全文获取类型
收费全文 | 439篇 |
免费 | 8篇 |
国内免费 | 2篇 |
专业分类
化学 | 283篇 |
力学 | 4篇 |
数学 | 58篇 |
物理学 | 104篇 |
出版年
2022年 | 4篇 |
2021年 | 8篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 8篇 |
2016年 | 8篇 |
2015年 | 7篇 |
2014年 | 8篇 |
2013年 | 18篇 |
2012年 | 19篇 |
2011年 | 26篇 |
2010年 | 7篇 |
2009年 | 11篇 |
2008年 | 20篇 |
2007年 | 16篇 |
2006年 | 8篇 |
2005年 | 12篇 |
2004年 | 10篇 |
2003年 | 18篇 |
2002年 | 14篇 |
2001年 | 7篇 |
2000年 | 9篇 |
1999年 | 15篇 |
1998年 | 5篇 |
1997年 | 11篇 |
1996年 | 7篇 |
1995年 | 12篇 |
1994年 | 5篇 |
1993年 | 14篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 12篇 |
1989年 | 5篇 |
1988年 | 9篇 |
1987年 | 10篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1974年 | 4篇 |
1973年 | 2篇 |
1970年 | 4篇 |
1967年 | 2篇 |
1966年 | 5篇 |
1965年 | 2篇 |
排序方式: 共有449条查询结果,搜索用时 265 毫秒
1.
Dr. Kyung-Seok Kang Dr. Krishnan A. Iyer Prof. Dr. Jeffrey Pyun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(35):e202200115
In this concept review, the fundamental and polymerization chemistry of inverse vulcanization for the preparation of statistical and segmented sulfur copolymers, which have been actively developed and advanced in various applications over the past decade is discussed. This concept review delves into a discussion of step-growth polymerization constructs to describe the inverse vulcanization process and discuss prepolymer approaches for the synthesis of segmented sulfur polyurethanes. Furthermore, this concept review discusses the advantages of inverse vulcanization in conjunction with dynamic covalent polymerization and post-polymerization modifications to prepare segmented block copolymers with enhanced thermomechanical and flame retardant properties of these materials. 相似文献
2.
3.
CV Tomy D Pal SS Banerjee S Ramakrishnan AK Grover S Bhattacharya MJ Higgins G Balakrishnan McK Paul 《Pramana》2002,58(5-6):925-935
The weakly pinned single crystals of the hexagonal 2H-NbSe2 compound have emerged as prototypes for determining and characterizing the phase boundaries of the possible order-disorder
transformations in the vortex matter. We present here a status report based on the ac and dc magnetization measurements of
the peak effect phenomenon in three crystals of 2H-NbSe2, in which the critical current densities vary over two orders of magnitude. We sketch the generic vortex phase diagram of
a weakly pinned superconductor, which also utilizes theoretical proposals. We also establish the connection between the metastability
effects and pinning. 相似文献
4.
The synthesis of oligoethylene glycols of defined lengths possessing different end functionalities is described. The utility of these molecules towards the development of a generic membrane anchor is demonstrated. 相似文献
5.
6.
7.
8.
P. C. Kalsi A. K. Pandey R. H. Iyer 《Journal of Radioanalytical and Nuclear Chemistry》1995,201(2):165-170
A -spectrometric method has been developed for the assay of uranium in crude UF4, which is used as a secondary source of input material for producing nuclear grade U-metal at natural uranium conversion plants. The method makes use of a NaI (Tl) detector coupled with a multichannel analyzer. The 1 MeV -ray of238U is used for calibration. A method for the fabrication of uniform -assay calibration standards is also suggested, based on the results of this investigation. The calibration standards were prepared by soaking the matrix in uranium solution and then drying the whole material. The amount of238U in the crude UF4 sample was directly estimated by comparing the areas under the 1 MeV -ray peak of known calibration standards with the corresponding areas of the samples to be measured. 100 g each of the standard and the sample were counted. 5 crude UF4 samples were analyzed by this method. The uranium contents in these samples were found to be in the range of 12.2–28.7 g. To compare the -ray spectrometry results with a completely independent method, chemical analysis by potentiometry of all the samples was also done. The -spectrometric results were found to agree within ±18% with the chemical analysis results. 相似文献
9.
Two low-dimensional compounds, KSnAsS(5) and K(2)SnAs(2)S(6), were prepared using liquid polythioarsenate salts, and the results differ from those obtained with the well studied thiophosphate flux. KSnAsS(5) crystallizes in the orthorhombic space group Pbam with cell parameters of a = 8.136(2) A, b = 13.784(4) A, c = 7.428(2) A. KSnAsS(5) features the unusual pyramidal species [AsS(2)(S(2))](3-). K(2)SnAs(2)S(6) crystallizes in the trigonal space group P3 macro with cell parameters a = 6.717(5) A, b = 7.204(8) A, gamma = 120 degrees. The compounds were obtained by controlling the Lewis basicity of the K(2)S/As(2)S(3)/S flux. The optical, thermal, and spectroscopic properties of the compounds are reported. 相似文献
10.
Wipf P Coleman CM Janjic JM Iyer PS Fodor MD Shafer YA Stephenson CR Kendall C Day BW 《Journal of combinatorial chemistry》2005,7(2):322-330
Cascade reactions of internal and terminal alkynes, zirconocene hydrochloride, dimethylzinc, and phosphinoyl imines (prepared in one step from aldehydes and diphenylphosphinoyl amide) lead to allylic phosphinoyl amides after aqueous workup. Microwave acceleration allows the completion of this one-pot reaction sequence in 10 min. These allylic amides can be converted into a variety of derivatives, including carbamates and sulfonamides, or reacted prior to workup with diiodomethane to give novel C-cyclopropylalkylamides. A solution-phase "libraries from libraries" approach was used to generate an intermediate 20-member library which was subsequently expanded to a 100-member library by a series of N-functionalizations. The biological activity was evaluated in an assay for competitive binding to the estrogen receptor (ERalpha), revealing three potent lead compounds of a new structural type. 相似文献