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排序方式: 共有790条查询结果,搜索用时 15 毫秒
1.
Chetan Bhadaliya Bala Krishna Panigrahy Dipanjan Goswami Sovan Maiti Sanjay Jagannath Gurule Arshad H. Khuroo 《Biomedical chromatography : BMC》2022,36(4):e5337
A selective, highly sensitive, precise, and novel bioanalytical method has been developed and validated to quantify sinococuline, an active constituent present in the phytopharmaceutical drug product containing Cocculus hirsutus plant extract, in vivo. Chromatographic separation was achieved on a Luna Omega Polar-C18 bonded analytical column maintained at 45°C. The isocratic mobile phase consisted of methanol and ammonium formate buffer (60:40, v/v) at acidic pH with a low flow rate of 0.250 mL/min. Detection was performed on an API 4000 mass spectrometer using electrospray ionization in positive polarity and multiple reaction monitoring mode to achieve a lower limit of quantification of 1.50 ng/mL. Excellent accuracy and precision were obtained after extracting the analyte from plasma samples using a chemical analogue as an internal standard in the absence of an isotope-labeled compound. The extraction efficacy was evidenced from recovery study, and the analyte was found to be stable in plasma. Validation study demonstrated linearity with coefficient of correlation, r ≥ 0.99, and minimal matrix effect. This bioanalytical method was successfully applied to evaluate pharmacokinetic parameters of sinococuline from a phase I clinical trial of an aqueous extract of C. hirsutus in healthy human volunteers. 相似文献
2.
B. Sahoo W. Keune E. Schuster W. Sturhahn T. S. Toellner E. E. Alp 《Hyperfine Interactions》2006,168(1-3):1185-1190
Amorphous (a-) Fe x Mg1?x alloys are interesting materials for the investigation of non-Debye-like low-energy vibrational excitations. We have prepared a-Fe x Mg1?x alloy thin films (0.3 ≤ × ≤0.7) by vapour quenching. The amorphous state was confirmed by conversion electron Mössbauer spectroscopy between 4.2–300 K, and the x- and temperature-dependence of the isomer shift and hyperfine magnetic field was measured. For x= 0.6 and 0.7, magnetic ordering occurs below ~150 K. The atomic vibrational density of states, g(E), was determined by nuclear resonant inelastic scattering, providing clear evidence for the non-Debye-like low-energy vibrational excitations. 相似文献
3.
The object of the paper is to study the absolute matrix summability problem of Fourier series, conjugate series and some associated
series under a new set of conditions on matrix methods, generalising many known results in the literature. 相似文献
4.
Himansu Sekhar Sahoo S. Mahalakshmi Md. Hedayetullah Mir R. Raghunathan 《Tetrahedron letters》2007,48(5):761-765
A remarkable upfield shift of the pyα protons of complexed 2,2′-bipyridine in [cis-Pd(bpy)(NO3)2] is observed which is considered to originate from the anisotropic influence of suitably positioned coordinated nitrate anions around the Pd(II) centre of the molecule. A typical complexation-induced downfield shift is observed for the NH2 protons in [cis-Pd(en)(NO3)2] where ‘en’ stands for ethylenediamine. 相似文献
5.
Nakao Y Imanaka H Sahoo AK Yada A Hiyama T 《Journal of the American Chemical Society》2005,127(19):6952-6953
Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes, highly stable tetraorganosilicon reagents, are found to react with aryl and alkenyl iodides in the presence of a palladium catalyst and K2CO3 as a base, significantly milder conditions compared with those ever reported for the silicon-based cross-coupling reactions. The reaction tolerates a wide range of functional groups, including silyl protectors, and allows a gram-scale synthesis to recover and reuse the silicon residue. 相似文献
6.
Shi W Sahoo Y Swihart MT Prasad PN 《Langmuir : the ACS journal of surfaces and colloids》2005,21(4):1610-1617
A method is presented for synthesizing core-shell structures consisting of monodisperse polystyrene latex nanospheres as cores and gold nanoparticles as shells. Use of polystyrene spheres as the core in these structures is advantageous because they are readily available commercially in a wide range of sizes, and with dyes or other molecules doped into them. Gold nanoparticles, ranging in size from 1 to 20 nm, are prepared by reduction of a gold precursor with sodium citrate or tetrakis(hydroxymethyl)phosphonium chloride (THPC). Carboxylate-terminated polystyrene spheres are functionalized with 2-aminoethanethiol hydrochloride (AET), which forms a peptide bond with carboxylic acid groups on their surface, resulting in a thiol-terminated surface. Gold nanoparticles then bind to the thiol groups to provide up to about 50% coverage of the surface. These nanoparticles serve as seeds for growth of a continuous gold shell by reduction of additional gold precursor. The shell thickness and roughness can be controlled by the size of the nanoparticle seeds as well as by the process of their growth into a continuous shell. By variation of the relative sizes of the latex core and the thickness of the gold overlayer, the plasmon resonance of the nanoshell can be tuned to specific wavelengths across the visible and infrared range of the electromagnetic spectrum, for applications ranging from the construction of photonic crystals to biophotonics. The position and width of the plasmon resonance extinction peak are well-predicted by extended Mie scattering theory. 相似文献
7.
An alkalophilic hyperproducer of alkaline protease, Bacillus sp. NG312, was isolated, and the enzyme showed maximum activity at pH 11.0 and 60°C. The temperature optimum was increased
by 10°C in presence of Ca2+. The crudeenzyme was found to have half-life of 11 d at 37°C and maximum stability at pH 9.0–10.0. It also exhibited very
good stability in presence of detergent components and some locally available commericial detergent powders. 相似文献
8.
Processes for the production of xylenes, which occur in an integrated aromatic complex, are discussed. A brief overview of the work carried out at Indian Petrochemicals Corporation Limited for the development of zeolite-based catalytic processes for the production of aromatics is presented. This includes xylene isomerization, transalkylation and disproportionation of C7 and C9 aromatics for maximization of xylenes, selective disproportionation of toluene and selective alkylation of mono-alkylaromatics to p-dialkylbenzene. Achievements in the commercialization of zeolite-based catalysts and processes for isomerization of m-xylene to p- and o-xylene along with dealkylation of ethylbenzene, and for selective ethylation of ethylbenzene to produce p-diethylbenzene are highlighted. 相似文献
9.
Various new structural entities related to x-azatricyclo[m.n.0. 0(a)()(,)(b)()]alkanes are constructed by the intramolecular [3 + 2] dipolar cycloaddition of nonstabilized cyclic azomethine ylides. The ylide is generated by the sequential double desilylation of N-alkyl alpha,alpha'-bis(trimethylsilyl)cyclic amines using Ag(I)F as a one-electron oxidant. 相似文献
10.
Pyridinium methanesulfonate (m.p. 185°C) and pyridinium p-toluenesulfonate (m.p. 121°C) were used as catalysts and media for the esterification of carboxylic acids with primary alcohols
to give the corresponding esters selectively in high yields. The high melting points of these pyridinium salts did not prevent
their application as ionic liquid medium for these reactions which were performed at 90°C. 相似文献