coherent X-ray scattering intensities, nk/k. 相似文献
3.
We characterize Poisson and Jacobi structures by means of complete lifts of the corresponding tensors: the lifts have to be
related to canonical structures by morphisms of corresponding vector bundles. Similar results hold for generalized Poisson
and Jacobi structures (canonical structures) associated with Lie algebroids and Jacobi algebroids. 相似文献
4.
J. Kircher M. Cardona M. Alouani S. Gopalan O. Jepsen O. K. Andersen
E. Kaldis
J. Karpinski S. Rusieki 《Physica C: Superconductivity and its Applications》1992,200(3-4):413-417We report results of ellipsometric measurements of the dielectric tensor of YBa2Cu4O8 as well as calculations employing density functional theory in the local density approximation (LDA). For the computation of the one-electron eigenvalues and states the linear-muffin-tin-orbital method (LMTO) was used. Measured and calculated results show good agreement. In particular, the calculation predicts different band structures for YBa2Cu3O7 and YBa2Cu4O8 in the vicinity of the Fermi energy which lead to significant differences in the optical spectra. One such difference is a region of small ε2 in the near infrared which is a fingerprint of the high (relative to the top of the highest fully occupied band) Fermi energy as compared to the situation in YBa2Cu3O7. Our experimental results confirm the theoretical findings. 相似文献
5.
Dorota G?azowska Janusz Matkowski 《Journal of Mathematical Analysis and Applications》2007,331(2):1187-1199
The invariance of the geometric mean G with respect to the Lagrangian mean-type mapping (Lf,Lg), i.e. the equation G○(Lf,Lg)=G, is considered. We show that the functions f and g must be of high class regularity. This fact allows to reduce the problem to a differential equation and determine the second derivatives of the generators f and g. 相似文献
6.
Tomasz Stawski Janusz Szklarzewicz Krzysztof Lewiński 《Transition Metal Chemistry》2006,31(3):353-361
The single crystal X-ray structure of (AsPh4)[W(bpy)(CN)6] is described. The structure of octa- and hepta-coordinated intermediates of substitutional photolysis of [Mo(CN)8]4− ion in aqueous media were determined by performing semi-empirical calculations. On the basis of obtained results as well
as on empirical data the photolysis scheme has been postulated. 相似文献
7.
Janusz Mierczyński Wenxian Shen Xiao-Qiang Zhao 《Journal of Differential Equations》2004,204(2):471-510
The purpose of this paper is to investigate uniform persistence for nonautonomous and random parabolic Kolmogorov systems via the skew-product semiflows approach. It is first shown that the uniform persistence of the skew-product semiflow associated with a nonautonomous (random) parabolic Kolmogorov system implies that of the system. Various sufficient conditions in terms of the so-called unsaturatedness and/or Lyapunov exponents for uniform persistence of the skew-product semiflows are then provided. Among others, it is shown that if the associated skew-product semiflow has a global attractor and its restriction to the boundary of the state space has a Morse decomposition which is unsaturated or whose external Lyapunov exponents are positive, then it is uniformly persistent. More specific conditions are discussed for uniform persistence in n-species, particularly 3-species, random competitive systems. 相似文献
8.
M. Werner P. Brenner N. Goldowski R. Heinze M. Marder H. von der Heyden D. A. Strom B. M. Rybak M. M. Ognew A. Cousen G. Schikorr Z. Karpinski Ch. Dufraisse R. May K. Laurell und M. G. Ammon 《Fresenius' Journal of Analytical Chemistry》1938,115(7-8):283-289
Ohne Zusammenfassung 相似文献
9.
Janusz B. Kyzio Krzysztof Ejsmont 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(2):o77-o79
The title compound, C19H15N3, was prepared by condensation of 3‐nitrosocarbazole and aniline with subsequent methylation. The structure is built up of stacks of almost planar molecules. Density functional theory (DFT) calculations predict a completely planar conformation, different from that observed in the crystal lattice. HOMA (harmonic oscillator model of aromaticity) indices, calculated for three aromatic rings, demonstrate the small influence of the azo substituent on π electrons in the carbazole system. 相似文献
10.
Piotr Dobrzynski Janusz Kasperczyk 《Journal of polymer science. Part A, Polymer chemistry》2006,44(10):3184-3201
Using zirconium(IV) acetylacetonate as an initiator of lactide/trimethylene carbonate copolymerization allowed us to obtain high‐molecular‐weight copolymers with high efficiency. The reactivity ratios of the comonomers were 13.0 for lactide and 0.53 for trimethylene carbonate. Despite the large differences between the values of the reactivity ratios, copolymers with randomized chain structures were obtained. This phenomenon occurred as a result of an intensive intermolecular transesterification process proceeding along with the reaction of copolymer chain growth and modifying its final structure. Conducting the copolymerization at the relatively low temperature of about 110 °C, which minimized the influence of intermolecular transesterification, made it possible to obtain semicrystalline copolymers with multiblock structures. Increasing the temperature of copolymerization up to 180 °C was associated with strong intensification of the transesterification reactions. At this temperature, amorphous copolymers were obtained with identical compositions but highly randomized chain structures. An analysis of the chain microstructures of the obtained copolymers, determining the average length of the blocks, the intermolecular transesterification ratio, and the degree of chain randomization, was conducted by means of NMR spectroscopy. For this purpose, very specific signal assignment in the carbonyl and methylene carbon regions of the 13C NMR spectra to appropriate comonomer sequences of polymeric chains was performed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3184–3201, 2006 相似文献