Summary Bidentate complexes of dimolybdenum tetraacetate with 1,3-diaxial diols show Cotton effects around 490–540 nm (CD band I), 400–440 nm (II), 350–380 nm (III), 320 nm (IV) and 280 nm (V). The sign of the Cotton effect II can be predicted by a proposed sector rule. It seems that from the Cotton effects for cyclic 1,3-diols the absolute configurations or conformations can be obtained.A part of this material was presented at III-rd International Conference on CD Spectroscopy [1] 相似文献
The investigations of reaction between Ag2SO4 and Ag2S in air atmosphere have been carried. Results of DTA and X-ray phase powder diffraction of a reaction mixture have confirmed that in the Ag?O?S system exists a new phase. A formula of the phase is Ag2SO2. 相似文献
A new series of 2-spiro(2,2-diphenylcyclopropane) cephalosporin sulfones was synthesizes as potent human leukocyte elastase inhibitors.SynPhar Laboratories Inc., #2 Taiho Alberta Centre, 4290-91A Street, Edmonton, Canada T6R 5V2. Published in Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1517–1523, November, 1998. 相似文献
Abstract Elimination of one methyl group by excess of N,N-dipropylamine transformed S-(3,4,6-tri-O-acetyl-2-deoxy-α-D-glucopyranosyl)-O,O-dimethyl-dithiophosphate1 into the N,N-dipropylammonium (R)S- (3,4,6-tri-O-acetyl-2-deoxy-α-D-glucopyranosyl)-O-methyl-dithiophosphate with chiral centre on phosphorus atom. 相似文献
The distribution coefficients and enantioseparation of cyclopentolate were studied in an extraction system containing d-tartaric acid ditertbutyl ester in organic phase and 2-hydroxypropyl-β-cyclodextrin (HP-β-CD) in aqueous phase. Various parameters involved in the enantioseparation such as the type and the concentration of chiral selectors, pH value and a wide range of organic solvents were investigated. The maximum enantioselectivity (α = 2.13) and optimum distribution coefficients (KR = 0.85, KS = 0.40) were obtained under the following conditions: 0.10 mol/L HP-β-CD in aqueous phase and 0.20 mol/L d-tartaric acid ditertbutyl ester in decanol as organic phase. Cyclopentolate is present as a racemic mixture to the aqueous phase. The potentially different biological activities of cyclopentolate enantiomers have not been examined yet. Two chiral liquid chromatography methods have been developed for the direct separation of the enantiomers of cyclopentolate. First method was used for the quantification analysis of cyclopentolate enantiomers in aqueous phase. Second method used two chiroptical detectors: electronic circular dichroism (ECD) and optical rotation (OR) for the identification of individual cyclopentolate enantiomers from the organic phase enriched with (R)-enantiomer. The absolute stereochemistry was determined by means of the comparison of the experimental and computed ECD spectra and signs of OR. The ECD spectra of chiral analytes were measured on-line using HPLC-ECD technique.
The method and the results of radon concentration measurements in water samples are presented. Since May 2000, measurements of radon concentration in well waters in the Kraków area have been carried out--both in urban wells (depth above 50 meters) and in other private wells (depth of several meters). The ionisation chamber AlphaGUARD PQ 2000PRO along with the additional special equipment AquaKIT were used for determination of radon concentration in water samples. A total of 45 wells were examined for radon concentration in water--19 urban wells, 21 private ones (from Nowa Huta, Ojcowska, Wola Justowska area--parts of Kraków) and 5 mineral water sources. Wola Justowska is a region where tectonics faults occur and radon can easily migrate from deep basement structure. All the obtained values of radon concentration are below 12 Bq/l. These preliminary results do not show a direct correlation between geological structure and radon concentration in water samples. However, further investigation is needed and is planned to be undertaken. 相似文献
Summary The effect of solvent on the photodegradation kinetics of fluvastatin was evaluated. The degradation rate of fluvastatin was estimated on the basis of the quantum yields and kinetic parameters determination. The photodegradation appeared to follow first-order kinetics. In order to establish the light intensity absorbed by a system, Reinecke’s salt was used as a chemical actinometer. 相似文献