全文获取类型
收费全文 | 1449篇 |
免费 | 13篇 |
国内免费 | 9篇 |
专业分类
化学 | 1251篇 |
晶体学 | 15篇 |
力学 | 6篇 |
数学 | 37篇 |
物理学 | 162篇 |
出版年
2020年 | 7篇 |
2019年 | 11篇 |
2018年 | 10篇 |
2017年 | 5篇 |
2016年 | 13篇 |
2015年 | 9篇 |
2014年 | 19篇 |
2013年 | 61篇 |
2012年 | 57篇 |
2011年 | 56篇 |
2010年 | 30篇 |
2009年 | 45篇 |
2008年 | 63篇 |
2007年 | 69篇 |
2006年 | 70篇 |
2005年 | 77篇 |
2004年 | 78篇 |
2003年 | 75篇 |
2002年 | 88篇 |
2001年 | 27篇 |
2000年 | 23篇 |
1999年 | 23篇 |
1998年 | 16篇 |
1997年 | 19篇 |
1996年 | 14篇 |
1995年 | 17篇 |
1994年 | 15篇 |
1993年 | 17篇 |
1992年 | 13篇 |
1991年 | 15篇 |
1990年 | 9篇 |
1989年 | 7篇 |
1988年 | 9篇 |
1987年 | 11篇 |
1986年 | 6篇 |
1985年 | 34篇 |
1984年 | 45篇 |
1983年 | 22篇 |
1982年 | 29篇 |
1981年 | 23篇 |
1980年 | 30篇 |
1979年 | 27篇 |
1978年 | 23篇 |
1977年 | 20篇 |
1976年 | 28篇 |
1975年 | 15篇 |
1974年 | 22篇 |
1973年 | 13篇 |
1972年 | 14篇 |
1967年 | 6篇 |
排序方式: 共有1471条查询结果,搜索用时 15 毫秒
1.
Isao Takemura 《Tetrahedron letters》2006,47(37):6673-6676
Two optional routes to β-phenylnaphthalene structure are developed by introducing α- and β-styryl groups onto different positions in the benzocyclobutene ring followed by ring enlargement. 相似文献
2.
Kosuke Morita Kouji Morimoto Daiya Kaji Yu Liang Zhao Atsushi Yoshida Toshimi Suda Akira Yoneda Tetsuya Ohnishi Hiromitsu Haba Eiji Ideguchi Hu Shan Xu Tao Zheng Hisaaki Kudo Keisuke Sueki Kenji Katori Isao Tanihata 《Acta Physica Hungarica A》2004,19(1-2):53-60
A gas-filled type of recoil separator for heavy element research was installed at an experimental hall of RIKEN Linear Accelerator facility to realize getting higher intensity of primary beam and long beam time. Performance of the separator was studied using target recoils and various nuclear reactions. The results show the high performance of the separator for heave element research. As an application of the GARIS, production and identification of an isotope of the 110th element 271[110] have been performed using the 208Pb(64Ni,1n)271[110] reaction. Three decay chains coincide well both in decay times and energies with the ones reported by the group of SHIP experiment at GSI, Germany. Our results provide a confirmation of the synthesis of an isotope 271[110] of element 110. 相似文献
3.
Hiromichi Kurosu Mizuyo Kikuchi Isao Ando 《Journal of Polymer Science.Polymer Physics》1995,33(5):769-775
The solid-state 15N CP/MAS NMR spectra and 15N spin-lattice relaxation times (T1) of doped and dedoped 15N-labeled polypyrroles prepared by electrochemical polymerization, have been measured by means of high-resolution solid-state 15N NMR. The 15N signal of polypyrrole consists of four peaks decomposed by line shape analysis. The four peaks obtained have been assigned to the various structures of polypyrrole. Further, the half-width of the 15N NMR spectra of polypyrroles is discussed as related to the electrical conductivity. © 1995 John Wiley & Sons, Inc. 相似文献
4.
Naoki Miyamoto Shusuke Nisiyama Satoshi Tomioka Takeaki Enoto 《Optics Communications》2007,272(1):67-72
We utilize nitroanisole, that absorbs infrared (IR) radiation as heat, as an optical modulation device based on a thermal process. The nitroanisole exhibits a thermal lens effect, i.e. a temperature dependent refractive index. Hence, the nitroanisole can induce phase modulation to visible light, in direct response to intensity of the incident IR radiation. The proposed method can be used to obtain the phase modulation distribution that corresponds to the IR intensity distribution, i.e. the IR hologram itself, on the nitroanisole by examining the phase map of visible light that is modulated upon passing through the nitroanisole. The IR wavefront can be reconstructed by calculating extracted IR holograms through the Fresnel transform. It is verified that both the amplitude and the phase of the IR wavefront can be reconstructed accurately by proposed method. 相似文献
5.
Isao Tanikawa Nobuo Hirakawa Hiroko Hosono Hiroshi Nakamura 《Analytical sciences》2007,23(11):1267-1274
Hydro-membrane gas chromatography (HMGC) is achieved by the annular condensation of water in a capillary column at less than 70 degrees C. The annular membrane of water is formed as a result of the wettability of the stationary phase, which is induced at a water contact angle ranging from 75 degrees to 79 degrees, as derived from a solubility parameter (delta) range of 15.7 +/- 0.3 MPa(1/2) of the coated resin. The range of the liquid to gas volume ratio (beta) required to support the annular membrane should be kept between 0.00005 and 0.0003. In the case of a 0.25-mm i.d. column, the ratio can be set by the combination of a 0.1 to 0.2 microl min(-1) water supply rate and helium gas flow rate. Separation by HMGC develops not only a gas-solid partition but also a focusing effect on the water membrane. One feature of HMGC is that it gives a non-adsorption chromatogram based on the blocking effect of pre-adsorbed water; furthermore, despite the presence of a relatively large quantity of water, the electron impact ionization efficiency is kept the same as in the usual GC/MS condition. The detection limit with the injection of 1 microl of aquatic solution was estimated to be less than 0.1 ppb of low-molecular-weight fatty acids with s/n = 5 on a mass chromatogram at m/z 45. The HMGC/EI-MS system can be applied to the trace analysis of C1 to C3 volatile acids, volatile inorganic acids, and halogenated organic acids in water. 相似文献
6.
A convergent synthesis of the key synthetic intermediate of hemibrevetoxin B was achieved via the intramolecular allylation of an α-chloroacetoxy ether and subsequent ring-closing metathesis. 相似文献
7.
A compact high-resolution optical heterodyne interferometer combining a two-frequency light module and a minute optical system
is described. The light module, which generates two independent frequencies of light, is fabricated by proton exchange method
on LiNbO3 substrate. We report an experiment evaluating measurement accuracy using a micro-displacement measurement system which incorporates
this interferometer. Results of the experiment with a standard thickness sample show high thermal stability with maximum measurement
error of 1.8 nm at a temperature from 19°C to 33°C. The system was used to measure the hysteresis of a piezoelectric element
for displacements of several nm, thereby making it possible to analyze the system quantitatively in practice. 相似文献
8.
9.
Takanari Yasui Takeshi Ohtsuka Tetsu Suzuki Shigeki Okajima Kazuya Nakayama Mitsuru Tomioka Katsuhiro Kamimura Takeo Namekata Hiroaki Minamide Hiromasa Ito 《International Journal of Infrared and Millimeter Waves》2006,27(2):199-210
A new, wide-band, high-speed and high-sensitivity THz detector has been developed. The prototype detector consists of a parabolic
cylindrical mirror, a long wire antenna and a Schottky barrier diode. Direct detection measurements have shown a stable sensitivity
of 150 ± 50 V/W for 1–2 THz without any adjustments. The long wire antenna was fixed at the focus of parabolic cylindrical
mirror then it has been realized less operation steps, easy coupling to the external THz signals and a dramatic enhancement
in the practicality of this system. The optically polished mirror and frosted surface one showed comparable sensitivities,
thus easy polishing and less cost mirror fabrication can be applied for this system. The radiation pattern showed a maximum
radiation angle of approximately 23° with its dominant main lobe, which was attributed to the wire antenna character and confirmed
good agreements with classical antenna theory. 相似文献
10.