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1.
2.
Martin Kellert Jan-Simon Jeshua Friedrichs Nadine Anke Ullrich Alexander Feinhals Jonas Tepper Peter Lnnecke Evamarie Hey-Hawkins 《Molecules (Basel, Switzerland)》2021,26(7)
The development of novel, tumor-selective and boron-rich compounds as potential agents for use in boron neutron capture therapy (BNCT) represents a very important field in cancer treatment by radiation therapy. Here, we report the design and synthesis of two promising compounds that combine meta-carborane, a water-soluble monosaccharide and a linking unit, namely glycine or ethylenediamine, for facile coupling with various tumor-selective biomolecules bearing a free amino or carboxylic acid group. In this work, coupling experiments with two selected biomolecules, a coumarin derivative and folic acid, were included. The task of every component in this approach was carefully chosen: the carborane moiety supplies ten boron atoms, which is a tenfold increase in boron content compared to the l-boronophenylalanine (l-BPA) presently used in BNCT; the sugar moiety compensates for the hydrophobic character of the carborane; the linking unit, depending on the chosen biomolecule, acts as the connection between the tumor-selective component and the boron-rich moiety; and the respective tumor-selective biomolecule provides the necessary selectivity. This approach makes it possible to develop a modular and feasible strategy for the synthesis of readily obtainable boron-rich agents with optimized properties for potential applications in BNCT. 相似文献
3.
4.
5.
P. David J. Hartfiel H. Janszen R. von Mutius J. Arvieux L. Farvacque B. Berthier B. Bonin J. C. Lugol 《Zeitschrift für Physik A Hadrons and Nuclei》1987,326(4):367-372
The excitation function of the fission probability P E E x) for238U has been measured in the reaction238U(α, α′ f) at 480 MeV bombarding energy. The reaction mechanism of this reaction is discussed for excitation energies belowB nf , the threshold for second chance fission, and aboveB nf up toE x =37 MeV. In comparing with results from fission induced by photons and by particle transfer reactions the (α, α′f) reaction gives too low values for the fission probabilityP f at excitation energies well aboveB nE . The role of the quasi-elastic knock-out process in this reaction is discussed. 相似文献
6.
M. Brando N. Büttgen V. Fritsch J. Hemberger H. Kaps H.-A. Krug von Nidda M. Nicklas K. Pucher W. Trinkl A. Loidl E.W. Scheidt M. Klemm S. Horn 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,25(3):289-298
We present susceptibility, microwave resistivity, NMR and heat-capacity results for Li1-xZnx(V1-yTiy)2O4 with 0 ?
x
? 0.3 and 0 ?
y
? 0.3. For all doping levels the susceptibility curves can be fitted with a Curie-Weiss law. The paramagnetic Curie-Weiss temperatures
remain negative with an average value close to that of the pure compound Θ≈ - 36 K. Spin-glass anomalies are observed in the susceptibility, heat-capacity and NMR measurements for both type of dopants.
From the temperature dependence of the spin-lattice relaxation rate we found critical-dynamic behavior in the Zn doped compounds
at the freezing temperatures. For the Ti-doped samples two successive freezing transitions into disordered low-temperature
states can be detected. The temperature dependence of the heat capacity for Zn-doped compounds does not resemble that of canonical
spin glasses and only a small fraction of the total vanadium entropy is frozen at the spin-glass transitions. For pure LiV2O4 the spin-glass transition is completely suppressed. The temperature dependence of the heat capacity for LiV2O4 can be described using a nuclear Schottky contribution and the non-Fermi liquid model, appropriate for a system close to
a spin-glass quantum critical point. Finally an (
x
/
y
,
T
)-phase diagram for the low-doping regime is presented.
Received 16 March 2001 and Received in final form 30 October 2001 相似文献
7.
H. G. Bohlen W. von Oertzen R. Kalpakchieva B. Gebauer S. M. Grimes A. Lenz T. N. Massey M. Milin Ch. Schulz Tz. Kokalova S. Torilov S. Thummerer 《Physics of Atomic Nuclei》2003,66(8):1494-1500
The structure of neutron-rich beryllium isotopes has been investigated using different heavy-ion-induced transfer reactions. In neutron transfer reactions, the population of final states shows a strong sensitivity to the chosen core nucleus, i.e., the target nuclei 9Be or 10Be, respectively. Molecular rotational bands up to high excitation energies are observed with 9Be as the core due to its pronounced 2α-cluster structure, whereas only a few states at low excitation energies are populated with 10Be as the core. For 11Be, a detailed investigation has been performed for the three states at 3.41, 3.89, and 3.96 MeV, which resulted in the most probable spin-parity assignments 3/2+, 5/2?, and 3/2?, respectively. Furthermore, we have studied particle-hole states of 16C using the 13C(12C, 9C)16C reaction and found 14 previously unknown states. Using the 12C(12C, 9C)15C reaction, five new states were observed for 15C. 相似文献
8.
Georg von Georgievics 《Monatshefte für Chemie / Chemical Monthly》1885,6(1):754-759
Ohne ZusammenfassungDiese Untersuchung ist vor mehr als Jahresfrist infolge Eintrittes in die chemische Praxis abgebrochen worden. Äussere Verhältnisse machen die Vollendung der begonnenen Versuche auch weiterhin unmöglich und sehe ich mich desshalb veranlasst, meine Beobachtungen zu veröffentlichen. 相似文献
9.
W. von Oertzen 《Acta Physica Hungarica A》2003,18(2-4):157-170
Nuclear clustering in N = Z nuclei has been studied for many decades. Of particular relevance are states close to the decay thresholds, as described by the Ikeda diagram. Recent interest has focused on loosely bound systems as observed with exotic nuclei. Extreme deformations are simultaneously observed. In the deformed shell model these are referred to as super- and hyper-deformation. Another feature related to clustering is the development of octupole deformations. A possible approach to describe these states is to use explicitly molecular concepts, with neutrons in covalent binding orbits. Examples for molecular structure in beryllium isotopes and in other neutron-rich light nuclei (carbon and neon) are now well established. The predicted chain states in the carbon isotopes are the first example of structures with an axis ratio of 3:1. A threshold diagram for molecular configurations in nuclei with clusters and covalent neutrons can be established. 相似文献
10.
W. von der Linden 《Applied Physics A: Materials Science & Processing》1995,60(2):155-165
The reconstruction of physical quantities from (computer-) experimental data is very often hampered by the presence of noise, insufficient information and above all by the ill-posed nature of the underlying inversion problem. It will be demonstrated that the maximum entropy concepts is particularly suited for this type of data-analysis problems. It is based on Bayesian statistics and provides a consistent probabilistic theory to obtain unbiased results, independent of any model assumptions. This is particularly desirable if there is no additional information to justify these hypotheses. If, on the other hand, additional prior knowledge is available, it can be effectively incorporated into the computation, leading to more stringent confidence intervals. 相似文献