Determination of rhenium in the URe2 binary compound by differential spectrophotometry

A differential spectrophotometric determination of rhenium in its binary compound with uranium is described; the method is based on the action of tin(II) chloride on perrhenate in the presence of dimethylglyoxime with measurement at 445 nm. Uranium does not interfere. For solutions containing about 1 mg of rhenium, the coefficient of variation was 0.08%.     

Hyperpolarization of Amino Acids in Water Utilizing Parahydrogen on a Rhodium Nanocatalyst

NMR offers many possibilities in chemical analysis, structural investigations, and medical diagnostics. Although it is broadly used, one of NMR spectroscopies main drawbacks is low sensitivity. Hyperpolarization techniques enhance NMR signals by more than four orders of magnitude allowing the design of new contrast agents. Parahydrogen induced polarization that utilizes the para-hydrogen's singlet state to create enhanced signals is of particular interest since it allows to produce molecular imaging agents within seconds. Herein, we present a strategy for signal enhancement of the carbonyl ¹³C in amino acids by using parahydrogen, as demonstrated for glycine and alanine. Importantly, the hyperpolarization step is carried out in water and chemically unmodified canonical amino acids are obtained. Our approach thus offers a high degree of biocompatibility, which is crucial for further application. The rapid sample hyperpolarization (within seconds) may enable the continuous production of biologically useful probes, such as metabolic contrast agents or probes for structural biology.     

Alkylation of Unsaturated Aldehyde and Allylic Bisacetate With Organomanganese Reagents in Presence of Tetrakis Acetonitrile Copper(I) Tetrafluroborate

The conjugate addition of organomanganese reagents to α,β‐unsaturated aldehydes and allylic bisacetate in presence of Me₃Si‐Cl and tetrakis acetonitrile copper(I) tetrafluroborate is described.     

ZrOCl2·8H2O: An Efficient Catalyst for One-Pot Synthesis of α-Amino Phosphonates Under Solvent-Free Conditions

A highly efficient protocol has been developed for the three-component reaction of an amine, an aldehyde, and diethyl phopshite catalyzed by ZrOCl₂·8H₂O, an environmentally friendly catalyst, at ambient temperature. The catalyst exhibited remarkable activity and tolerated a wide variety of functional groups, providing the desired amino phosphonates in excellent yields under solvent-free conditions. Alternatively, the reaction rate can be significantly enhanced by carrying out the reaction in a monomode microwave reactor as a promoter.     

Ultrasound assisted regioselective sulfonation of aromatic compounds with sulfuric acid

A simple and convenient methodology for selective sulfonation of aromatic compounds using sulfuric acid under sonication is described. The present methodology shows a considerable enhancement in the reaction rate along with improved selectivity compared with the reactions performed under silent conditions. The effect of various parameters such as agitation speed, sulfuric acid concentration, and temperature on reaction system have been investigated and are explained on the basis of ultrasonically generated cavitational effects.     

Overtone spectroscopy of some benzaldehyde derivatives

Overtone spectrum of o, m and p-nitrobenzaldehydes and p-chlorobenzaldehyde has been studied in 2000–12000 cm⁻¹ region. Vibrational frequencies and anharmonicity constants for aryl as well as alkyl CH stretch vibrations have been determined. We have also determined the internuclear distances for the aryl CH bond in the different molecules. The small variation observed in these distances is an indication of the substitution effect. It is observed that in the case of p-disubstituted benzens, the shift in aryl CH bond is proportional to sum of the Hammet σ of the substituents. However in the case of o-disubstituted benzenes it is only 80% of the para-substituted shift.     

First enantioselective organocatalytic allylation of simple aldimines with allyltrichlorosilane

A new organocatalytic system, novel chiral bisformamide and in situ generated L-proline-derived allylsilane reagent , which converts different aldimines to homoallylic amines in good to high yields (up to 95%) and good enantioselectivities (up to 85% ee) has been described.     

Post buckling response of functionally graded materials plate subjected to mechanical and thermal loadings with random material properties

In this paper, the second order statistics of post buckling response of functionally graded materials plate (FGM) subjected to mechanical and thermal loading with nonuniform temperature changes subjected to temperature independent (TID) and dependent (TD) material properties is examined. Material properties such as material properties of each constituent’s materials, volume fraction index are taken as independent random input variables. The basic formulation is based on higher order shear deformation theory (HSDT) with von-Karman nonlinear kinematic using modified C⁰ continuity. A direct iterative based C⁰ nonlinear finite element method (FEM) combined with mean centered first order perturbation technique (FOPT) proposed by last two authors for the composite plate is extended for Functionally Graded Materials (FGMs) plate with reasonable accuracy to compute the second order statistics (mean and coefficient of variation) of the post buckling load response of the FGM plates. The effect of random material properties with amplitude ratios, volume fraction index, plate thickness ratios, aspect ratios, boundary conditions and types of loadings subjected to TID and TD material properties are presented through numerical examples. The performance of outlined present approach is validated with the results available in literatures and independent Monte Carlo simulation (MCS).