全文获取类型
收费全文 | 161篇 |
免费 | 2篇 |
专业分类
化学 | 133篇 |
力学 | 6篇 |
数学 | 3篇 |
物理学 | 21篇 |
出版年
2022年 | 2篇 |
2020年 | 2篇 |
2019年 | 2篇 |
2017年 | 2篇 |
2013年 | 8篇 |
2012年 | 6篇 |
2011年 | 5篇 |
2010年 | 2篇 |
2009年 | 2篇 |
2008年 | 4篇 |
2007年 | 5篇 |
2006年 | 4篇 |
2005年 | 5篇 |
2004年 | 5篇 |
2003年 | 3篇 |
2002年 | 2篇 |
1992年 | 3篇 |
1987年 | 2篇 |
1971年 | 2篇 |
1970年 | 6篇 |
1967年 | 5篇 |
1959年 | 2篇 |
1956年 | 2篇 |
1954年 | 2篇 |
1953年 | 2篇 |
1943年 | 2篇 |
1917年 | 2篇 |
1914年 | 2篇 |
1913年 | 4篇 |
1912年 | 10篇 |
1911年 | 1篇 |
1909年 | 1篇 |
1908年 | 2篇 |
1907年 | 2篇 |
1904年 | 1篇 |
1903年 | 3篇 |
1902年 | 3篇 |
1900年 | 1篇 |
1898年 | 1篇 |
1895年 | 1篇 |
1893年 | 2篇 |
1891年 | 2篇 |
1887年 | 1篇 |
1886年 | 3篇 |
1885年 | 1篇 |
1883年 | 1篇 |
1881年 | 1篇 |
1879年 | 5篇 |
1865年 | 1篇 |
1862年 | 3篇 |
排序方式: 共有163条查询结果,搜索用时 187 毫秒
1.
Seoung-Soo Lee Ho-In Park Chung-Hyung Joh Song-Ho Byeon 《Journal of solid state chemistry》2007,180(12):3529-3534
Three different synthetic methods, the liquid phase process in HCl solution, the solvothermal reaction, and the surfactant-assisted solvothermal reaction, were explored to selectively control the particle shape and to enhance the luminescence intensity of the PbFCl-type red-emitting oxychloride phosphors LnOCl:Eu (Ln=La and Gd). The solvothermal pressure facilitated the low-temperature crystallization of the rod-shape particles for both Ln=La and Gd. It is noted that LaOCl:Eu nanorods show highly porous particle surface and quite low photoemission intensity. In contrast, the solvothermal synthesis could highly enhance the red-emission of GdOCl:Eu with no porous surface so as to be comparable to that of commercial Y2O3:Eu phosphor. An addition of surfactant material during solvothermal reaction yielded a rhomboidal-shape phosphor particles with no porous surface for both Ln=La and Gd. Interestingly, the elimination of surface porosity by using a surfactant significantly increased the emission intensity of LaOCl:Eu. It is proposed that the application of solvothermal technique for the synthesis of the PbFCl-type oxychloride phosphors is very effective to selectively control the particle shape and consequently to enhance the photoemission intensity if we use an appropriate surfactant material. 相似文献
2.
Reactive oxygen species (ROS) has been implicated as an inducer of NF-kappaB activity in numbers of cell types where exposure of cells to ROS such as H(2)O(2) leads to NF-kappaB activation. In contrast, exposure to oxidative stress in certain cell types induced reduction of tumor necrosis factor (TNF)- induced NF-kappaB activation. And various thiol-modifying agents including gold compounds and cyclopentenone prostaglandins inhibit NF-kappaB activation by blocking IkappaB kinase (IKK). To understand such conflicting effect of oxidative stress on NF- kappakB activation, HeLa cells were incubated with H(2)O(2) or diamide and TNF-induced expression of NF-kappaB reporter gene was measured. NF-kappaB activation was significantly blocked by these oxidizing agents, and the inhibition was accompanied with reduced nuclear NF-kappaB and inappropriate cytosolic IkappaB degradation. H(2)O(2) and diamide also inhibited IKK activation in HeLa and RAW 264.7 cells stimulated with TNF and lipopolysaccharide, respectively, and directly blocked IKK activity in vitro. In cells treated with H(2)O(2) alone, nuclear NF-kappaB was induced after 2 h without detectable degradation of cytosolic IkappaBalphaa or activation of IKK. Our results suggest that ROS has a dual effect on NF-kappaB activation in the same HeLa cells: it inhibits acute IKK-mediated NF-kappakB activation induced by inflammatory signals, while longer-term exposure to ROS induces NF-kappaB activity through an IKK-independent pathway. 相似文献
3.
4.
Yasushi Joh Koichi Harada Heimei Yuki Shunsuke Murahashi 《Journal of polymer science. Part A, Polymer chemistry》1971,9(4):1089-1102
The polymerization of isobutyl vinyl ether by vanadium trichloride in n-heptane was studied. VCl3 ? LiCl was prepared by the reduction of VCl4 with stoichiometric amounts of BuLi. This type of catalyst induces stereospecific polymerization of isobutyl vinyl ether without the action of trialkyl aluminum to an isotactic polymer when a rise in temperature during the polymerization was depressed by cooling. It is suggested that the cause of the stereospecific polymerization might be due to the catalyst structure in which LiCl coexists with VCl3, namely, VCl3 ? LiCl or VCl2 ? 2LiCl as a solid solution in the crystalline lattice, since VCl3 prepared by thermal decomposition of VCl4 and a commercial VCl3 did not produce the crystalline polymer and soluble catalysts such as VCl4 in heptane and VCl3 ? LiCl in ether solution did not yield the stereospecific polymer. It was found that some additives, such as tetrahydrofuran or ethylene glycol diphenyl ether, to the catalyst increased the stereospecific polymerization activity of the catalysts. Influence of the polymerization conditions such as temperature, time, monomer and catalyst concentrations, and the kind of solvent on the formed polymer was also examined. 相似文献
5.
Jinsoo Kim Jimin Park Young Ju Jung Eun Chol Kim Taek Ahn Jae-Won Ka 《Liquid crystals》2013,40(5):589-599
We have synthesised a series of new reactive mesogens with photopolymerisable di-acrylates and their corresponding non-reactive analogues based on the π-conjugated aromatic core, fluorene (F)-di-[thiophene (T)-benzene (B)], using the Stille and Suzuki coupling reaction. The effect of lateral alkyl chains on the 9-position of the central fluorene moiety as well as α, ω- side alkyl chains attached to the π-conjugated aromatic core on the mesomorphism was investigated by utilising differential scanning calorimetry (DSC) and polarising optical microscopy (POM). A wide angle X-ray scattering (WAXS) study at the various temperatures was also carried out to reveal phase structures. Photopolymerisable di-acrylates connected directly to the rigid aromatic core showed higher phase transition temperatures, probably due to the induced dipole moment in comparison with those of a non-reactive methyl–ether counterpart. 相似文献
6.
7.
8.
9.
10.