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1.
2.
Let G be a set of n points in general
position (i.e., no three points are on a line)
in the plane, and let C be a caterpillar on n vertices.
We show that one can always find a rectilinear embedding of C in the plane
such that the vertices of C are the points of G and no two edges of C
go to parallel segments. This proves a conjecture of
Robert E. Jamison. 相似文献
3.
4.
Dávid Szegvári Romána Zelkó Péter Horváth András Gergely 《Journal of inclusion phenomena and macrocyclic chemistry》2007,57(1-4):169-172
Enantioselective solubility of rac-norgestrel was found in the presence of γ-cyclodextrin or hydroxypropyl-γ-cyclodextrin.
In both cases the efficacious enantiomer was dissolved in greater extent. Calculating the molar absorptivity and molar ellipticity
spectra of the γ- and hydroxypropyl-γ-cyclodextrin aqueous complexes, a simple and rapid direct circular dichroism (CD) spectrometric
method was obtained for the determination of the enantiomer ratio in aqueous solutions. 相似文献
5.
G. N. Kozhemyakin D. V. Lutskiy M. A. Rom P. V. Mateychenko 《Crystallography Reports》2008,53(7):1267-1271
The growth conditions and structural quality of Sb-Bi gradient single crystals with Bi content from 2 to 18 at %, grown by
the Czochralski method with solid phase feed, are investigated. Bi distribution in the crystals along their pulling direction
are studied by electron probe microanalysis and the change in the interplanar spacing is analyzed by double-crystal X-ray
diffraction. It is established that the pulling rate and feed mass affect the Bi distribution in Sb-Bi single crystals. 相似文献
6.
Let C be a family of n different unit circles in the plane. We show that C determines at least n - c intersection points,
where c is the number of connected components in ∪C ∈ CC. This proves a conjecture of A. Bezdek. 相似文献
7.
F. Román S. Montserrat J. M. Hutchinson 《Journal of Thermal Analysis and Calorimetry》2007,87(1):113-118
The procedure for
the fabrication of epoxy-based polymer layered silicate nanocomposites is
important in respect of the nanostructure that is developed. To further our
understanding of this, the influence of an organically modified clay (montmorillonite,
MMT) on the curing kinetics of an epoxy resin has been studied by differential
scanning calorimetry. Clay loadings of 10 and 20 mass% are used, and isothermal
as well as dynamic cures have been investigated. For both cure schedules the
effect of the MMT is to advance the reaction. Kinetic analysis yields values
for the activation energy, but shows that the reaction cannot be described
simply by the usual autocatalytic equation. The glass transition of the cured
nanocomposites is lower than that for the cured neat resin, a result that
is attributed to homopolymerisation taking place in addition to the epoxy–amine
reaction. 相似文献
8.
Matthew J. Hills Irmgard Kiewitt Kumar D. Mukherjee 《Applied biochemistry and biotechnology》1991,27(2):123-129
Lipase from rape (Brassica napus L., immobilized onto celite, catalyzes esterification and transesterification reactions in hexane. The activity of the lipase is stimulated up to 35 fold by the addition of water (1.3% w/v). The activity of the lipase in hydrolysis is about 8 times higher than in the esterification reactions in hexane. Interesteri-fication reactions between mono- and diacylglycerols and transesterification reactions of mono- and diacylglycerols with alcohols were also catalyzed at relatively high rates but transesterification/esterification of these acylglycerols with fatty acids was comparatively slow. In transesterification reactions, triacylglycerols reacted rather slowly. 相似文献
9.
Irmgard Heber 《Colloid and polymer science》1967,215(2):145-149
Zusammenfassung Steigert man für das Poly?thylen die Kristallisationstemperatur, so findet man Kristallformen in der folgenden Reihenfolge:
rautenf?rmige Einkristalle— rautenf?rmige Einkristalle mit abgeschnittenen spitzen Ecken (“truncated lozenge crystals”)-l?ngliche
sechseckf?rmige Einkristalle, bei denen die kristallographische b-Achse der orthorhombischen Elementarzelle in Richtung der l?ngsten Ausdehnung des Kristalls liegt. Diese l?nglichen Sechsecke
lagern sich zu Sph?rolithen zusammen, und zwar so, da? die kristallographische b-Achse radial liegt, wie es auch bei den aus der Schmelze gewachsenen Sph?rolithen der Fall ist. Damit sind für das Poly?thylen
übergangsformen zwischen den Einkristallen und Sph?rolithen aufgezeigt.
Sph?rolithe, die aus der L?sung gewachsen sind, zeigen im Polarisationsmikroskop nur dann ein konzentrisches Ringsystem, wenn
bei der Bildung der Sph?rolithe ein Mindestangebot an Substanz vorhanden ist. Die Ringbreite nimmt dann mit steigender Kristallisationstemperatur
zu. Bei aus der Schmelze gewachsenen Poly?thylen-Sph?rolithen ist mit der Bildung von nicht-kristallographischen Verzweigungen
eine Drehung der Indikatrix verbunden. Vermutlich wird also auch bei aus der L?sung gewachsenen Sph?rolithen das Ringsystem
auf dem Auftreten von Verzweigungen infolge hohen Angebotes von kristallisierender Substanz beruhen.
Summary With increasing temperature of crystallization polyethylene crystallizes from solution as lozenge single crystals, truncated lozenge crystals and longish hexagonal crystals, with the crystallographic b-axis along the long diagonal. In the solutions longish hexagonal crystal plates are able to cluster and to form spherulites, in which their crystallographic b-axes are oriented radially like the b-axes in spherulites grown from the melt. Various transition species have been observed. In polarised light the spherulites grown from solution show a concentric ring-system only, if during the crystallization a sufficient quantity of polyethylene is present. The ring-width increases with increasing crystallization temperature. Further it is shown that in polyethylene spherulites grown from the melt the rotation of the indicatrix is connected with a non-crystallographic branching. We suppose, that also for the solution-grown spherulites the ring-system depends on branching.相似文献
10.