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It is a well-known feature of odd space-time dimensions d that there exist two inequivalent fundamental representations A and B of the Dirac gamma matrices. Moreover, the parity transformation swaps the fermion fields living in A and B. As a consequence, a parity-invariant Lagrangian can only be constructed by incorporating both the representations. Based upon these ideas and contrary to long-held belief, we show that in addition to a discrete exchange symmetry for the massless case, we can also define chiral symmetry provided the Lagrangian contains fields corresponding to both the inequivalent representations. We also study the transformation properties of the corresponding chiral currents under parity and charge-conjugation operations. We work explicitly in 2 + 1 dimensions and later show how some of these ideas generalize to an arbitrary number of odd dimensions. 相似文献
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Jaime E. Muñoz Rivera Maria Grazia Naso 《Journal of Mathematical Analysis and Applications》2007,326(1):691-707
We study the asymptotic behavior of the solutions of a class of linear dissipative integral differential equations. We show in the abstract setting a necessary and sufficient condition to get an exponential decay of the solution. In the case of the lack of exponential decay, we find the polynomial rate of decay of the solution. Some examples are given. 相似文献
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Jaime Pfretzschner Pedro Cobo Francisco Simón María Cuesta Alejandro Fernández 《Applied Acoustics》2006,67(1):62-73
Microperforated panels (MPPs) coupled to a rigid wall have been proposed recently as an alternative to porous absorbers in situations having concerns with bacterial contamination and small particles discharge, like food, pharmaceutical and microelectronic industries. There exists also an increasing interest for MPP absorbers in the transportation industry and civil engineering. In general, an optimally designed MPP with good broadband absorption requires many submillimetric holes distributed over a panel of also submillimetric thickness. Such thin plates or foils become so fragile that they need to be protected from mechanical damage. In this paper, an alternative strategy is investigated which allows the design of MPPs with panels of millimetric thickness while maintaining their acoustic performance. These absorbers, named microperforated insertion units (MIUs), avoid the structural problems of the classical MPPs. An assessment of the sound absorption properties of these structures is presented. Comparisons between calculations and measurements are also made under two experimental conditions: plane waves at normal incidence (impedance tube) and free field (anechoic room). 相似文献
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Jaime Wisniak 《The Chemical Educator》2000,5(5):263-268
Amedeo Avogadro was a multifaceted and prolific scientist active in many areas of physics and chemistry, but most of his results did not make a scientific impact. His hypothesis, equal volumes = equal number of molecules remained in obscurity until Cannizaro rekindled it by making it a stepping-stone in the development of the atomic theory. 相似文献
8.
Mueller JA Cowell A Chandler BD Sigman MS 《Journal of the American Chemical Society》2005,127(42):14817-14824
A kinetic investigation into the origin of enantioselectivity for the Pd[(-)-sparteine]Cl(2)-catalyzed aerobic oxidative kinetic resolution (OKR) is reported. A mechanism to account for a newly discovered chloride dissociation from Pd[(-)-sparteine]Cl(2) prior to alcohol binding is proposed. The mechanism includes (1) chloride dissociation from Pd[(-)-sparteine]Cl(2) to form cationic Pd(-)-sparteine]Cl, (2) alcohol binding, (3) deprotonation of Pd-bound alcohol to form a Pd-alkoxide, and (4) beta-hydride elimination of Pd-alkoxide to form ketone product and a Pd-hydride. Utilizing the addition of (-)-sparteine HCl to control the [Cl(-)] and [H(+)] and the resulting derived rate law, the key microscopic kinetic and thermodynamic constants were extracted for each enantiomer of sec-phenethyl alcohol. These constants allow for the successful simulation of the oxidation rate in the presence of exogenous (-)-sparteine HCl. A rate law for oxidation of the racemic alcohol was derived that allows for the successful prediction of the experimentally measured k(rel) values when using the extracted constants. Besides a factor of 10 difference between the relative rates of beta-hydride elimination for the enantiomers, the main enhancement in enantiodetermination results from a concentration effect of (-)-sparteine HCl and the relative rates of reprotonation of the diastereomeric Pd-alkoxides. 相似文献
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The inclusion complexes between the most commonly used cyclodextrins (alpha-, beta-, and gamma-CD) and 1-bromoadamantane were prepared and studied experimentally by NMR methods and by molecular dynamics simulations (AMBER force field) with solvation. The NMR results suggest host/guest ratios of 2:1, 1:1, and 1:1 for the complexes with alpha-, beta-, and gamma-cyclodextrin, respectively, as well as defined geometries for the complexes. Averaged geometrical data from the molecular dynamics simulations agree with the complexation geometries deduced experimentally. 相似文献
10.
Santiago Conde Carlos Corral Jaime Lissavetzky 《Journal of heterocyclic chemistry》1980,17(5):937-940
The synthesis by two alternative routes of 1-(3-benzo[b]thienyloxy)-3-isopropylamino-2-propanol hydrochloride ( 1a HCl), a thiophenic isoster of Propranolol, and related compounds, is reported. The protecting and enolizing properties of the 2-methoxycarbonyl group on benzo[b]thiophene-3-one, along with its facile removal, are utilized in the first route. In the second one, conversion of 3-bromobenzo[b]thiophene in 1-(3-benzo[b]thienyloxy)-2,3-o-isopropylidenepropane is the key step. On the other hand, hydrolysis of 1-(3-benzo[b]furanyloxy)-2,3-o-isopropylidenepropane to the corresponding diol, in order to obtain a furanic isoster of Propranolol (17a ), was unsuccessful. 相似文献